scholarly journals Reaction Mechanism of Calcium Hydroxide with Gaseous Hydrogen Chloride

1998 ◽  
Vol 53 (6) ◽  
pp. 871-880 ◽  
Author(s):  
K. M. Allal ◽  
J. C. Dolignier ◽  
G. Martin
1985 ◽  
Vol 50 (8) ◽  
pp. 1842-1851 ◽  
Author(s):  
Petr Švec

The course of chlorination of 2,4,6-trichlorophenol (I) in water and approximately 20% sulfuric and hydrochloric acids has been investigated. In all these media the reaction gives primarily 2,4,6,6-tetrachloro-2,4-cyclohexadienone (II) which is subsequently chlorinated under formation of polychlorinated alicyclic ketones or isomerized to give the more stable 2,4,6,6-tetrachloro-2,5-cyclohexadienone (III), the precursor of further arising chlorinated 1,4-benzoquinones. The ratio of the arising polychlorinated alicyclic ketones to chlorinated 1,4-benzoquinones is significantly influenced by concentration of hydrogen chloride in the reaction medium. On the basis of model experiments, the reaction mechanism of exhaustive chlorination of 2,4,6-trichlorophenol has been suggested.


1966 ◽  
Vol 24 (8) ◽  
pp. 646-650
Author(s):  
Kazuo WATANABE ◽  
Toshiharu SUGIHARA ◽  
Masakazu TANAKA

2020 ◽  
Vol 59 (20) ◽  
pp. 9699-9704
Author(s):  
Atsushi Iizuka ◽  
Yuma Morishita ◽  
Etsuro Shibata ◽  
Chikako Takatoh ◽  
Hiromitsu Cho

1980 ◽  
Vol 84 (12) ◽  
pp. 1448-1453 ◽  
Author(s):  
Yoonok Kang ◽  
Jean Ann Skiles ◽  
J. P. Wightman

2005 ◽  
Vol 60 (21) ◽  
pp. 5819-5829 ◽  
Author(s):  
Michael Koch ◽  
Xinhai Zhang ◽  
Jun Deng ◽  
Andreas Kavouras ◽  
Gernot Krammer ◽  
...  

1995 ◽  
Vol 91 (5) ◽  
pp. 941-948 ◽  
Author(s):  
Arla Kytökivi ◽  
Marina Lindblad ◽  
Andrew Root

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