Modeling of Soot Precursor and Early Stage Soot Formation

2004 ◽  
Author(s):  
Nadezhda Slavinskaya ◽  
Elke Goos ◽  
Marina Braun-Unkhoff ◽  
Peter Frank
Keyword(s):  
Soot Formation ◽  
Early Stage ◽  
Soot Precursor

A Numerical Study on the Influence of Hydrogen Addition on Soot Formation in a Laminar Aviation Kerosene (Jet A1) Flame at Elevated Pressure

2021 ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan
Keyword(s):  
Volume Fraction ◽  
Soot Formation ◽  
Laminar Flame ◽  
Numerical Study ◽  
Soot Volume Fraction ◽  
Elevated Pressure ◽  
Condensation Process ◽  
Hydrogen Addition ◽  
Aviation Kerosene ◽  
Soot Precursor

Abstract The hydrogen addition is a potential way to reduce the soot emission of aviation kerosene. The current study analyzed the effect of hydrogen addition on aviation kerosene (Jet A1) soot formation in a laminar flame at elevated pressure to obtain a fundamental understanding of the reduced soot formation by hydrogen addition. The soot formation of flame was simulated by CoFlame code. The soot formation of kerosene-nitrogen-air, (kerosene + replaced hydrogen addition)-nitrogen-air, (kerosene + direct hydrogen addition)-nitrogen-air and (kerosene + direct nitrogen addition)-nitrogen-air laminar flames were simulated. The calculated pressure includes 1, 2 and 5 atm. The hydrogen addition increases the peak temperature of Jet A1 flame and extends the height of flame. The hydrogen addition suppresses the soot precursor formation of Jet A1 by physical dilution effect and chemical inhibition effect, which weaken the poly-aromatic hydrocarbon (PAH) condensation process and reduce the soot formation. The elevated pressure significantly accelerates the soot precursor formation and increases the soot formation in flame. Meanwhile, the ratio of reduced soot volume fraction to base soot volume fraction by hydrogen addition decreases with the increase of pressure, indicating that the elevated pressure weakens the suppression effect of hydrogen addition on soot formation in Jet A1 flame.

scholarly journals Joint Study of Impingement Combustion Simulation and Diesel Visualization Experiment of Variable Injection Pressure in Constant Volume Vessel

Energies ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 6210
Author(s):  
Yuanzhi Tang ◽  
Diming Lou ◽  
Chengguan Wang ◽  
Piqiang Tan ◽  
Zhiyuan Hu ◽  
...  
Keyword(s):  
Alternative Fuels ◽  
Soot Formation ◽  
Early Stage ◽  
Combustion Process ◽  
Injection Pressure ◽  
Constant Volume ◽  
Dynamics Simulation ◽  
Visualization Experiment ◽  
Combustion Simulation ◽  
Image Pixels

In this paper, the visualization experiments of spray, ignition, and combustion of diesel under variable injection pressure (from 90 to 130 MPa) were studied by using a constant volume vessel and impinging combustion plate system. With the development of the down-sizing of diesel engines, the wall impinging combustion without liquid spray collision will be the research focus in the diesel engine combustion process. The flame natural luminosity in the experiment represents the soot formation of diesel combustion. Besides, the detailed information of diesel spray mixing combustion was obtained by using the CFD (Computational Fluid Dynamics) simulation of alternative fuels in CONVERGE™. The specific conclusions are as follows. The high velocity of the spray under the higher injection pressure could reduce the low-mixing area near the impinging wall by entraining more air. Under higher injection pressure in simulation, the gas diffused more extensively, and more heat was released after combustion. Therefore, a large amount of soot formed in the early stage of combustion and then oxidized in high-temperature regions, which agreed with the conclusions in the experiments. Under the influence of the superposition of image pixels of the flame, the change of soot generation with injection pressure is smaller than the actual value, so the visualization experiment can be used as the basis of combustion prediction.

Two-dimensional imaging of ignition and soot formation processes in a diesel flame

2005 ◽  
Vol 6 (1) ◽  
pp. 21-42 ◽  
Author(s):  
H Kosaka ◽  
T Aizawa ◽  
T Kamimoto
Keyword(s):  
Soot Formation ◽  
Diesel Spray ◽  
Oxidation Reactions ◽  
Soot Particles ◽  
Nozzle Orifice ◽  
Spray Flame ◽  
Soot Precursor ◽  
Planar Laser ◽  
Laser Induced Incandescence ◽  
Ambient Gas

The processes of ignition and formation of soot precursor and soot particles in a diesel spray flame achieved in a rapid compression machine (RCM) were imaged two-dimensionally using the laser sheet techniques. For the two-dimensional imaging of time and of location where ignition first occurs in a diesel spray, planar laser-induced fluorescence (PLIF) of formaldehyde was applied to a diesel spray in an RCM. Formaldehyde has been hypothesized to be one of the stable intermediate species marking the start of oxidation reactions in a transient spray under compression ignition conditions. In this study, the laser-induced fluorescence (LIF) images of the formaldehyde formed in a diesel fuel spray during the ignition process have been obtained by exciting formaldehyde with the third harmonic of a neodymium-doped yttrium aluminium garnet (Nd:YAG) laser. The LIF images of formaldehyde in a spray revealed that the time when the first fluorescence is detected is almost identical with the time when the total heat release due to low-temperature oxidation reactions equals the heat absorption by fuel vaporization in the spray. The formaldehyde level rose steadily until the high-temperature reaction phase of diesel spray ignition. At the start of this ‘hot-ignition’ phase, the formaldehyde concentration fell rapidly, thus signalling the end of the low-temperature ignition phase. Increases in the initial ambient gas temperatures advanced the hot-ignition starting time. The first hot ignition occurred in the periphery of spray head at initial ambient gas temperatures between 580 and 660 K. When the ambient gas temperature was increased to 790 K, the position of the first ignition moved to the central region of the spray head. For the investigation of soot formation processes in a diesel spray flame, simultaneous imaging of the soot precursor and soot particles in a transient spray flame in an RCM was conducted by PLIF and by planar laser-induced incandescence (PLII) techniques. The third harmonic (355 nm) and the fundamental (1064 nm) laser pulses from an Nd:YAG laser, between which a delay of 44 ns was imposed by 13.3 m of optical path difference, were used to excite LIF from the soot precursor and laser-induced incandescence (LII) from soot particles in the spray flame. The LIF and the LII were separately imaged by two image-intensified charge-coupled device cameras with identical detection wavelengths of 400 nm and bandwidths of 80 nm. The LIF from the soot precursor was mainly located in the central region of the spray flame between 40 and 55 mm (between 270 and 370 times the nozzle orifice diameter d°) from the nozzle orifice. The LII from soot particles was observed to surround the soot precursor LIF region and to extend downstream. The first appearance of the LIF from the soot precursor in the spray flame preceded the appearance of the LII from soot particles. The intensity of the LIF from the soot precursor reached its maximum immediately after rich premixed combustion. In contrast, the intensity of the LII from soot particles increased gradually and reached its maximum after the end of injection. Measured LIF spectra, of the soot precursor in the spray flame, were very broad with the peak between 430 and 460 nm.

A Numerical and Experimental Study of Soot Precursor and Primary Particle Size of N-Butylbenzene in Laminar Flame

2021 ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan
Keyword(s):  
Soot Particle ◽  
Primary Particle ◽  
Volume Fraction ◽  
Soot Formation ◽  
Laminar Flame ◽  
Particle Diameter ◽  
Soot Volume Fraction ◽  
The Core ◽  
Soot Precursor ◽  
Combined Mechanism

Abstract The current study analyzed the soot precursor of the n-butylbenzene found in diesel and kerosene in laminar flame, and integrated the corresponding poly-aromatic hydrocarbon (PAH) growth mechanism with the popular n-butylbenzene oxidation mechanisms to improve the soot formation prediction of n-butylbenzene. The size of soot precursor was determined by the fringe length in the core of soot particle since the nanostructure of the core of soot particle is similar with that of nascent soot particle formed by soot precursor nucleation. The geometric mean fringe length in core of soot particles was measured to be 0.67 nm approximating to the size of five-ringed PAH (A5). An A5 growth mechanism was added on a popular n-butylbenzene mechanism, and the combined mechanism was further reduced. After validation by the ignition delay time in literature, the combined mechanism was then validated by the primary particle diameter in laboratory and soot volume fraction of n-propylbenzene in literature. The calculated soot precursor concentration and PAH condensation rate of the combined mechanism are smaller than that of the base mechanism. The simulated primary soot particle diameter of proposed combined mechanism agrees well with the measure primary soot particle diameter. Comparing to the simulated soot volume fraction of base n-butylbenzene mechanism, the simulated soot volume fraction of proposed combined n-butylbenzene-A5 mechanism agrees well with the measure soot volume fraction of n-propylbenzene in literature. This study provides certain support for further investigation of soot formation of n-butylbenzene and its relative fuel like diesel and kerosene.

scholarly journals Ultrafine particulate matter in methane-air premixed flames with oxygen enrichment

2021 ◽  
Author(s):  
Shruthi Dasappa ◽  
Joaquin Camacho
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Equivalence Ratio ◽  
Volume Fraction ◽  
Soot Formation ◽  
Flame Temperature ◽  
Number Density ◽  
Soot Precursors ◽  
Soot Precursor ◽  
Ultrafine Particulate Matter

A complementary computational and experimental study is carried out on the formation of ultrafine particulate matter in premixed laminar methane air flames. Specifically, soot formation is examined in premixed stretch-stabilized flames to observe soot inception and growth at relatively high flame temperatures common to oxygen enriched applications. Particle size distribution functions (PSDF) measured by mobility sizing show clear trends as the equivalence ratio increases from Φ = 2.2 to Φ = 2.4. For a given equivalence ratio, the measured distribution decreases in median mobility particle size as the maximum flame temperature increases from approximately 1950 K to 2050 K. The median mobility particle size is 20 nm or less for all flame conditions studied. The volume fraction decreases with increasing flame temperature for all equivalence ratio conditions. The Φ = 2.2 condition is close to the soot inception limit and both number density and volume fraction decrease monotonically with increasing flame temperature. The higher equivalence ratio conditions show a peak in number density at 2000 K which may indicate competing soot inception processes are optimized at this temperature. Flame structure computations are carried out using detailed gas-phase combustion chemistry of the Appel, Bockhorn, Frenklach (ABF) model to examine the connection of the observed PSDF to soot precursor chemistry. Agreement between measured and computed flame standoff distances indicates that the ABF model could provide a reasonable prediction of the flame temperature and soot precursor formation for the flames currently studied. To the first order, the trends observed in the measured PSDF could be understood in terms of computed trends for the formation of benzene, naphthalene and other soot precursors. Results of the current study inform particulate matter behavior for methane and natural gas combustion applications at elevated temperature and oxygen enriched conditions.

Investigation of Soot Formation in Fuel-Rich Premixed Propane/Air Microcombustion at Low Temperatures

2020 ◽  
Author(s):  
Abdul H. Khalid ◽  
Jiashen Tian ◽  
Brent B. Skabelund ◽  
Ryan J. Milcarek
Keyword(s):  
Equivalence Ratio ◽  
Flow Reactor ◽  
Soot Formation ◽  
Inert Gas ◽  
Flow Rates ◽  
Soot Precursor ◽  
Before And After ◽  
Micro Flow ◽  
Gas Dilution ◽  
Lower Temperature

Abstract The advantage of micro/meso combustion includes higher efficiency, improved heat and mass transfer, swift startup and shutdown when compared with regular combustion. This study aims to investigate the critical sooting equivalence ratio and soot precursor formation in a micro-flow reactor with a controlled temperature profile of diameter 2.3mm and their dependence on the temperature ranging from 800–1250 °C. The equivalence ratio is varied from 1–13 and flow rates of 10 and 100sccm were investigated. Also, nitrogen is used to study the effect of inert gas dilution. A gas chromatograph is used to study the exhaust gas composition. The reactor is analyzed visually for the traces of soot particles before and after combustion, each time the temperature and/or equivalence ratio is varied. From 750–950°C, no soot is indicted at all equivalence ratios even up to 100. The inert gas dilution helped in raising the critical sooting equivalence ratio as expected because of the lower temperature. The results indicated an opposite trend to what has been well understood for the pre-mixed sooting flames, i.e., decreasing temperature decreases soot formation. The capability of the reactor to examine the effects of temperature on the critical sooting equivalence ratio at different flow rates has been successfully demonstrated.

The Effects of Inlet Charge Component on the Formation of Soot in Diesel Engine

2012 ◽  
Vol 610-613 ◽  
pp. 2079-2084
Author(s):  
Yang Zhao ◽  
Zhong Wang ◽  
Ming Di Li ◽  
Rui Na Li
Keyword(s):  
Diesel Engine ◽  
Initial Temperature ◽  
Soot Formation ◽  
Great Influence ◽  
Initial Pressure ◽  
Coupling Model ◽  
Excess Air ◽  
Soot Precursor ◽  
Excess Air Coefficient ◽  
Temperature And Pressure

Air contains oxygen, nitrogen, etc. The gas separated technology and mixed method could increase or decrease the certain components of air. Changing the concentration of the component has a great influence on soot formation of diesel engine. The influences of excess air coefficient and the oxygen, nitrogen proportion of inlet air, the initial temperature and the initial pressure on PAHs (the soot precursor) formation of diesel engine were discussed in this paper. The results showed that the coupling model of diesel PAHs could predict the reaction temperature, the concentration of the reaction intermediates (CO, CO2 and O2), and the ignition delay during the combustion progress accurately. The concentration of the soot and its precursor PAHs could be decreased effectively by changing the proportion of the oxygen and nitrogen in the inlet air. After increasing the excess air coefficient, the numbers of the reaction intermediate free radicals (H and OH) were increased and the concentration of aromatic hydrocarbons was decreased. The beginning angle of chemical reaction was advanced by increasing the initial temperature and pressure. And it is beneficial to decrease the concentration of PAHs.

scholarly journals Ultrafine Particulate Matter in Methane-Air Premixed Flames With Oxygen Enrichment

2021 ◽  
Vol 7 ◽  
Author(s):  
Shruthi Dasappa ◽  
Joaquin Camacho
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Equivalence Ratio ◽  
Volume Fraction ◽  
Soot Formation ◽  
Flame Temperature ◽  
Number Density ◽  
Soot Precursors ◽  
Soot Precursor ◽  
Ultrafine Particulate Matter

A complementary computational and experimental study is carried out on the formation of ultrafine particulate matter in premixed laminar methane air flames. Specifically, soot formation is examined in premixed stretch-stabilized flames to observe soot inception and growth at relatively high flame temperatures common to oxygen enriched applications. Particle size distribution functions (PSDF) measured by mobility sizing show clear trends as the equivalence ratio increases from Φ = 2.2 to Φ = 2.4. For a given equivalence ratio, the measured distribution decreases in median mobility particle size as the maximum flame temperature increases from approximately 1,950–2,050 K. The median mobility particle size is 20 nm or less for all flame conditions studied. The volume fraction decreases with increasing flame temperature for all equivalence ratio conditions. The Φ = 2.2 condition is close to the soot inception limit and both number density and volume fraction decrease monotonically with increasing flame temperature. The higher equivalence ratio conditions show a peak in number density at 2,000 K which may indicate competing soot inception processes are optimized at this temperature. Flame structure computations are carried out using detailed gas-phase combustion chemistry of the Appel, Bockhorn, Frenklach (ABF) model to examine the connection of the observed PSDF to soot precursor chemistry. Agreement between measured and computed flame standoff distances indicates that the ABF model could provide a reasonable prediction of the flame temperature and soot precursor formation for the flames currently studied. To the first order, the trends observed in the measured PSDF could be understood in terms of computed trends for the formation of benzene, naphthalene and other soot precursors. Results of the current study inform particulate matter behavior for methane and natural gas combustion applications at elevated temperature and oxygen enriched conditions.

A Comparison Study of Soot Precursor and Aggregate Property Between Algae-Based Aviation Biofuel and Aviation Kerosene RP-3 in Laminar Flame

2021 ◽  
Vol 143 (11) ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan ◽  
Yiyang Yang
Keyword(s):  
Growth Mechanism ◽  
Soot Formation ◽  
Laminar Flame ◽  
Carbon Number ◽  
Comparison Study ◽  
Aviation Kerosene ◽  
Soot Precursors ◽  
Soot Precursor ◽  
Aggregate Property ◽  
Aviation Biofuel

Abstract Algae-based aviation biofuel shows the potential to reduce soot emission in flight. A comparison study of soot precursor and aggregate property between algae-based biofuel and aviation kerosene RP-3 in laminar flame was conducted to investigate the reason of biofuel’s less soot formation. The soot precursors were determined by the fringe lengths of soot particles. At a typical dimensionless height DH = 0.50 of both flames, the geometric mean fringe lengths of biofuel and RP-3 are measured to be 0.67 and 0.73 nm, respectively, approximating to the size of five-ringed (A5) and seven-ringed (A7) poly-aromatic hydrocarbon, respectively. An A5 growth mechanism was then added to biofuel surrogate mechanisms for soot formation simulation. Since the carbon number component of biofuel is wide and difficult for comprehensive mechanism development, two surrogate mechanisms were developed. One is based on the C8–C16 n-alkane that covers biofuel’s main components, and the other one is based on biofuel’s average carbon number to simplify the mechanism. Meanwhile, an A7 growth mechanism was added to a popular RP-3 mechanism. The soot formation simulation with the combination mechanisms for both fuels provides a better agreement with the measured primary particle diameter and suggests that the reason for less soot production by biofuel is its less soot precursor production that weakens soot nucleation and growth. Lastly, the soot fractal dimension of biofuel is smaller than that of RP-3, indicating that biofuel has a looser soot aggregate.

Alterations in the number of motoneurons containing immunoreactive calcitonin gene-related peptide(CGRP)& choline acetyltransferase(ChAT) in the cervical spinal cord of the wobbler mouse during the development of the motoneuron disease

1995 ◽  
Vol 53 ◽  
pp. 970-971
Author(s):  
L. Vacca-Galloway ◽  
Y.Q. Zhang ◽  
P. Bose ◽  
S.H. Zhang
Keyword(s):  
Spinal Cord ◽  
Early Stage ◽  
Cervical Spinal Cord ◽  
Wild Type Mouse ◽  
Reflex Response ◽  
Mouse Strains ◽  
Behavioral Tests ◽  
Wobbler Mouse ◽  
Stage 4 ◽  
Stage 1

The Wobbler mouse (wr) has been studied as a model for inherited human motoneuron diseases (MNDs). Using behavioral tests for forelimb power, walking, climbing, and the “clasp-like reflex” response, the progress of the MND can be categorized into early (Stage 1, age 21 days) and late (Stage 4, age 3 months) stages. Age-and sex-matched normal phenotype littermates (NFR/wr) were used as controls (Stage 0), as well as mice from two related wild-type mouse strains: NFR/N and a C57BI/6N. Using behavioral tests, we also detected pre-symptomatic Wobblers at postnatal ages 7 and 14 days. The mice were anesthetized and perfusion-fixed for immunocytochemical (ICC) of CGRP and ChAT in the spinal cord (C3 to C5).Using computerized morphomety (Vidas, Zeiss), the numbers of IR-CGRP labelled motoneurons were significantly lower in 14 day old Wobbler specimens compared with the controls (Fig. 1). The same trend was observed at 21 days (Stage 1) and 3 months (Stage 4). The IR-CGRP-containing motoneurons in the Wobbler specimens declined progressively with age.

Sign in / Sign up

Export Citation Format

Share Document