scholarly journals Utilization of metallurgical solid by-products for the development of inorganic polymeric construction materials

2013 ◽  
Vol 11 (2) ◽  
pp. 127-136

This paper deals with the geopolymerization of the red mud generated in the primary aluminium production and the slag generated in the ferronickel production, in order to develop inorganic polymeric materials with advanced mechanical and physical properties. In particular, the effect of the main synthesis parameters of the inorganic polymeric materials on their mechanical strength and water absorption was investigated. Moreover, the structure of the inorganic polymeric materials was studied according to X-ray Diffraction analysis, Fourier Transform Infra Red spectroscopy and Scanning Electronic Microscopy. The inorganic polymeric materials produced by the geopolymerization of the red mud developed compressive strength up to 21 MPa and presented water absorption lower than 3 %, while the geopolymerization of the ferronickel slag resulted in materials with compressive strength higher than 110 MPa and extremely low water absorption (< 1 %). According to these results, the developed materials may be viewed as alternatives in the industrial sectors of construction and building materials.

2017 ◽  
Vol 888 ◽  
pp. 37-41
Author(s):  
Hasrul Yahya ◽  
Mohd Roslee Othman ◽  
Zainal Arifin Ahmad

Porcelain balls as grinding media are produced by firing process of clay, quartz and feldspar mixtures. This application need high technological properties such as high compressive strength and hardness, wear resistance, low water absorption and excellent chemical resistance. These properties are associated with higher firing temperatures. The porcelain balls were prepared by mixing 30 wt.% clay, 40 wt.% feldspar and 30 wt.% quartz. The samples were sintered at 1200°C, 1230°C, 1250°C, 1270°C and 1300°C for 2 hours with heating rate of 3°C/min. Both green powder and fired samples were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF) and scanning electron microscopy (SEM).The properties of the fired samples were evaluated by compressive strength, hardness, shrinkage, water absorption, bulk density, and porosity measurement. Increasing of compressive strength, hardness and density are associated with increasing of firing temperatures. Porcelain balls PB1 and PB2 can be produced as grinding media with optimum mechanical and physical properties at firing temperature 1270°C and 1250°C, respectively.


2021 ◽  
Vol 10 (2) ◽  
pp. 41
Author(s):  
Mei Sofiatul Hasanah ◽  
Yushardi Yushardi ◽  
Albertus Djoko Lesmono

The increase in Indonesia's development activities increases people's consumption of more quality construction materials and is easy to reach in terms of price. Building materials with good quality can improve the quality of building construction. The increasing need of the community for building materials triggered the development of the brick-making industry. Redbrick is an element of building used in building construction made from clay base material with or without other mixed materials. This research is a type of experimental research. The purpose of this study is to know and analyze the composition of the addition of corn bark ash and ash corn cob appropriately to produce the quality of bricks with high compressive strength, low water absorption, and large density. Additional materials in this study in the form of corn bark ash and ash corn cob. The quality of red bricks is seen from three aspects, namely compressive strength, water absorption, and density. The largest compressive strength was obtained in the addition of ash corn cob by 2.5% by 37.2 Kg/Cm2 and the compressive strength of 49.5 Kg/Cm2 on the addition of corn skin ash by 2.5%. Water absorption measurement of all types of red bricks the results of the study showed all the results of water absorption is not eligible sni. The highest density was obtained from a mixture of 2.5% ash corn cob material of 17.5 gr/Cm3. the best composition to produce bricks with strong compressive value and high density and have low water absorption is 2.5% addition of ash corn cob and the addition of 2.5% corn skin ash. Keywords: Red bricks, strong press, water absorption, density.


Author(s):  
Shwetha S

Abstract: Mining is a process of extraction of valuable minerals or geological substances from the earth; however, mining degrades the ecosystem. Earlier studies have discovered that about 10-15% of the ore mined is not utilized and discarded due to lack of cost-effective extraction technology for low graded ore in India. These soils cause environmental degradation as they do not support the growth of vegetation. Thus, the land becomes abandoned and fits for nothing. These soils have created an unsolved problem in mining industries. Bringing a solution to this issue is a challenging task. And it is necessary due to the presence of heavy metals in them. Concomitantly, there is a substantial demand for the construction materials. Due to increase in the population the need for shelter is increasing day by day. So, it is imperious to use these mining soils in building materials such as bricks, concrete blocks and other products which are of high value in day-to-day life. In the present study we attempt to prepare non modular bricks by using iron tailings or soils and clay soil. Here in this study we prepared different bricks varying their composition with respect to percentage of mine waste viz... 0,20,40,60,80, 100.The bricks made up 20%, 40%, 60% of mine soil replaced with the regular clay soil, attained compressive strength of 10.07MPa, 7.11MPa, 3.95MPa respectively with a water absorption of 14.57%, 15.61%, 18.44% respectively. So, mined soil which is unfertile and useless otherwise can answer sustainability by going for Brick making. Keywords: Mine soil, Bricks, compressive strength, water absorption


Buildings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 82
Author(s):  
Salmabanu Luhar ◽  
Demetris Nicolaides ◽  
Ismail Luhar

Even though, an innovative inorganic family of geopolymer concretes are eye-catching potential building materials, it is quite essential to comprehend the fire and thermal resistance of these structural materials at a very high temperature and also when experiencing fire with a view to make certain not only the safety and security of lives and properties but also to establish them as more sustainable edifice materials for future. The experimental and field observations of degree of cracking, spalling and loss of strength within the geopolymer concretes subsequent to exposure at elevated temperature and incidences of occurrences of disastrous fires extend an indication of their resistance against such severely catastrophic conditions. The impact of heat and fire on mechanical attributes viz., mechanical-compressive strength, flexural behavior, elastic modulus; durability—thermal shrinkage; chemical stability; the impact of thermal creep on compressive strength; and microstructure properties—XRD, FTIR, NMR, SEM as well as physico-chemical modifications of geopolymer composites subsequent to their exposures at elevated temperatures is reviewed in depth. The present scientific state-of-the-art review manuscript aimed to assess the fire and thermal resistance of geopolymer concrete along with its thermo-chemistry at a towering temperature in order to introduce this novel, most modern, user and eco-benign construction materials as potentially promising, sustainable, durable, thermal and fire-resistant building materials promoting their optimal and apposite applications for construction and infrastructure industries.


2018 ◽  
Vol 7 (2.29) ◽  
pp. 927 ◽  
Author(s):  
Bishir Kado ◽  
Shahrin Mohammad ◽  
Yeong Huei Lee ◽  
Poi Ngian Shek ◽  
Mariyana Aida Ab Kadir

Lightweight construction is aimed to achieve a sustainable feature by reducing transportation frequency and construction materials usage during construction phase. Lightweight precast concrete may serve an alternative for the lightweight construction. There are rarely application can be found for structural members as lightweight panels always to be used for secondary or non-load bearing members. This paper presents an experimental study on properties (compressive strength, splitting tensile strength, water absorption) of lightweight foamed concrete (LFC) at two different curing methods. LFC with densities of 1500, 1700, and 1800 kg/m3, cement-sand ratio of 2:1 and water-cement ratio of 0.5 were investigated. The results showed LFC can be produced with the properties ofdensity range of 1500 to 1800 kg/m3 and corresponding compressive strength of 10 to 39 MPa. The higher the density of LFC, the less the water absorption for all the curing method considered, the highest and the lowest water absorption was 11.3% and 2.0% for 1500 kg/m3 cured in water and 1800 kg/m3 cured in air respectively. Compressive strength of LFC increases with age and density while water cured LFC has high compressive strength. Splitting tensile strength increases with density of LFC, but air cured LFC has more splitting tensile strength than water cured of the same density. The highest splitting tensile strength recorded was 3.92 MPa for 1800 kg/m3 cured in air, which was about 16% of its compressive strength at 28 days of curing age. These properties are important and can be applied to LFC precast structural members with air or water curing method which have less references for LFC in structural usage.  


2020 ◽  
Vol 70 (6) ◽  
pp. 596-602
Author(s):  
P.K. Mehta ◽  
A. Kumaraswamy ◽  
V. K. Saraswat ◽  
Praveen Kumar B.

Utilisation of propellant waste in fabrication of bricks is not only used as efficient waste disposal method but also to get better functional properties. In the present study, high energy propellant (HEP) waste additive mixed with soil and fly ash in different proportions during manufacturing of bricks has been investigated experimentally. X-ray diffraction (XRD) studies were carried out to confirm the brick formation and the effect of HEP waste. Ceramic bricks were fabricated with HEP waste additive in proper proportions i.e. 0.5 wt %, 1.0 wt %, 1.5 wt %, 2.0 wt %, 2.5 wt %, 3 wt %, 3.5 wt %, and 4 wt % and then evaluated for water absorption capability and compressive strength. Compressive strength of 6.7 N/mm2, and Water absorption of 22 % have been observed from modified fired bricks impregnated with HEM waste additive. Scanning electron microscopy (SEM) studies were carried out to analyze the effect of HEP waste additive on pore formation and distribution in the bricks. Further, the heat resulting from decomposition of propellants can cause a decrease in the energy required of baking process. The process of manufacturing of bricks with HEP waste additive is first of its kind till date.


2020 ◽  
Vol 40 (2) ◽  
Author(s):  
Daniela Eugenia Angulo-Ramírez ◽  
William Gustavo Valencia-Saavedra ◽  
Ruby Mejía de Gutiérrez

Concretes based on alkaliactivated binders have attracted considerable attention as new alternative construction materials, which can substitute Portland Cement (OPC) in several applications. These binders are obtained through the chemical reaction between an alkaline activator and reactive aluminosilicate materials, also named precursors. Commonly used precursors are fly ash (FA), blast furnace slag (GBFS), and metakaolin. The present study evaluated properties such as compressive strength, rate of water absorption (sorptivity), and chloride permeability in two types of alkaliactivated concretes (AAC): FA/GBFS 80/20 and GBFS/OPC 80/20. OPC and GBFS/OPC* concretes without alkaliactivation were used as reference materials. The highest compressive strength was observed in the FA/GBFS concrete, which reported 26,1% greater strength compared to OPC concrete after 28 days of curing. The compressive strength of alkaliactivated FA/GBFS 80/20 and GBFS/OPC 80/20 was 61 MPa and 42 MPa at 360 days of curing, respectively. These AAC showed low permeability to the chloride ion and a reduced water absorption. It is concluded that these materials have suitable properties for various applications in the construction sector.


Cerâmica ◽  
2019 ◽  
Vol 65 (373) ◽  
pp. 153-161 ◽  
Author(s):  
H. M. Khater

Abstract Production of lightweight building materials attract the attention of the scientists worldwide with the need for reducing the structure deadweight, provide better thermal insulation for buildings, and cost less to transport. The current work focused on the production of lightweight geopolymer composites by the incorporation of aluminum powder and aluminum slag in various ratios for water-cooled slag/kaolinite sand composite; the activators used were 6% of equal ratio from sodium hydroxide and sodium silicate. The properties of the produced lightweight geopolymer composites were studied by measurement of compressive strength, bulk density, water absorption, FTIR, XRD and SEM imaging. Results showed the enhancement for both physicomechanical and microstructural characteristics with using aluminum powder and aluminum slag forming lightweight composites with densities below 2.15 g/cm3 depending on the studied mix composition.


2020 ◽  
Vol 853 ◽  
pp. 120-125
Author(s):  
Airvin John C. Palacio ◽  
Nioro G. Furiscal ◽  
Katrina Mae L. Abalos ◽  
Dioven Angelo A. Alferez ◽  
Edmer A. Bade ◽  
...  

Waste disposal is one of the issues that plague the society. Philippines is an agricultural country due to its strategic location in the tropics. Because of this nature, the agriculture sector tends to produce a huge amount of waste that if not disposed properly could pose a threat to the society and to the environment. With the advancement of technology, it has been a challenge for researchers to improve the quality of construction materials that is used in the industry. Studies have been performed on the possibilities of incorporating agricultural wastes to various construction materials as a form of waste diversion. In order to address the problem with agricultural wastes as well as to improve the property of construction materials, a study on coconut waste and eggshell waste was conducted as a constituent in concrete brick production. In this study, the density, compressive strength as well as the water absorption of concrete bricks with coconut charcoal powder (CCP) and eggshell powder (ESP) as replacement for fine aggregates and cement was conducted. Different mix ratios (0%, 2.5%, 5%, 10% CCP with a constant value of 5% ESP in each mix ratio) were carried out and the results were compared to a control sample. From the results of the density test, the concrete bricks with 5% CCP and 5% ESP was the lightest at a density of 1678.184 kg/m3, it also showed the least water absorption at 8.58% and exhibited the highest compressive strength at 17.5 MPa.


2021 ◽  
Vol 13 (22) ◽  
pp. 12741
Author(s):  
Nathália C. G. Silveira ◽  
Maysa L. F. Martins ◽  
Augusto C. S. Bezerra ◽  
Fernando G. S. Araújo

About 120 million tons of red mud is produced worldwide each year. Due to its high basicity and potential leaching, its storage is a critical environmental problem. This material is typically stored in dams, which demands prior care of the disposal area and includes monitoring and maintenance throughout its useful life. Consequently, it is crucial to figure out an industrial solution able to consumes large volumes of this material. At this moment, there are several studies, the majority in metallurgical procedures, building materials, and in the chemical industry, discussing how to reuse red mud. This paper provides a review of the aluminium process, including metal importance, its global production, and the environmental impact due to its manufacture process. It presents a review of the potential application of red mud showing its overall generation, some relevant characterisation results collected from the literature, and its utilisation in diverse areas of engineering. The study aimed to highlight applications where red mud characteristics may be favourable.


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