New Innovation Using Sodium LignoSulfonate Surfactant Synthesized from Bagasse to Enhanced Oil Recovery for Light Crude Oil

Author(s):  
R. Setiati,
2021 ◽  
Author(s):  
Christophe Darnault ◽  
Bruce Phibbs ◽  
Casey McCarroll ◽  
Brightin Blanton

<p>Advances in the field of nanoscience and nanotechnology have resulted in the development of engineered nanoparticles, with unique physico-chemical properties, and their applications to all the sectors of industry, including the petroleum industry. This presentation will discuss several advances and applications of silica-based nanofluids in chemical enhanced oil recovery (EOR) processes related to interfacial phenomena in multiphase systems and physics of multiphase flow in porous media, and in particular the oil recovery characteristics resulting from nanofluids based low-salinity water flooding and chemical EOR processes. Laboratory experiments were carried out using homogeneous sandpack columns simulating oil-wet and water-wet reservoirs. To simulate oil-wet reservoirs, the sandpack columns were saturated with a light crude oil (West Texas Intermediate) at first. While in the case of the simulated water-wet reservoirs, these reservoirs were made by saturating the sandpack columns initially with a 1.0 wt% brine (NaCl) and then followed by an injection of the light crude oil. The subsequent oil-saturated (oil-wet system) and oil-brine mixture (water-wet system) within the sandpack columns were then subject to water flooding (non-sequenced recovery) or EOR processes (sequenced recovery) utilizing brine and/or surfactant as controls as well as low (0.01 wt%) and high (0.1 wt%) silica-based nanofluids. When compared with the high concentration of silica-based nanofluid, the low silica-based nanofluid concentration produced low fractional and cumulative oil recovery results in the water flooding process of oil recovery for both oil-wet and water-wet reservoir systems; however, the low silica-based nanofluid concentration was found to be the most effective with EOR process for both oil-wet and water-wet reservoir systems. Our findings permit to choose optimal concentrations of silica nanoparticles to be employed for either water flooding or EOR processes in order to increase the oil extraction efficiency.</p>


2021 ◽  
Vol 1053 (1) ◽  
pp. 012068
Author(s):  
Teodora Dasilva ◽  
Ronny Windu Sudrajat ◽  
Mega Kasmiyatun ◽  
Slamet Priyanto ◽  
Suherman ◽  
...  

SPE Journal ◽  
2018 ◽  
Vol 23 (03) ◽  
pp. 803-818 ◽  
Author(s):  
Mehrnoosh Moradi Bidhendi ◽  
Griselda Garcia-Olvera ◽  
Brendon Morin ◽  
John S. Oakey ◽  
Vladimir Alvarado

Summary Injection of water with a designed chemistry has been proposed as a novel enhanced-oil-recovery (EOR) method, commonly referred to as low-salinity (LS) or smart waterflooding, among other labels. The multiple names encompass a family of EOR methods that rely on modifying injection-water chemistry to increase oil recovery. Despite successful laboratory experiments and field trials, underlying EOR mechanisms remain controversial and poorly understood. At present, the vast majority of the proposed mechanisms rely on rock/fluid interactions. In this work, we propose an alternative fluid/fluid interaction mechanism (i.e., an increase in crude-oil/water interfacial viscoelasticity upon injection of designed brine as a suppressor of oil trapping by snap-off). A crude oil from Wyoming was selected for its known interfacial responsiveness to water chemistry. Brines were prepared with analytic-grade salts to test the effect of specific anions and cations. The brines’ ionic strengths were modified by dilution with deionized water to the desired salinity. A battery of experiments was performed to show a link between dynamic interfacial viscoelasticity and recovery. Experiments include double-wall ring interfacial rheometry, direct visualization on microfluidic devices, and coreflooding experiments in Berea sandstone cores. Interfacial rheological results show that interfacial viscoelasticity generally increases as brine salinity is decreased, regardless of which cations and anions are present in brine. However, the rate of elasticity buildup and the plateau value depend on specific ions available in solution. Snap-off analysis in a microfluidic device, consisting of a flow-focusing geometry, demonstrates that increased viscoelasticity suppresses interfacial pinch-off, and sustains a more continuous oil phase. This effect was examined in coreflooding experiments with sodium sulfate brines. Corefloods were designed to limit wettability alteration by maintaining a low temperature (25°C) and short aging times. Geochemical analysis provided information on in-situ water chemistry. Oil-recovery and pressure responses were shown to directly correlate with interfacial elasticity [i.e., recovery factor (RF) is consistently greater the larger the induced interfacial viscoelasticity for the system examined in this paper]. Our results demonstrate that a largely overlooked interfacial effect of engineered waterflooding can serve as an alternative and more complete explanation of LS or engineered waterflooding recovery. This new mechanism offers a direction to design water chemistry for optimized waterflooding recovery in engineered water-chemistry processes, and opens a new route to design EOR methods.


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