Bismaleimide Based Shape Memory Polymers: Correlation Between Chemical Composition and Mechanical Properties

Author(s):  
Amber McClung ◽  
Joseph Shumaker ◽  
Jeffery Baur ◽  
Stephanie Reed ◽  
Shawna Matthys
RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90212-90219 ◽  
Author(s):  
Pengfei Yang ◽  
Guangming Zhu ◽  
Xuelin Shen ◽  
Xiaogang Yan ◽  
Jing Nie

A POSS–PCL shape memory network is synthesized. The cage-like POSS not only serves as a chemical netpoint, also causes improvement in mechanical properties. Optimized networks exhibit both excellent tensile strength and nearly complete recovery.


2005 ◽  
Author(s):  
Michelle M. Keihl ◽  
Robert S. Bortolin ◽  
Brian Sanders ◽  
Shiv Joshi ◽  
Zeb Tidwell

2013 ◽  
Vol 2013 (0) ◽  
pp. _J044012-1-_J044012-5
Author(s):  
Kazuhiro SUGITANI ◽  
Kazuto TAKASHIMA ◽  
Toshiro NORITSUGU ◽  
Toshiharu MUKAI

Author(s):  
Matthew K. McBride ◽  
Brady T. Worrell ◽  
Tobin Brown ◽  
Lewis M. Cox ◽  
Nancy Sowan ◽  
...  

The ability to behave in a fluidlike manner fundamentally separates thermoset and thermoplastic polymers. Bridging this divide, covalent adaptable networks (CANs) structurally resemble thermosets with permanent covalent crosslinks but are able to flow in a manner that resembles thermoplastic behavior only when a dynamic chemical reaction is active. As a consequence, the rheological behavior of CANs becomes intrinsically tied to the dynamic reaction kinetics and the stimuli that are used to trigger those, including temperature, light, and chemical stimuli, providing unprecedented control over viscoelastic properties. CANs represent a highly capable material that serves as a powerful tool to improve mechanical properties and processing in a wide variety of polymer applications, including composites, hydrogels, and shape-memory polymers. This review aims to highlight the enabling material properties of CANs and the applied fields where the CAN concept has been embraced.


MRS Bulletin ◽  
2009 ◽  
Vol 34 (3) ◽  
pp. 178-183 ◽  
Author(s):  
Harold S. Park ◽  
Wei Cai ◽  
Horacio D. Espinosa ◽  
Hanchen Huang

AbstractNanowires are among the most exciting one-dimensional nanomaterials because of their unique properties, which result primarily from their chemical composition and large surface area to volume ratio. These properties make them ideal building blocks for the development of next generation electronics, opto-electronics, and sensor systems. In this article, we focus on the unique mechanical properties of nanowires, which emerge from surface atoms having different electron densities and fewer bonding neighbors than atoms lying within the nanowire bulk. In this respect, atomistic simulations have revealed a plethora of novel surface-driven mechanical behavior and properties, including both increases and decreases in elastic stiffness, phase transformations, shape memory, and pseudoelastic effects. This article reviews such atomistic simulations, as well as experimental data of these phenomena, while assessing future challenges and directions.


2016 ◽  
Vol 37 (23) ◽  
pp. 1972-1977 ◽  
Author(s):  
Lindsay N. Woodard ◽  
Vanessa M. Page ◽  
Kevin T. Kmetz ◽  
Melissa A. Grunlan

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