scholarly journals Investigation of solidification behavior of the Sn-rich ternary Sn–Bi–Zn alloys

10.30544/259 ◽  
2017 ◽  
Vol 23 (1) ◽  
pp. 11-20
Author(s):  
S Mladenović ◽  
D Manasijević ◽  
M Gorgievski ◽  
D Minić ◽  
Silvana Branislav Dimitrijević
Keyword(s):  
Electron Microscopy ◽  
Phase Diagram ◽  
Scanning Electron Microscopy ◽  
Calphad Method ◽  
Solidification Behavior ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Solidification Simulation ◽  
Zn Alloys ◽  
Scanning Electron

Solidification properties and microstructure of six as-cast Sn–Bi–Zn alloys with 80 at.% of Sn and variable contents of Bi and Zn were experimentally investigated using the scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) and differential scanning calorimetry (DSC). The experimentally obtained results were compared with predicted phase equilibria according to the calculation of phase diagram (CALPHAD) method and by the Scheil solidification simulation. 

Research on compatibility and surface of high impact bio-based polyamide

2021 ◽  
pp. 095400832110055
Author(s):  
Yang Wang ◽  
Yuhui Zhang ◽  
Yuhan Xu ◽  
Xiucai Liu ◽  
Weihong Guo
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Crystallization Behavior ◽  
High Impact ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

The super-tough bio-based nylon was prepared by melt extrusion. In order to improve the compatibility between bio-based nylon and elastomer, the elastomer POE was grafted with maleic anhydride. Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA) were used to study the compatibility and micro-distribution between super-tough bio-based nylon and toughened elastomers. The results of mechanical strength experiments show that the 20% content of POE-g-MAH has the best toughening effect. After toughening, the toughness of the super-tough nylon was significantly improved. The notched impact strength was 88 kJ/m2 increasing by 1700%, which was in line with the industrial super-tough nylon. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) were used to study the crystallization behavior of bio-based PA56, and the effect of bio-based PA56 with high crystallinity on mechanical properties was analyzed from the microstructure.

Study of an Energetic-oxidant Co-crystal: Preparation, Characterisation, and Crystallisation Mechanism

2017 ◽  
Vol 67 (5) ◽  
pp. 510 ◽  
Author(s):  
Han Gao ◽  
Wei Jiang ◽  
Jie Liu ◽  
Gazi Hao ◽  
Lei Xiao ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Diffraction Spectrum ◽  
Solvent Evaporation Method ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

<p>An energetic co-crystal consisting of the most promising military explosive 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and the most well-known oxidant applied in propellants ammonium perchlorate has been prepared with a simple solvent evaporation method. Scanning electron microscopy revealed that the morphology of co-crystal differs greatly from each component. The X-ray diffraction spectrum, FTIR, Raman spectra, and differential scanning calorimetry characterisation further prove the formation of the co-crystal. The result of determination of hygroscopic rate indicated the hygroscopicity was effectively reduced. At last, the crystallisation mechanism has been discussed.</p>

An Al13Co4 phase in the Al–Cu–Co alloy system

1992 ◽  
Vol 7 (5) ◽  
pp. 1100-1103 ◽  
Author(s):  
B. Grushko ◽  
Ch. Freiburg
Keyword(s):  
Electron Microscopy ◽  
Phase Diagram ◽  
Scanning Electron Microscopy ◽  
Liquid Phase ◽  
Alloy System ◽  
Homogeneity Region ◽  
X Ray ◽  
Decagonal Phase ◽  
Scanning Electron

A part of the Al–Cu–Co phase diagram adjacent to the Al13Co4 composition was studied at 800 °C by scanning electron microscopy and x-ray diffractometry. The homogeneity region of the Al13Co4 phase was found to extend up to 6 at. % Cu. At 800 °C this phase is in equilibrium with Al(Co, Cu), Al5Co2, Al9Co2, the decagonal phase, and a liquid phase. The existence of the Y-phase and Al3Co was not confirmed at this temperature.

Hydriding Behaviour of Mg-C Nanocomposites

2003 ◽  
Vol 801 ◽  
Author(s):  
A. Bassetti ◽  
E. Bonetti ◽  
A. L. Fiorini ◽  
J. Grbovic ◽  
A. Montone ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Weight Ratio ◽  
Hydrogen Desorption ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Carbon Nanocomposites ◽  
X Ray ◽  
Scanning Electron

ABSTRACTMagnesium carbon nanocomposites for hydrogen storage have been synthesized by ball milling with different amount of benzene, acting as a lubricant. Their microstructure has been studied by X-ray diffraction and scanning electron microscopy, while the hydrogen desorption temperature has been tested by differential scanning calorimetry. Experimental results show that the microstructure after milling, the hydrogenation capabilities of the material and the reactivity with the air are related to the amount of additives. In particular the carbon to benzene ratio seems to play a major role. In fact, with an optimum value of carbon to benzene weight ratio of 1/6, the amount of carbon being 15 wt% of the milled mixture, a decomposition heat equal to 57% of pure MgH2 was measured, even after air manipulation of the sample.

Processing of Biodegradable Polymer Composite Using Soy Protein-Based Resin and Nanoclay

2016 ◽  
Author(s):  
Mohammad K. Hossain ◽  
Samira N. Shaily ◽  
Hadiya J. Harrigan ◽  
Terrie Mickens
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Optical Microscopy ◽  
Soy Protein ◽  
Poly Vinyl Alcohol ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

A completely biodegradable composite was fabricated from an herbal polymer, soy protein concentrate (SPC) resin. Soy protein was modified by adding 30 wt% of glycerol and 5 wt% of poly vinyl alcohol (PVA) to enhance its mechanical as well as thermal property. 3%, 5%, 10%, and 20% nanoclay (NC) were infused into the system. To evaluate its mechanical properties, crystallinity, thermal properties, bonding interaction, and morphological evaluation, tensile, X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR) tests, and optical microscopy (OM) and scanning electron microscopy (SEM) evaluation were performed. Tensile tests showed that the addition of nanoclay improved the mechanical properties of the modified resin. Soy protein is hydrophilic due to the presence of amino acids that contain various polar groups such as amine, carboxyl, and hydroxyl. As a result, polar nanoclay particles that are exfoliated can be evenly dispersed in the SPC resin. From experimental results, it is clear that adding of nanoclay with SPC resin significantly increased the stiffness of the SPC resin. A combination of 5% clay, 30% glycerol, and 5% PVA with the modified SPC resulted in the maximum stress of 18 MPa and Young modulus of 958 MPa. The modified SPC showed a reduced failure strain as well. X-ray diffraction curves showed an improvement of crystallinity of the prepared resin with increasing amount of nanoclay. Interaction among soy, glycerol, PVA, and nanoclay was clearly demonstrated from the FTIR analysis. Optical microscopy (OM) and scanning electron microscopy (SEM) micrographs revealed rougher surface in the nanoclay infused SPC samples compared to that of the neat one. SEM evaluation revealed rougher fracture surface in the NC infused samples.

scholarly journals Synthesis and characterization of graphene oxide flakes for transparent thin films

2021 ◽  
Vol 22 (3) ◽  
pp. 595-601
Author(s):  
R.G. Abaszade ◽  
S.A. Mamedova ◽  
F.G. Agayev ◽  
S.I. Budzulyak ◽  
O.A. Kapush ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Graphene Oxide ◽  
Indium Tin Oxide ◽  
Electromagnetic Interference ◽  
Large Scale ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

We have synthesized large scale, thin, transparent graphene oxide (GO) flakes by Hummer’s method and investigated their suitability for fabrication of transparent nanocomposites. The GO flakes were comprehensively characterized by X-ray diffraction, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray analysis (EDX), Raman spectroscopy and Differential Scanning Calorimetry (DSC). X-ray diffraction displayed the peak of graphene oxide at 9°degree, which is characteristic peak of GO in agreement with the literature results. Scanning Electron Microscopy images revealed that thin, transparent, flake form GO with 14,8 µm lateral size and 0,31µm thickness were synthesized. The comparison with literature results show that for the first time, our group could synthesize large scale, thin and more transparent GO flakes by simple Hummer’s method using simple dispersed graphite. EDX measurements indicate the formation of layered structure with oxygen containing functional groups. The intensity ratio between D and G peaks in the Raman spectra proves that less defective GO flakes have been synthesized. The solution ability of the synthesized material indicate that high quality GO flakes were synthesized, which make them effective soluble material due to oxygen containing groups formed on the graphene plane during synthesis process.DSC results shows that these flakes are thermally stable till 200°C.  Due to high solubility properties, large scale and transparency they can be very useful in fabrication of high optical transparent nanocompoties for replacement indium tin oxide transparent conductors in solar panels, biomedical applications and microwave absorbers for electromagnetic interference (EMI) environmental protection.

scholarly journals Studi Metode Pendinginan Super Cepat untuk Pembentukan Bulk Metallic Glasses pada Paduan Cu45Zr45Al5Ag5

2019 ◽  
Vol 3 (2) ◽  
pp. 10-17
Author(s):  
Andromeda Dwi Laksono ◽  
Rifqi Aulia Tanjung
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Metallic Glasses ◽  
Electron Probe ◽  
Bulk Metallic Glasses ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Energy Dispersion Spectrometer ◽  
Scanning Electron

Bulk Metallic Glass (BMG) memiliki sifat mekanik, magnetik, kimia dan fisik yang berbeda dengan paduan polikristalin karena susunan internal atomnya yang tidak teratur. Sehingga, BMG memiliki kekuatan mekanik yang baik, kekerasan yang tinggi, ketahanan terhadap aus dan korosi yang tinggi, dan kehalusan permukaan yang baik. Berdasarkan sifat tersebut, BMG memiliki kelayakan yang menjanjikan di bidang industry. Dalam penelitian ini, metode pengecoran cetakan di tembaga digunakan untuk menyiapkan BMG paduan Cu45Zr45Al5Ag5. Paduan dileburkan ulang dengan pendinginan super cepat menggunakan mesin pendingin di bawah temperatur -25 oC. Dengan metode pengecoran cetakan di tembaga, sampel ukuran besar berbentuk batang dipotong dengan diameter 2 mm hingga 4 mm dan panjang 30 mm. Batang kemudian dipotong lagi menjadi spesimen berbentuk cakram. Untuk memastikan apakah sampel adalah BMG atau tidak, sampel dievaluasi dengan Scanning Electron Microscopy (SEM), Energy Dispersion Spectrometer (EDS), Differential Scanning Calorimetry (DSC), Electron Probe X-ray Micro Analyzer (EPMA), dan X -ray Difraction (XRD). Hasilnya dibahas dalam penelitian ini. Kata Kunci: Bulk Metallic Glasses, Cu45Zr45Al5Ag5, Pengecoran Cetakan di Tembaga.

Intermetallic Alloys Ni3Si and Ni3(Si,Ti): Microstructures and Properties

2008 ◽  
Vol 368-372 ◽  
pp. 1143-1145 ◽  
Author(s):  
Ding Fan ◽  
Yao Ning Sun ◽  
Min Zheng ◽  
Jian Bin Zhang ◽  
Yu Feng Zheng
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Continuous Wave ◽  
Chemical Compositions ◽  
Intermetallic Alloys ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

Laser cladding experiment was carried out with a 5 kW continuous wave CO2 laser by preplacing Ni75Si25 and Ni78Si13Ti9 powders onto Ni-based superalloy substrate. The microstructure of the specimens was monitored by using optical and scanning electron microscopy. The chemical compositions of the alloys and their phases were obtained using X-ray diffraction and energy dispersive x-ray spectroscopy. The phase transformation temperatures were determined by non-isothermal differential scanning calorimetry tests. The microhardness of the laser cladded sample was measured.

scholarly journals ENHANCEMENT OF LORNOXICAM SOLUBILITY BY INCLUSION COMPLEXATION WITH CYCLODEXTRIN: PREPARATION AND CHARACTERIZATION

2016 ◽  
Vol 9 (1) ◽  
pp. 132 ◽  
Author(s):  
Shahira Fawzy El-menshawe ◽  
Essam Eissa ◽  
Adel A. Ali ◽  
Ahmed A. Abderhman
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Freeze Drying ◽  
Inclusion Complexation ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Physical Mixing ◽  
Solid Complexes ◽  
Scanning Electron

<p><strong>Objective: </strong>Lornoxicam is a potent anti-inflammatory drug which has analgesic and antipyretic properties. It is water-insoluble powder. The inclusion complexes of lornoxicam (LOR) with β-cyclodextrin (βCD) and 2-hydroxypropyl-β-cyclodextrin (HPCD) were prepared and characterised in order to improve the solubility of the drug and enhance its bioavailability.</p><p><strong>Methods: </strong>Complexes were prepared by physical mixing and freeze-drying in three different drug/polymer ratios (1:1, 1:2 and 3:2). The solid complexes were characterised through differential scanning calorimetry (DSC), scanning electron microscopy (SEM), X-ray diffraction, nuclear magnetic resonance (NMR) spectroscopy, and Fourier transformed infrared (FTIR) spectroscopy.</p><p><strong>Results: </strong>The data showed that LOR may be complexed with cyclodextrin (CD) forming soluble complexes. The lyophilized 1:2 LOR/HPCD complex is the most soluble.</p><p><strong>Conclusion: </strong>Solubility increases with lyophilization than with physical mixing and by the use of HPCD than βCD in complexation.</p>

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