scholarly journals Investigation of copper(I) sulphide leaching in oxidative hydrochloric acid solution

10.30544/71 ◽  
2015 ◽  
Vol 21 (4) ◽  
pp. 253-258 ◽  
Author(s):  
Branislav Marković ◽  
Miroslav Sokić ◽  
Željko Kamberović ◽  
Dragana Živković ◽  
Nada Štrbac ◽  
...  

Present work is focused on the copper (I) sulphide leaching with sodium chloride in hydrochloric acid solution and with introduction of gaseous oxygen. Chemical reactions of leaching and their thermodynamic probabilities are predicted based on the literature data and products which were formed during the process and the overall leaching reaction was defined. The influence of temperature and time on the leaching degree of copper was experimentally determined. The quantity of dissolved copper increases with the increase of both investigated parameters. Elemental sulphur was formed as the main leaching product, precipitated at the particle surfaces and chloride ions have a role to disrupt the creation of this passive layer.

2010 ◽  
Vol 61 (9) ◽  
pp. 783-789 ◽  
Author(s):  
G. S Peng ◽  
K. H. Chen ◽  
H. C. Fang ◽  
H. Chao ◽  
S. Y. Chen

1975 ◽  
Vol 28 (9) ◽  
pp. 1901 ◽  
Author(s):  
SF Lincoln ◽  
AC Sandercock ◽  
DR Stranks

The parameters describing chloride exchange on indium(III), determined by 35Cl N.M.R., are: k(298 K)= (8.8�0+4) x 106 s-1, ΔH? = 45.7�2.3 kJ mol-1 and ΔS? = 42�8 J mol-1 K-1; and k(298 K)= (2.0�0.1)x106 s-1, ΔH? = 37.7�1.9 kJ mol-1, and ΔS? = 3�6 J mol-1 K-1 in 10.95M and 7.00M aqueous hydrochloric acid respectively, calculated from the observed exchange rate kex4[InCl4(H2O)2-].��� For thallium(III) lower limits of kex(219 K) = 1.6 x 106 s-1 and 1.3 x 106 s-1 were obtained in 10.95M and 7.00M aqueous hydrochloric acid, respectively, where [TlCl6]3- is assumed to be the exchanging species.


RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24576-24588 ◽  
Author(s):  
H. S. Gadow ◽  
M. M. Motawea

The inhibitive effect and adsorption behavior of ginger roots extract (GRE) on the corrosion of carbon steel in 1.0 M HCl solution at different temperatures were investigated.


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