Solutocapillary-convection-driven macrovoid defect formation in polymeric membranes

2001 ◽  
Author(s):  
J. Zartman ◽  
V. Khare ◽  
A. Greenberg ◽  
M. Pekny ◽  
P. Todd ◽  
...  
Keyword(s):  
Defect Formation ◽  
Polymeric Membranes

SEM/FESEM imaging of lamellar structures in melt extruded polyethylene films

1992 ◽  
Vol 50 (2) ◽  
pp. 1142-1143
Author(s):  
R.T. Chen ◽  
M.G. Jamieson ◽  
R. Callahan
Keyword(s):  
Imaging Techniques ◽  
Membrane Surface ◽  
High Stress ◽  
Extrusion Direction ◽  
Polymeric Membranes ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Crystalline Polymers ◽  
Lamellar Structures ◽  
Resolution Imaging

“Row lamellar” structures have previously been observed when highly crystalline polymers are melt-extruded and recrystallized under high stress. With annealing to perfect the stacked lamellar superstructure and subsequent stretching in the machine (extrusion) direction, slit-like micropores form between the stacked lamellae. This process has been adopted to produce polymeric membranes on a commercial scale with controlled microporous structures. In order to produce the desired pore morphology, row lamellar structures must be established in the membrane precursors, i.e., as-extruded and annealed polymer films or hollow fibers. Due to the lack of pronounced surface topography, the lamellar structures have typically been investigated by replica-TEM, an indirect and time consuming procedure. Recently, with the availability of high resolution imaging techniques such as scanning tunneling microscopy (STM) and field emission scanning electron microscopy (FESEM), the microporous structures on the membrane surface as well as lamellar structures in the precursors can be directly examined.The materials investigated are Celgard® polyethylene (PE) flat sheet membranes and their film precursors, both as-extruded and annealed, made at different extrusion rates (E.R.).

Xenon ion irradiation of superconducting YBa2Cu3O7 thin films

1990 ◽  
Vol 48 (4) ◽  
pp. 92-93
Author(s):  
H. Watanabe ◽  
B. Kabius ◽  
B. Roas ◽  
K. Urban
Keyword(s):  
Defect Formation ◽  
Ion Irradiation ◽  
High Resolution Electron Microscopy ◽  
Structural Disorder ◽  
Flux Lines ◽  
Pinning Effect ◽  
Magnetic Flux Lines ◽  
Resolution Electron ◽  
Radiation Induced ◽  
Induced Defects

Recently it was reported that the critical current density(Jc) of YBa2Cu2O7, in the presence of magnetic field, is enhanced by ion irradiation. The enhancement is thought to be due to the pinning of the magnetic flux lines by radiation-induced defects or by structural disorder. The aim of the present study was to understand the fundamental mechanisms of the defect formation in association with the pinning effect in YBa2Cu3O7 by means of high-resolution electron microscopy(HRTEM).The YBa2Cu3O7 specimens were prepared by laser ablation in an insitu process. During deposition, a substrate temperature and oxygen atmosphere were kept at about 1073 K and 0.4 mbar, respectively. In this way high quality epitaxially films can be obtained with the caxis parallel to the <100 > SrTiO3 substrate normal. The specimens were irradiated at a temperature of 77 K with 173 MeV Xe ions up to a dose of 3.0 × 1016 m−2.

Low-voltage field-emission SEM of polymeric membranes for glucose biosensors

1990 ◽  
Vol 48 (3) ◽  
pp. 860-861
Author(s):  
Lorna K. Mayo ◽  
Kenneth C. Moore ◽  
Mark A. Arnold
Keyword(s):  
Glucose Sensor ◽  
Low Voltage ◽  
Glucose Sensors ◽  
Polymeric Membranes ◽  
Artificial Endocrine Pancreas ◽  
Self Monitoring ◽  
Conducting Materials ◽  
Insulin Dependent ◽  
Living Tissues ◽  
Voltage Scanning

An implantable artificial endocrine pancreas consisting of a glucose sensor and a closed-loop insulin delivery system could potentially replace the need for glucose self-monitoring and regulation among insulin dependent diabetics. Achieving such a break through largely depends on the development of an appropriate, biocompatible membrane for the sensor. Biocompatibility is crucial since changes in the glucose sensors membrane resulting from attack by orinter action with living tissues can interfere with sensor reliability and accuracy. If such interactions can be understood, however, compensations can be made for their effects. Current polymer technology offers several possible membranes that meet the unique chemical dynamics required of a glucose sensor. Two of the most promising polymer membranes are polytetrafluoroethylene (PTFE) and silicone (Si). Low-voltage scanning electron microscopy, which is an excellent technique for characterizing a variety of polymeric and non-conducting materials, 27 was applied to the examination of experimental sensor membranes.

Column: Polymeric Membranes

Polymer News ◽  
2004 ◽  
Vol 29 (8) ◽  
pp. 253-257
Author(s):  
Tejraj Aminabhavi ◽  
Udaya Toti ◽  
Mahaveer Kurkuri ◽  
Nadagouda Mallikarjuna ◽  
Lakshmi Shetti
Keyword(s):  
Polymeric Membranes

Defect formation in solids by decay of electronic excitations

1985 ◽  
Vol 147 (11) ◽  
pp. 523 ◽  
Author(s):  
M.I. Klinger ◽  
Ch.B. Lushchik ◽  
T.V. Mashovets ◽  
G.A. Kholodar' ◽  
M.K. Sheinkman ◽  
...  
Keyword(s):  
Defect Formation ◽  
Electronic Excitations

INFLUENCE OF THE LOCATION OF THE BASEBOARD JUMPER FOR FIRMWARE FOR DEFECT FORMATION IN CHAIN DRIVE SPROCKET FORGING

2020 ◽  
Author(s):  
I.A. Tserna ◽  
◽  
V.V. Bukhov ◽  
Keyword(s):  
Computer Simulation ◽  
Defect Formation ◽  
Chain Drive ◽  
Combine Harvester

The paper presents the results of computer simulation of the process of de-formationforged chain wheels, combine harvester; the influence of the placement of the jumper outline for firmware on the processes of defect formation in forging.

Fouling Is the Beginning: Upcycling Biopolymer-Fouled Substrates for Fabricating High-Permeance Thin-Film Composite Polyamide Membranes

2020 ◽  
Author(s):  
Ruobin Dai ◽  
Hongyi Han ◽  
Tianlin Wang ◽  
Jiayi Li ◽  
Chuyang Y. Tang ◽  
...  
Keyword(s):  
Thin Film ◽  
High Pressure ◽  
End Of Life ◽  
Water Purification ◽  
Low Pressure ◽  
Polymeric Membranes ◽  
Membrane Recycling ◽  
Film Composite ◽  
Thin Film Composite ◽  
First Time

Commercial polymeric membranes are generally recognized to have low sustainability as membranes need to be replaced and abandoned after reaching the end of their life. At present, only techniques for downcycling end-of-life high-pressure membranes are available. For the first time, this study paves the way for upcycling fouled/end-of-life low-pressure membranes to fabricate new high-pressure membranes for water purification, forming a closed eco-loop of membrane recycling with significantly improved sustainability.

Reasons for the formation of crack-like defects in 09Г2С heavy plate steel for tank steel structures

2020 ◽  
Vol 10 (5) ◽  
pp. 479-489
Author(s):  
Vitaly М. Goritsky ◽  
◽  
Georgy R. Shneyderov ◽  
Eugeny P. Studenov ◽  
Olga A. Zadubrovskaya ◽  
...  
Keyword(s):  
Impact Toughness ◽  
Defect Formation ◽  
Steel Structures ◽  
Controlled Rolling ◽  
Plate Steel ◽  
Heavy Plate ◽  
Oil Storage ◽  
Magnetic Inspection ◽  
Metal Microstructure

Determination of causes of crack-like defects in the heavy plate steel 09Г2С is a crucial task, the solution of which is aimed at improving the mechanical safety of oil storage steel vertical tanks. In order to determine the causes for the formation of a group of crack-like defects oriented towards rolling, revealed during grinding and magnetic inspection of the tank wall surface near the vertical weld, the analysis of the chemical composition and testing of the mechanical properties of heavy plate steel were carried out, including the determination of the anisotropy of impact toughness in the temperature range from +20 to –75 °С, analysis of metal microstructure in the area of defect formation on transversal sections and rolled surface. Impact bending tests of 09Г2С heavy plate steel after controlled rolling in longitudinal and transverse directions showed no anisotropy of impact toughness, as well as high purity of steel as for sulfur and titanium, which at higher content causes impact toughness anisotropy. The revealed features of metal microstructure near the defects made it possible to conclude that the crack-like defects were formed during the rolling of gas bubbles at the stage of preparing semi-finished rolled products for finishing rolling. One of the possible methods to prevent such defects from getting into finished rolled products is the use of automated systems of visual inspection of rolled products in the manufacturing process.

ASPECTS ON POLYMER-SOLVENT EQUILIBRIUM AND DIFFUSION IN POLYMERIC MEMBRANES

2013 ◽  
Vol 12 (8) ◽  
pp. 1583-1591 ◽  
Author(s):  
Eugenia Teodora Iacob Tudose Ioan Mamaliga ◽  
Ciprian Constantin Negoescu ◽  
Nicoleta Bunduc
Keyword(s):  
Polymeric Membranes ◽  
And Diffusion ◽  
Polymer Solvent
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