Observation of vibrational relaxation dynamics in X3Sigma(-)g oxygen following stimulated Raman excitation to the v=1 level - Implications for the RELIEF flow tagging technique

Author(s):  
Glenn Diskin ◽  
Walter Lempert ◽  
Richard Miles
2018 ◽  
Vol 20 (5) ◽  
pp. 3320-3327 ◽  
Author(s):  
Tomohisa Takaya ◽  
Masato Anan ◽  
Koichi Iwata

Time-resolved near-IR stimulated Raman spectroscopy indicates acceleration of vibrational relaxation in carotenoids by carbonyl substitution on their peripheral rings.


2004 ◽  
Vol 108 (51) ◽  
pp. 11209-11217 ◽  
Author(s):  
Gerald M. Sando ◽  
Kevin Dahl ◽  
Jeffrey C. Owrutsky

2019 ◽  
Vol 21 (31) ◽  
pp. 16895-16904 ◽  
Author(s):  
Marcin Pastorczak ◽  
Michał Nejbauer ◽  
Czesław Radzewicz

We constructed a setup for fs-infrared pump–stimulated Raman probe spectroscopy and applied it to study vibrational relaxation pathways in HDO/D2O.


2019 ◽  
Vol 11 (2) ◽  
pp. 548-555 ◽  
Author(s):  
Xiaoqian Li ◽  
Dexia Zhou ◽  
Hongxing Hao ◽  
Hailong Chen ◽  
Yuxiang Weng ◽  
...  

1999 ◽  
Vol 19 (1-4) ◽  
pp. 75-78 ◽  
Author(s):  
Takakazu Nakabayashi ◽  
Hiromi Okamoto ◽  
Mitsuo Tasumi

Vibrational relaxation dynamics of trans-stilbene in the S1 state immediately after photoexcitation is studied by picosecond time-resolved anti-Stokes Raman spectroscopy with several pump and probe wavelengths. Pump-wavelength dependence of the anti- Stokes spectrum indicates that, when pump photons with high excess energy (≈5200cm-1) are used, the anti-Stokes Raman bands at 0 ps delay time arise from vibrationally excited transients with excess vibrational energy not thermally distributed in the molecule. Probe-wavelength dependence suggests that the vibrationally excited transients at 0 ps are mostly on the lowest excited vibrational levels, as far as the olefinic C═C stretching and the C–Ph stretching modes are concerned. The vibrational relaxation process of S1trans-stilbene is discussed on the basis of the observed results.


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