Low Dosage Hydrate Inhibitors (LDHI): Advances in Flow Assurance Technology for Gas Production Systems

Author(s):  
Leonard W. Clark ◽  
Joanne Aanderson
Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1849 ◽  
Author(s):  
Adriana Velloso Alves de Souza ◽  
Francisca Rosário ◽  
João Cajaiba

Calcium carbonate scale is formed during oil and gas production. Tube-blocking tests (TBTs) are used to define the minimum inhibitory concentration (MIC) in order to prevent scale adhesion in the petroleum production system equipment. However, non-adhered crystals may favor heterogeneous nucleation to other deposits such as calcium naphthenates, causing a more severe scale problem, increasing production losses and treatment costs. The objective of the present work was to develop a new dynamic test methodology to determine the MIC for CaCO3 using a sintered metal filter. Organophosphorus inhibitors were selected for comparison with the conventional dynamic tube-blocking system. The results demonstrated that the use of the filter allowed an MIC of the inhibitors to be obtained considering the precipitation prevention. The inhibitor concentration in the conventional tube-blocking system does not prevent precipitation, acting only on adhesion and crystal growth on the capillary wall. Tests to evaluate the potential of calcium naphthenates formation in a naphthenate flow rig dynamic system demonstrated the influence of heterogeneous nucleation from non-adhered carbonate crystals, potentially aggravating deposition problems in oil and gas production systems.


Agronomy ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1784
Author(s):  
Beatriz Ligoski ◽  
Lucas Ferreira Gonçalves ◽  
Flavio Lopes Claudio ◽  
Estenio Moreira Alves ◽  
Ana Maria Krüger ◽  
...  

Legume–grass intercropping systems are a sustainable option to improve nutritional quality of animal feed and decrease livestock greenhouse gas emissions. Thus, the present study evaluated yield, chemical composition and in vitro gas production of silages produced with intercropped palisade grass (Urochloa brizantha.(A.Rich.) R.D.Webster), pigeon pea (Cajanus cajan cv. Super N) and corn (Zea mays. L.). Forage was harvested and placed inside micro-silos, which were opened after 100 days and samples were collected for chemical composition and in vitro gas production analyses. Intercropped silage had higher crude protein, acid detergent fiber, and lignin content than corn silage. Moreover, intercropped silage decreased total gas and methane production. Therefore, intercropped silage showed potential to increase conserved feed nutritional quality and reduce methane emissions in livestock production systems.


2015 ◽  
Vol 55 (2) ◽  
pp. 477
Author(s):  
Zachary Aman ◽  
Bruce Norris ◽  
Michael Johns ◽  
Eric F. May

As production moves towards harsher operating conditions, the conventional strategy of complete hydrate avoidance may not be economically viable. In the past two decades, the development of new technologies, such as low-dosage hydrate inhibitors and active pipeline heating, have enabled new management strategies where limited quantities of hydrate may be allowed to form without endangering the flowline. While this strategy may result in cost savings for long-distance tiebacks, its success hinges on accurate predictive capabilities for hydrate formation and transportability. In this extended abstract, the authors present a new freeware Hydrate Flow Assurance Simulation Tool (HyFAST), where the risk of hydrate plug formation can be directly predicted in subsea flowlines for use in flow assurance concept selection and process engineering. This tool is based on deterministic hydrate plug formation stages—including phase dispersion, hydrate growth rate and particle agglomeration—developed in the international engineering community in the past 20 years. HyFAST expands this conventional paradigm by introducing a new probabilistic engine to account for dynamic hydrate nucleation. This expanded capability enables flow-assurance engineers to directly quantify the risk of plug formation as a function of: flowline length; insulation thickness; produced water concentration; the amount of thermodynamic inhibitor injected; and, the amount of low-dosage hydrate inhibitor injected. An open discussion of all models and assumptions underlying the tool is presented, and the use of this tool to quantify hydrate plug formation risk is demonstrated.


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