scholarly journals Rare earth elements as tracers for provenancing ancient ceramics

Author(s):  
M. Isabel Prudêncio ◽  
M. Isabel Dias ◽  
M. José Trindade ◽  
M. Amália Sequeira Braga

Clay analysis plays a crucial role in studies of ancient ceramics, contributing with answers to better understanding resource exploitation strategies, production technologies, and regional and interregional interaction patterns. The vessels are made essentially by clays, the composition of the ceramics reflectingthe origin of the clay materials used and conclusions may be inferred concerning the type of raw materials and the establishment of the geographic area of production. Different geochemical patterns found in clays from different geological contexts, consist on an important basis for the comparison with ceramics since the identification of the clays used for productions can contribute to delimit a potential area of clay resources and thus establishing provenance. This is particularly useful when no archaeological evidence of production exists. REE patterns are very important for the characterization of ceramic productions and their relation with raw materials, as subtle variations between them reflect differences in their relative behaviour in response to the chemical environment, making this group particularly useful in geochemistry studies. So, REE are crucial trace elements to pursue studies of raw materials and provenance establishment and trade routes reconstruction in ancient times. As terras raras como indicadores geoquímicos na proveniência de cerâmica antiga - O estudo das argilas assume um papel crucial na investigação de cerâmicas antigas, contribuindo para o esclarecimento e melhor compreensão de estratégias de exploração de recursos de matérias-primas, tecnologias de produção e padrões de interacção regional e inter-regional. Os recipientes cerâmicos são essencialmente constituídos por argilas, reflectindo a sua composição a origem dos materiais argilosos usados, podendo ser retiradas conclusões relativamente ao tipo de matérias-primas, bem como ao estabelecimento de áreas geográficas de produção. Os diversos padrões geoquímicos encontrados nas argilas provenientes de diferentes contextos geológicos, constituem uma importante base para a comparação com as cerâmicas, uma vez que a identificação das argilas usadas em certas produções, pode contribuir para a delimitação da potencial área fonte de argilas, estabelecendo-se assim a sua proveniência. Este facto é particularmente relevante quando não existe evidência arqueológica de produção. Os padrões de terras raras são muito importantes para a caracterização das produções cerâmicas e sua relação com as matérias-primas, uma vez que as variaçõessubtis que apresentam reflectem diferenças no seu comportamento em resposta ao sistema químico que as rodeiam, tornando este grupo particularmente útil em estudos de geoquímica. Deste modo, as terras raras são elementos traço cruciais em estudos de matérias-primas e no estabelecimento de proveniência de cerâmicas, contribuindo para a reconstrução de rotas comerciais em tempos antigos.

2019 ◽  
Vol 11 (15) ◽  
pp. 4229 ◽  
Author(s):  
Francesca Gambino ◽  
Alessandro Borghi ◽  
Anna d’Atri ◽  
Luca Martire ◽  
Martina Cavallo ◽  
...  

The study of ancient marble plays an important role in the interpretation of historical and archaeological sites and gives interesting information about building materials used in ancient times and their trade routes. The present work focuses on Chianocco marble that represents one of the most important ancient white marbles for cultural heritage exploited in the Piedmont region (Northwest Italy) and employed for the Palazzo Madama façade. A multi-analytical study based on petrographic (optical and scanning electron microscopy), electron microprobe, cathodoluminescence and stable isotope analyses was carried out on these marbles in order to perform an archaeometric study. Chianocco marble was used in Turin during the baroque era by the Savoy architect Filippo Juvarra (1678–1736) in historical buildings, such as the façade of the Palazzo Madama, the plinth of the façade of the town Cathedral and the columns (now plastered) of the portico of Piazza San Carlo. This stone is a dolomitic rock belonging to the Mesozoic cover of the Dora Maira Massif (Pennidic Unit). It shows a vuggy fabric characterized by a vacuolar texture due to tectonic brecciation and subsequent selective dissolution during subaerial exposure. This kind of research is useful to highlight the importance of the use of local stones as building materials and to investigate stone materials for the restoration and maintenance of historical buildings.


2019 ◽  
Vol 4 (11) ◽  
Author(s):  
Giacomo Eramo ◽  
Annarosa Mangone

Abstract Ceramics are among the most studied findings, one of the best markers for providing technological and functional information in archaeological contexts. Their chemical-mineralogical characterization allows to answer a large number of historical-archaeological questions about classification, provenance, production technologies, trade routes, economic exchange, etc. The best methodological approach not only integrates morphological-stylistic studies to the archaeometric ones, but also includes a synergic instrumental strategy aimed both to take advantage of each different analytical technique to the best of its potentiality and to over step the problems connected to the preciousness and uniqueness of the objects. As far as the mineralogical and petrographical composition of preindustrial ceramics is concerned, its determination is crucial to answer provenance and technological issues like raw materials procurement and the production processes in this respect, equivalent firing temperature, redox atmosphere during firing are important factors that help in understanding the relevant mineralogical and micro-structural transformations. In this paper, we illustrate how an integrated approach of analytical techniques, tested on different classes of ceramics – pottery with spathic calcite, Apulian red figure pottery and technical ceramics – can provide answers to archaeological questions.


2014 ◽  
Vol 6 (2) ◽  
pp. 1
Author(s):  
Saibatul Hamdi

The purpose of this research is to know the mechanical strength of gypsum board by utilizing waste sawn wood. Raw materials used consist of flour, gypsum,wood particles, boraks and kambang (Goniothalamus sp), wood tarap (Artocarpus elasticus REINW) and lua (Ficus glomerata ROXB). Wood particle 40 mesh and 60 mesh, concentrations boraks of 1 and 2 and the percentage particles of gypsum sawn timber is 300, 400 and 500%. The results showed that the average value Modulus of Rufture (MoR) in lua wood ranges from 12.55 – 14,47 kgcm2, wood kambang 25.10-31,11 kgcm2 and wood tarap 19.20- 24,18 kgcm2. As for Modulus of Elasticity (MoE) on the lua 1129,80- 2092,70 kgcm2, wood kambang 2512,37-3971,32 kgcm2 and tarap 2050,63-2691,09 kgcm2. Gypsum board are mechanical properties do not meet quality standards created SNI 03-6434-2000.Keywords: sawdust, lua, kambang, tarap, gypsum, mechanical


Author(s):  
Chernichkina A.D.

A large number of biologically active substances, organic acids, tannins, and pectin substances were detected during the study of fruits, leaves, and pulp of the fruits of mountain Ash. The content of these substances in leaves and pulp will significantly expand the arsenal of medicinal plant raw materials used. Given the wide distribution of mountain Ash in the territory of the Russian Federation, harvesting leaves from the same plants after harvesting the fruit and using pulp will make it possible to obtain new phytopreparations.


Food Industry ◽  
2020 ◽  
Vol 5 (2) ◽  
pp. 71-78
Author(s):  
Ekaterina Minnikhanova ◽  
Nataliya Zavorokhina ◽  
Anna Gilina

Abstract The inclusion of polysaccharide thickeners in the recipes of sweet dishes increases the functional reserves of the body, contributes to the preservation of health and the prevention of diseases. The purpose of the research is to study the sensory characteristics of polysaccharides of various nature when combined with food acids, to develop a recipe for a basic mixture of low-calorie meals for public catering. The authors analyzed citric, lactic and succinic acids in combinations with polysaccharides of various nature. Organoleptic tests were evaluated by a touch panel. The organization of the tasting analysis corresponded to GOST ISO 6658-2016; the consistency was determined according to GOST 31986-2012, GOST ISO 11036-2017, GOST ISO 8588-2011. The optimal organoleptic combinations of the presented food acids and complex additives of sweeteners (CDP) were identified, which included aspartame, sodium saccharinate, Sucralose, sweetness coefficient – 340: the mixture with citric acid had a long pleasant aftertaste without foreign tastes and the best taste characteristics. Using the “A-not A” method, we found that the sample with the addition of CDP is identical to the sucrose solution. In the second part of the study, polysaccharides were added to model samples of acids with complex sweeteners; the best sensory characteristics were obtained by model samples consisting of a mixture of low-esterified Apple pectin with lactic acid and KDP. The technology of obtaining a stable elastic jelly using low-esterified Apple pectin has been developed, since the complex mixture of sweeteners and food acids does not have a dehydrating effect. Developed a dry mix recipe that can serve as a basic development, low-calorie sweet products for catering and has a variance of use of lactic and succinic acids, depending on the flavor characteristics of the raw materials used and its corrective ability.


2020 ◽  
Vol 4 (2) ◽  
Author(s):  
Ivan Yulianto ◽  
Ario Seno Nugroho

An alternative strategy to reduce the trade balance deficit simultaneously to increase the net foreign exchange is the import-substitution for raw materials used to produce an export goods. This paper proposes an import substitution study on footwear products that have a dependency on imported raw materials by 70 percent, with the largest composition being leather raw materials by 67 percent. This paper analyzes the relationship between subsidies on the leather industry to leather import-substitution, multiplier effect to footwear sector, and Indonesia trade balance. Author make use of simulation the on Input-Output 2010 table and Computable General Equilibrium (CGE) Model. The simulation shows 100 billion subsidies on the leather sector, lead for the substitution-import of leather by 7,94 million rupiah, increase the net export foreign exchange by 1.1 billion rupiah of the footwear sector, and for overall, increase Indonesia trade balance deficit by 68 billion rupiah. Keywords: Computable General Equilibrium, footwear, leather, net foreign exchange, subsidy.ABSTRAK: Salah satu terobosan untuk mengurangi defisit neraca perdagangan dan meningkatkan nilai neto devisa ekspor adalah dengan substitusi impor bahan baku yang digunakan untuk memproduksi barang ekspor. Paper ini mengusulkan kajian substitusi impor pada produk alas kaki yang mempunyai ketergantungan bahan baku impornya sebesar 70 persen, dengan komposisi terbesar adalah bahan baku kulit sebesar 67 persen. Tujuan penelitian ini adalah untuk mengetahui dampak stimulus subsidi pada industri kulit terhadap subtitusi impor kulit, dukungan multiplier sektor kulit terhadap sektor alas kaki, serta terhadap devisa ekspor Indonesia. Penelitian ini menggunakan simulasi model Computable General Equilibrium (CGE). Hasil simulasi menunjukkan stimulus subsidi sebesar 100 milyar rupiah pada sektor kulit memberikan substitusi bahan baku kulit sebesar 7,94 juta rupiah, menaikkan devisa ekspor sektor alas kaki sebesar 1.1 miliar rupiah, serta secara keseluruhan menambah defisit neraca berjalan Indonesia sebesar 68 miliar rupiah. Kata kunci: alas kaki, Computable General Equilibrium (CGE), devisa ekspor, kulit, subsidi.


2012 ◽  
Vol 7 (4) ◽  
Author(s):  
Norikazu Sugaya

This new surface treatment is simple and easy as well as low in cost. The processes can even be performed by hand. Pharmaceutical raw materials used for the surface treatment, such as hydrochloric acid and nitric acid used in a mixed acid washing process and vegetable oil used in an organic film forming process, are easily obtained in many countries.


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.


2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Lino Bianco

AbstractRuins are a statement on the building materials used and the construction method employed. Casa Ippolito, now in ruins, is typical of 17th-century Maltese aristocratic country residences. It represents an illustration of secondary or anthropogenic geodiversity. This paper scrutinises these ruins as a primary source in reconstructing the building’s architecture. The methodology involved on-site geographical surveying, including visual inspection and non-invasive tests, a geological survey of the local lithostratigraphy, and examination of notarial deeds and secondary sources to support findings about the building’s history as read from its ruins. An unmanned aerial vehicle was used to digitally record the parlous state of the architectural structure and karsten tubes were used to quantify the surface porosity of the limestone. The results are expressed from four perspectives. The anatomy of Casa Ippolito, as revealed in its ruins, provides a cross-section of its building history and shows two distinct phases in its construction. The tissue of Casa Ippolito—the building elements and materials—speaks of the knowledge of raw materials and their properties among the builders who worked on both phases. The architectural history of Casa Ippolito reveals how it supported its inhabitants’ wellbeing in terms of shelter, water and food. Finally, the ruins in their present state bring to the fore the site’s potential for cultural tourism. This case study aims to show that such ruins are not just geocultural remains of historical built fabric. They are open wounds in the built structure; they underpin the anatomy of the building and support insights into its former dynamics. Ruins offer an essay in material culture and building physics. Architectural ruins of masonry structures are anthropogenic discourse rendered in stone which facilitate not only the reconstruction of spaces but also places for human users; they are a statement on the wellbeing of humanity throughout history.


2021 ◽  
Vol 11 (10) ◽  
pp. 4392
Author(s):  
Apolka Ujj ◽  
Kinga Percsi ◽  
Andras Beres ◽  
Laszlo Aleksza ◽  
Fernanda Ramos Diaz ◽  
...  

The use and quality analysis of household compost have become very important issues in recent years due to the increasing interest in local food production and safe, self-produced food. The phenomenon was further exacerbated by the COVID-19 pandemic quarantine period, which gave new impetus to the growth of small home gardens. However, the knowledge associated with making high-quality compost is often lacking in home gardeners. Therefore, the objective of this research was to find answers to the following questions: can the quality of backyard compost be considered safe in terms of toxicity and nutrient content? Can weed seed dispersion affect the usability of backyard compost? In general, can the circulation of organic matter be increased with the spread of home composting? In this study, 16 different house composts were analysed for stability, weed seed contamination, toxic elements, and nutrient content using analysis of variance. The results of the research showed that the quality properties of the composts (including their weed seed dispersion effect) were greatly influenced by the different techniques and raw materials used. The toxicity levels, as well as the content of macro and microelements, were within the parameters of safe-quality compost. The specific macronutrient (Ca, Mg) and micronutrient (Fe, Mn) contents of the tested composts have a similar and, in some cases, more favorable nutrient supply capacity in crop production than the frequently-used cow manure-based composts. With a plan of basic education on composting, there is potential to encourage farmyard composting.


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