scholarly journals Analysis on the MSW thermal degradation processes

2013 ◽  
Vol 9 (1) ◽  
pp. 57-62

The waste to renewable energy source has become a priority in the wastes treatment field. The research goal is not only the wastes destruction but also a better thermal energy recovery from the processes. The municipal solid waste presents a high heterogeneity degree from the dimensional point of view, form and its components specific weight of as well as thermal-chemical characteristics. That’s why there are many treatment methods, each one with its own particularities. For a better understanding of the phenomenon during thermal degradation processes both under pyrolysis or atmospheric pressure gasification stages we first accomplished a laboratory scale series of experiments in a tubular reactor, on small quantities (5 – 10 grams) of reconstituted urban wastes. For the validation of the obtained data on more representative samples we extended the experiment to an original industrial scale pilot installation that enables the continuous thermal treatment of 10 – 50 waste kilograms per hour under oxidant or non-oxidant atmosphere (on choice) and at variable temperature between 400 °C – 1100 ºC. The residential time of the treated sample in the installation and the flow conditions can be set independently. The installation reproduces the incinerators or the pyrolysis / gasification reactor process conditions and provides complete information on the wastes thermal degradation kinetics and on the pollutant emissions. The particularity of the device consists in the product advancing piston – like flow system based on the bed vibration. The product particles in the bed have a translation movement without any layer shift. Therefore the particles distribution in a given product bed section is the same all along the installation from the feeding inlet to the extraction. That characteristic enables us to extrapolate and compare the laboratory results of the fixed bed treatment to the industrial pilot continuously treatment applied on the same product: reconstituted municipal solid waste, one of the most heterogynous solid wastes in mixture. The main targets were the sample mass reduction rate, the resulting gases composition, the samples mechanical behavior for different temperature levels, residential time, treatment atmosphere conditions and different steam flow rates (in the gasification process). The results were compared to an established reference – the incineration. The paper presents the research and results on the degradation mechanisms of MSW treated samples in those two equipments from the Science Division CNRS, Department of Industrial Methods, University of Technology Compiègne, France.

2020 ◽  
Vol 12 (21) ◽  
pp. 9086 ◽  
Author(s):  
Chen-Piao Yen ◽  
Song-Yan Zhou ◽  
Yun-Hwei Shen

The treatment and disposal of municipal solid waste incineration (MSWI) fly ash containing significant amounts of dissolvable salts and heavy metals is a seriously challenge. At present, the common treatment method for MSWI fly ash in Taiwan is the cement-based stabilization/solidification (S/S) process. In this work, an integrated hydrometallurgical process for the treatment of MSWI fly ash was evaluated. Ca was first recovered by combining water washing and ion exchange sequentially. Meanwhile, Zn in the water-washed fly ash was recovered by combining acid leaching and ion exchange sequentially. Combining the water washing efficiency of 30% on raw ash and the acid leaching efficiency of 40% on pre-washed ash, a total of 58% mass reduction rate of fly ash was achieved. In addition, an 80% Zn and 58% Ca recovery was achieved.


2013 ◽  
Vol 779-780 ◽  
pp. 1394-1397
Author(s):  
Jin Wei Jia ◽  
Xin Qian Shu ◽  
He Long Hui ◽  
Xing Min Fu ◽  
Shu Cheng Liu ◽  
...  

To investigate the effects of gangue on pyrolysis of municipal solid waste (MSW), pyrolysis of MSW with gangue has been conducted by TG and fixed-bed reactor, respectively. The effect of gangue on pyrolysis product yields and compositions of gaseous products was investigated and the obtained results were compared with similar experiments without gangue. It was shown that gangue can improve the pyrolytic reaction of MSW, reduce the char yield, increase the liquid yield. And influences of gangue on yields of H2, CO, CH4 and CO2 were more apparent, the yields of H2, CO and CO2 with gangue were improved 12.5%, 11.8% and 175%, respectively, conversely, the yield of CH4 was reduced 15.4% compared with no gangue.


2014 ◽  
Vol 1010-1012 ◽  
pp. 947-951
Author(s):  
Jin Wei Jia ◽  
Ming Yuan Lu ◽  
Yue Fu Yuan ◽  
Lu Liu ◽  
Feng Sheng Yang ◽  
...  

An experimental study on co-pyrolysis of municipal solid waste and corn stalk was performed in a fixed-bed reactor under atmospheric pressure. The effect of different blending ratio on the pyrolysis product yields and compositions of the gaseous products was investigated. The results indicated that there exist synergetic effects in the co-pyrolysis of municipal solid waste and corn stalk. Under the different blending ratio conditions, the char and liquid yields were lower than the theoretical values calculated on pyrolysis of each individual municipal solid waste and corn stalk, and consequently the gas yields were higher. H2 and CH4 obtained co-pyrolysis at 800°C-900°C of 40% blending ratio conditions were higher than those of municipal solid waste and corn stalk alone.


Author(s):  
Aiduan Li ◽  
Majeda Khraisheh

The emerging biofuel industry demands large amount of biomass feedstock. Although commercial ethanol has been produced from primary biomass sources such as corns, the global food crisis caused by the use of primary biomass has been raised. Thus, lignocellulosic biomass, known as second generation of biomass, has become a promising source for ethanol production. However, the more complex structure requires more advance technology. MSW with more than 60% of biodegradable composition, as one of the promising biomass sources has the potential benefits of replacing primary biomass and preventing environment from MSW pollution.In this paper, three major biodegradable municipal solid waste (BMSW) components: kitchen organic waste (KOW), green organic waste (GOW) and paper and card waste (PCW), are classified and characterised according to substrate composition, cellulose crystallinity, bulk density and particle size. The substrate composition indicates how much cellulose, lignin, hermicellulose each model waste has. The cellulose content shows the potential glucose/ethanol product yield. Other chemical composition such as lignin and hemicellulose indicates how easy of each model waste can be converted. These contents are also important information when selecting pretreatment methods and conversion process conditions in the following steps.Based on the comprehensive understanding of biomass structures and compositions, studies look into the effects of substrate properties (such crystallinity, presence of lignin and cellulose content on process performances during enzymatic hydrolysis adsorption. Results indicated how the adsorption process is affected by the substrate properties. This provides understanding of the role of substrate properties during enzyme-cellulose adsorption.


2010 ◽  
Vol 101 (16) ◽  
pp. 6517-6520 ◽  
Author(s):  
Siyi Luo ◽  
Bo Xiao ◽  
Zhiquan Hu ◽  
Shiming Liu ◽  
Yanwen Guan ◽  
...  

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