scholarly journals Perhitungan laju korosi dan perancangan sistem proteksi katodik anoda korban di lambung kapal tugboat Bontang o4 PT Badak NGL Bontang

2017 ◽  
Vol 7 (2) ◽  
Author(s):  
R.A. Saputra ◽  
P.D. Setyawan ◽  
S. Sugiman ◽  
A. Zainuri

Corrosion happens differently for each point of hull plate which caused of corrosion rate differences. So that is very important to measure it for each point, which is calculated using Weight Gain Loss Method. The measurement of plate thickness that used is Ultrasonic Test Method conducted by PT BKI. To determine the condition of ship protection, then the coating and sacrificial anode system is evaluated by testing the composition and current and voltage of anode as well. Furthermore, the number and position of anode is also analyzed. So that the re-design of cathode protection is needed by referring to the PT BKI’s standards. Then the prediction of corrosion rate is calculated by using the design of cathode protection. The largest corrosion rates are in the amidships and portside for each plate lane, they are on the keel plate point K3 is 0.37 mm/years, pedestal plate point A4 is 1.05 mm/years, bilge plate point B4 is 0.62 mm/years and side plate point C5 is 0.39 mm/years. But the number of installed anode is 31 anodes with an irregular position. So in this study, done the redesign system of cathode protection based on regulations issued by PT BKI, with the result of the number of the anode is 56 units. Using the design, then carried a prediction by the result is lower, that on the keel plate is 0.073 mm/years, pedestal plate is 0.021 mm/years, bilge plate is 0.013 mm/years and the side plate is 0.014 mm/years.

2019 ◽  
Vol 121 ◽  
pp. 01008
Author(s):  
Mark Kovalev ◽  
Ekaterina Alekseeva ◽  
Nikita Shaposhnikov ◽  
Anton Povyshev

Galvanizing is one of the most common methods of corrosion protection. For the deposition of zinc coatings used such methods as gas-thermal deposition, thermal diffusion saturation in powder, hot-dip galvanizing, cladding, and galvanic precipitating during electrolysis. The hot-dip galvanizing is the most common method, which is used in construction, automotive and other industries. Paper presents the results of research of zinc coatings used in sea conditions. The aim of the work was to determine an acceleration factor by comparing the corrosion rate in laboratory conditions with the data from field tests. Laboratory studies were carried out in a salt fog chamber. Samples were periodically removed from chamber to build the dependence of the corrosion rate on the exposure time. Field tests were carried out at the exploitation area. Result of the work is a guide that allows to predict the corrosion rates of zinc coatings using laboratory tests. The advantage of this test method is shorter time of exposure in comparison with field test.


2013 ◽  
Vol 318 ◽  
pp. 312-315
Author(s):  
Xiong Yang ◽  
Jian Tong ◽  
Xiao Ming Li

The effects of concentration and temperature of hydrochloric acid and etching time on the corrosion rates of 434 stainless steel fibres are investigated by using weight loss method,The results show that with the concentration of hydrochloric acid increase,the temperature of hydrochloric acid rise, etching time prolonging, the corrosion rate of 434 stainless steel fibres is increased, and the corrosion rate of smalldimension of 434 stainless steel fibres faster.Though Cl- of hydrochloric acid doesn’t take direct part in the reaction,the corrosion rate is significantly accelerated.


1985 ◽  
Vol 38 (8) ◽  
pp. 1133 ◽  
Author(s):  
BG Pound ◽  
MH Abdurrahman ◽  
MP Glucina ◽  
GA Wright ◽  
RM Sharp

The corrosion rates of low-carbon steel, and 304, 316 and 410/420 stainless steels in simulated geothermal media containing hydrogen sulfide have been measured by means of the polarization resistance technique. Good agreement was found between weight-loss and polarization resistance measurements of the corrosion rate for all the metals tested. Carbon steel formed a non-adherent film of mackinawite (Fe1 + xS). The lack of protection afforded to the steel by the film resulted in an approximately constant corrosion rate. The stainless steels also exhibited corrosion rates that were independent of time. However, the 410 and 420 alloys formed an adherent film consisting mainly of troilite ( FeS ) which provided only limited passivity. In contrast, the 304 and 316 alloys appeared to be essentially protected by a passive film which did not seem to involve an iron sulfide phase. However, all the stainless steels, particularly the 410 and 420 alloys, showed pitting, which indicated that some breakdown of the passive films occurred.


2014 ◽  
Vol 1665 ◽  
pp. 195-202 ◽  
Author(s):  
Osamu Kato ◽  
Hiromi Tanabe ◽  
Tomofumi Sakuragi ◽  
Tsutomu Nishimura ◽  
Tsuyoshi Tateishi

ABSTRACTCorrosion behavior is a key issue in the assessment of disposal performance for activated waste such as spent fuel assemblies (i.e., hulls and end-pieces) because corrosion is expected to initiate radionuclide (e.g., C-14) leaching from such waste. Because the anticipated corrosion rate is extremely low, understanding and modeling Zircaloy (Zry) corrosion behavior under geological disposal conditions is important in predicting very long-term corrosion. Corrosion models applicable in the higher temperature ranges of nuclear reactors have been proposed based on considerable testing in the 523−633 K temperature range.In this study, corrosion tests were carried out to confirm the applicability of such existing models to the low temperature range of geological disposal, and to examine the influence of material, environmental, and other factors on corrosion rates under geological disposal conditions. A characterization analysis of the generated oxide film was also performed.To confirm applicability, the corrosion rate of Zry-4 in pure water with a temperature change from 303 K to 433 K was obtained using a hydrogen measuring technique, giving a corrosion rate for 180 days of 8 × 10-3 μm/y at 303 K.To investigate the influence of various factors, corrosion tests were carried out. The corrosion rates for Zry-2 and Zry-4 were almost same, and increased with a temperature increase from 303 K to 353 K. The influence of pH (12.5) compared with pure water was about 1.4 at 180 days at 303 K.


2018 ◽  
Vol 7 (2.14) ◽  
pp. 512 ◽  
Author(s):  
Olawale Ajibola ◽  
Oladeji Ige ◽  
Peter Olubambi

The twofold impact of wear and corrosion on wrought A6061 alloy in hydraulic DOT3 brake fluid environment was studied. The wear studies were performed on the samples using a developed wear-jig. Weight loss corrosion test method was used to determine the corrosion rate of the wrought A6061 alloy samples immersed in the brake fluid for a total of 1680 hours. From the results of wear tests carried out on the A6061 alloy sample with brake oil, the highest wear value of 5.24x10-7 mg/mm2/cycle (approx.) was obtained from 6 N (approx) force after 130 minutes. The wrought A6061 alloy material demonstrated the highest corrosion rates nearly 3.0 x10-2 mg/mm2/yr within the early 168 hours of immersion in brake fluid. The result is practically lower than the corrosion rate of cast specimen in DOT3 brake oil or some other alloys immersed in other corrosive media that were previously reported in the literature. The results show that small amount of chemical corrosion is sufficient to cause and accelerate mechanical wear of the material in usage.


1970 ◽  
Vol 9 (9) ◽  
pp. 39-43
Author(s):  
Basu Ram Aryal ◽  
Jagadeesh Bhattarai

Simultaneous additions of tungsten, chromium and zirconium in the chromium- and zirconium-enriched sputter-deposited binary W-xCr and W-yZr are effective to improve the corrosion resistance property of the ternary amorphous W- xCr-yZr alloys after immersion for 240 h in 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter-deposited (10-57)W-(18-42)Cr-(25-73)Zr alloys is higher than those of alloy-constituting elements (that is, tungsten, chromium and zirconium) in aggressive 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter−deposited W–xCr–yZr alloys containing 10-57 at% tungsten, 18-42 at% chromium and 25-73 at% zirconium were in the range of 1.5-2.5 × 10−3 mm/y or lower which are more than two orders of magnitude lower than that of sputter-deposited tungsten and even about one order of magnitude lower than those of the sputter-deposited zirconium in 1 M NaOH solution. Keywords: Ternary W–Cr–Zr alloys; Amorphous; Corrosion rate; Open circuit potential; 1 M NaOH. DOI: http://dx.doi.org/10.3126/sw.v9i9.5516 SW 2011; 9(9): 39-43


2002 ◽  
Vol 67 (11) ◽  
pp. 777-782 ◽  
Author(s):  
Dragutin Drazic ◽  
Jovan Popic

By combining electrochemical corrosion rate measurements and spectrophotometric analysis of the electrolyte it was shown that at room temperature chromium dissolves in deaerated 0.1M Na2SO4 + H2SO4 (pH1) solution as Cr(II) and Cr(III) ions in he ratio Cr(II):Cr(III)?7:1. This process was stable over 4h without any detectable change. The total corrosion rate of chromium calculated from the analytical data is about 12 times higher, than that determined electrochemically by cathodic Tafel line extrapolation to the corrosion potential. This finding was confirmed by applying the weight-loss method for the determination of the corrosion rate. This enormous difference between these experimentally determined corrosion rates can be explained by the rather fast, "anomalous" dissolution process proposed by Kolotyrkin and coworkers (chemical reaction of Cr with H2O molecules) occurring simultaneously with the electrochemical corrosion process.


2021 ◽  
Vol 1201 (1) ◽  
pp. 012079
Author(s):  
S B Gjertsen ◽  
A Palencsar ◽  
M Seiersten ◽  
T H Hemmingsen

Abstract Models for predicting top-of-line corrosion (TLC) rates on carbon steels are important tools for cost-effectively designing and operating natural gas transportation pipelines. The work presented in this paper is aimed to investigate how the corrosion rates on carbon steel is affected by acids typically present in the transported pipeline fluids. This investigation may contribute to the development of improved models. In a series of experiments, the corrosion rate differences for pure CO2 (carbonic acid) corrosion and pure organic acid corrosion (acetic acid and formic acid) on X65 carbon steel were investigated at starting pH values; 4.5, 5.3, or 6.3. The experiments were conducted in deaerated low-salinity aqueous solutions at atmospheric pressure and temperature of 65 °C. The corrosion rates were evaluated from linear polarization resistance data as well as mass loss and released iron concentration. A correlation between lower pH values and increased corrosion rates was found for the organic acid experiments. However, the pH was not the most critical factor for the rates of carbon steel corrosion in these experiments. The experimental results showed that the type of acid species involved and the concentration of the undissociated acid in the solution influenced the corrosion rates considerably.


2014 ◽  
Vol 11 (4) ◽  
pp. 1577-1582
Author(s):  
Baghdad Science Journal

The corrosion behavior of copper and carbon steel in 1M concentration of hydrochloric acid (HCl) and sulphuric acid (H2SO4) has been studied. The corrosion inhibition of copper and carbon steel in 1M concentration of hydrochloric acid (HCl) and sulphuric acid (H2SO4) by Ciprofloxacin has been investigated. Specimens were exposed in the acidic media for 7 hours and corrosion rates evaluated by using the weight loss method. The effect of temperature (from 283 ºK to 333 ºK), pH (from 1to 6), inhibitor concentration (10-4 to 10-2) has been studied. It was observed that sulphuric acid environment was most corrosive to the metals because of its oxidizing nature, followed by hydrochloric acid. The rate of metal dissolution increased with increasing exposure time. Corrosion rates of carbon steel in the acidic media found to be higher.


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