scholarly journals Chemical disequilibrium in spinel-lherzolites from Ariege (French Pyrenees)

Keyword(s):  
1996 ◽  
Vol 134 (1-3) ◽  
pp. 159-179 ◽  
Author(s):  
Gilles Chazot ◽  
Martin Menzies ◽  
Ben Harte

1997 ◽  
Vol 61 (405) ◽  
pp. 257-269 ◽  
Author(s):  
Suzanne Y. O'Reilly ◽  
D. Chen ◽  
W. L. Griffin ◽  
C. G. Ryan

AbstractThe proton microprobe has been used to determine contents of Ca, Ti, Ni, Mn and Zn in the olivine of 54 spinel lherzolite xenoliths from Australian and Chinese basalts. These data are compared with proton-probe data for Ni, Mn and Zn in the olivine of 180 garnet peridotite xenoliths from African and Siberian kimberlites. Fe, Mn, Ni and Zn contents are well-correlated; because the spinel lherzolite olivines have higher mean Fe contents than garnet peridotite olivines (average Fo89.6vs. Fo90–92) they also have lower Ni and higher Mn contents. Zn and Fe are well-correlated in garnet peridotite olivine, but in spinel peridotites this relationship is perturbed by partitioning of Zn into spinel. None of these elements shows significant correlation with temperature. Consistent differences in trace-element contents of olivines in the two suites is interpreted as reflecting the greater degree of depletion of Archean garnet peridotites as compared to Phanerozoic spinel lherzolites. Ca and Ti contents of spinel-peridotite olivine are well correlated with one another, and with temperature as determined by several types of geothermometer. However, Ca contents are poorly correlated with pressure as determined by the Ca-in-olivine barometer of Köhler and Brey (1990). This reflects the strong T-dependence of this barometer: the uncertainty in pressure (calculated by this method) which is produced by the ±50°C uncertainty expected of any geothermometer is ca ± 8 kbar, corresponding to the entire width of the spinel-lherzolite field at 900–1200°C.


2013 ◽  
Vol 41 ◽  
pp. 113-121 ◽  
Author(s):  
C. Natali ◽  
L. Beccaluva ◽  
G. Bianchini ◽  
R.M. Ellam ◽  
F. Siena ◽  
...  

Nature ◽  
1986 ◽  
Vol 322 (6080) ◽  
pp. 626-628 ◽  
Author(s):  
Glen S. Mattioli ◽  
Bernard J. Wood

1980 ◽  
Vol 88 (3) ◽  
pp. 337-342 ◽  
Author(s):  
R. L. Hervig ◽  
J. V. Smith
Keyword(s):  

2020 ◽  
Author(s):  
Eduardo Novais-Rodrigues ◽  
Tiago Jalowitzki ◽  
Fernanda Gervasoni ◽  
Hirochika Sumino ◽  
Yannick Bussweiler ◽  
...  

1986 ◽  
Vol 77 (3) ◽  
pp. 181-201 ◽  
Author(s):  
R. L. Hervig ◽  
J. V. Smith ◽  
J. B. Dawson

ABSTRACTElectron and ion microprobe analyses for P, Si, Ti, Al, Cr, V, Sc, Fe, Mn, Mg, Ni, Co, Ca, Sr, Na, K and Li in olivine, pyroxenes and garnet in forty-two cold and twelve hot garnet lherzolites from kimberlites, nine spinel lherzolites from kimberlites and eighteen from alkali basalts, and one cold garnet lherzolite from the Malaita alnöite, are compared with published data for minerals occurring in lherzolite, harzburgite and eclogite xenoliths, for silicate megacrysts in kimberlites, and for silicate inclusions in diamonds. Despite wide ranges in the chemistry of minerals from garnet and spinel lherzolites, there are distinct regions in composition space that would enable determination of the parent lithology of disaggregated minerals in kimberlites and alkali basalts. Titanium correlates with Fe3+ in garnets. Chromium, Al, V and Sc are distributed similarly between silicates in lherzolites. Sodium correlates with trivalent ions in olivine, and increases with temperature. The distribution of Na, but not of K and Li, between olivine and clinopyroxene correlates with temperature. The regular partitioning of Ti, Mn and Ni places constraints on crystal-liquid partition coefficients. Above the stability temperature of mica, ‘metasomatising fluids’ may scavenge Cr and other trivalent ions as they increase Ti in silicates.


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