scholarly journals Phase equilibria in the quasiternary system Ag2Se–CdSe–In2Se3

2008 ◽  
Vol 1 (3/4) ◽  
pp. 274-282 ◽  
Author(s):  
I.A. IVASHCHENKO ◽  
◽  
O.F. ZMIY ◽  
I.D. OLEKSEYUK ◽  
◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Quasiternary System

scholarly journals Tl2Se–TlInSe2–Tl4P2Se6 QUASITERNARY SYSTEM

2019 ◽  
Vol 85 (2) ◽  
pp. 101-110
Author(s):  
Igor Barchiy ◽  
Valeriya Tovt ◽  
Michal Piasecki ◽  
Anatolii Fedorchuk ◽  
Artem Pogodin ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Ternary System ◽  
Phase Equilibria ◽  
Solid Solutions ◽  
Chemical Interaction ◽  
Structural Parameters ◽  
State Diagram ◽  
Complex Compounds ◽  
Perspective View ◽  
Quasiternary System

Complex chalcogenide compound are widely used as working elements for semiconductor optical technology, thermal generation, solar power. Special attention is paid to compounds of the M2P2Se6 type (M – Ag, Cu) which due to its layer crystal structure possess promising ferroelectric, thermoelectric and electro-optical properties. Heterovalent substitutions of cations 2М2+ ® 4M1+ in the composition of M2P2Se6 type compounds must leads to deformation of the crystal structure, changing in the value of the dipole moment and, accordingly, to change the electro-physical properties. The Tl2Se–In2Se3–“P2Se4” system characterized by the formation of intermediate complex compounds which melts congruently TlInSe2 (1023 К), Tl4P2Se6 (758 К), TlInP2Se6 (875 К) and TlIn5Se8 (melts incongruently L+In2Se3«TlIn5Se8 at 1029 К), In4(P2Se6)3 (formed by syntactic reaction at 880 К). Triangulation of the Tl2Se–In2Se3–“P2Se4” system was shown that then divided on secondary quasiternary systems, one of them is Tl2Se–TlInSe2–Tl4P2Se6. Phase equilibria in the Tl2Se – TlInSe2 – Tl4P2Se6 quasiternary system were studied using classical methods of physicochemical analysis DTA (chromel-alumel thermocouple, with an accuracy of ±5 K), XRD (DRON-3-13 diffractometer, Cu Ka radiation, Ni filter, Guinier Huber G670 diffractometer, CuKα1 radiation), MSA (metallographic microscope Lomo Metam R1) in combination with the simplex method of mathematical modeling of phase equilibria in multi-component systems. Crystal structure calculation was carried out with program WinCSD. Investigation of physical-chemical interaction allowed to constructed perspective view of phase state diagram and liquidus surface projection of the Tl2Se–TlInSe2–Tl4P2Se6 ternary system. In the ternary system formed the boundary solid solution: a- on the basis of Tl2Se, b- on the basis of TlInSe2, g-, d-, e- on the basis of ltm-, mtm- and htm-Tl4P2Se6 (ltm, mtm, htm – low, middle and high temperature modification, respectively). The liquidus of the ternary system consists of primary crystallization areas: Tl2Se-е1-Е1-е2-Tl2Se (a phase), TlInSe2-е3-U2-U1-E1-TlInSe2 (b phase), m1-U1-E1-e2-m1 (g phase), m2-U2-U1-m1-m2 (d phase) and Tl4P2Se6-e5-U2-m2-Tl4P2Se6 (ε phase). The Tl2Se–TlInSe2–Tl4P2Se6 quasiternary system is characterized by the processes: monovariant eutectic L«htmTl4P2Se6+TlInSe2 (e5-U2, 776-693 К), monovariant eutectic L«Tl2Se+TlInSe2 (e1-Е1, 614-539 К), monovariant eutectic L«Tl2Sе+ltmTl4P2Se6 (e2-Е1, 610-539 К); monovariant peritectic L+mtmTl4P2Se6«ltmTl4P2Se6 (m1-U1, 640-620 К); monovariant peritectic L+htmTl4P2Se6« mtmTl4P2Se6 (m2-U2, 747-693 К); monovariant peritectic L+mtmTl4P2Se6«TlInSe2 (U2-U1, 693-620 К); monovariant peritectic L+ltmTl4P2Se6«TlInSe2 (U1-E1, 620-539 К). Lines of the monovariant equilibria are crossed in three point: U2 – invariant peritectic process L+htmTl4P2Se6«TlInSe2+mtmTl4P2Se6 (12 mol.% Tl2Se, 20 mol.% TlInSe2, 68 mol.% Tl4P2Se6, 693 К), U1 – invariant peritectic process L+mtmTl4P2Se6«TlInSe2+ltmTl4P2Se6 (38 mol.% Tl2Se, 9 mol.% TlInSe2, 53 mol.% Tl4P2Se6, 620 К), E1 – invariant eutectic process L « Tl2Se+TlInSe2+ltmTl4P2Se6 (47 mol.% Tl2Se, 7 mol.% TlInSe2, 46 mol.% Tl4P2Se6, 539 К). New complex compounds were not observed in the ternary system. Limited solid solutions on the basis of TlInSe2, Tl4P2Se6 initial compounds are not up to 5–8 mol%. Crystal-structure studies of Tl2Se, TlInSe2 and Tl4P2Se6 complex chalcogenides were carried out by a powder method, refinement of the structural parameters – by the Rietveld method. The lattice parameters are: Tl2Se – Р4/n, а=8,540; с=12,380 Å, TlInSe2 – I4/mcm, a=8.064, c=6.833 Å, Tl4P2Se6 – P121/c1, a=12.239, b=9.055, c=12.328 Å, b=98.83. Crystal-chemical analysis of the compounds showed that they are characterized by a mixed ion-covalent type of chemical bond. During the transition from the binary Tl2Se to TlInSe2 ternary compound the covalent component of the In–Se bond is enhanced, the opposite change is observed for Tl4P2Se6, an increase in the ion component of the Tl–Se bond. The study of the mechanisms of formation of solid solutions showed that with the reciprocal solubility of the TlInSe2, Tl4P2Se6 ternary compounds characterized by the formation of substitution structure, the dissolution of Tl2Se in ternary selenides follows the substitution and subtraction mechanism.

scholarly journals PHASE EQUILIBRIA IN THE CuInSe2-Ge-Se QUASİTERNARY SYSTEM

2020 ◽  
Vol 18 (2) ◽  
pp. 244-249
Author(s):  
N.M. Allazova ◽  
◽  
R.F. Abbasova ◽  
T.M. Ilyasli ◽  
I.I. Aliyev ◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Quasiternary System

scholarly journals Phase equilibria in the quasiternary system Cu2Se–SnSe2–Sb2Se3

2009 ◽  
Vol 2 (3/4) ◽  
pp. 164-169 ◽  
Author(s):  
T.A. OSTAPYUK ◽  
◽  
I.M. YERMIYCHUK ◽  
O.F. ZMIY ◽  
I.D. OLEKSEYUK ◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Quasiternary System

Phase equilibria in partially open systems under pressure: the decomposition of stoichiometric GeO2 oxide

2003 ◽  
Vol 173 (12) ◽  
pp. 1359 ◽  
Author(s):  
Vadim V. Brazhkin ◽  
Roman N. Voloshin ◽  
A.G. Lyapin ◽  
Svetlana V. Popova
Keyword(s):  
Phase Equilibria ◽  
Open Systems

VAN LAAR EQUATION AND UNIFAC TO CORRELATE THE DATA LIQUID PHASE EQUILIBRIA FOR THE EXTRACTION OF PHENOLIC COMPOUNDS FROM MODEL COAL TAR

2016 ◽  
Vol 72 (9) ◽  
Author(s):  
Dewi Selvia Fardhyanti ◽  
Wahyudi B. Sediawan ◽  
Panut Mulyono ◽  
Muslikhin Hidayat
Keyword(s):  
Phenolic Compounds ◽  
Liquid Phase ◽  
Phase Equilibria ◽  
Coal Tar ◽  
Van Laar Equation

THERMODYNAMIC MODELLING OF MAFIC GRANULITES: DISCREPANCIES BETWEEN OBSERVED AND PREDICTED PHASE EQUILIBRIA

2018 ◽  
Author(s):  
Jacob B. Forshaw ◽  
◽  
David J. Waters ◽  
David R.M. Pattison ◽  
Richard M. Palin ◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Thermodynamic Modelling
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