Melting of polymer mixtures with extended softening temperature ranges

1986 ◽  
Author(s):  
H. CHANG
Keyword(s):  
Softening Temperature ◽  
Polymer Mixtures ◽  
Temperature Ranges

Influence of Additive on High Temperature Performance of Glaze

2011 ◽  
Vol 314-316 ◽  
pp. 231-235
Author(s):  
Tian Fei Ma ◽  
Hong Xia Li ◽  
Guo Qi Liu ◽  
Jian Bin Yu ◽  
Wen Gang Yang
Keyword(s):  
Grain Size ◽  
Oxidation Resistance ◽  
Base Material ◽  
Silicon Powder ◽  
Softening Temperature ◽  
Alumina Powder ◽  
Flow Temperature ◽  
Temperature Performance ◽  
Temperature Ranges ◽  
Melting Properties

Using SiO2 – Al2O3 – B2O3 – K2O – Na2O system glaze as base material, adding silicon powder or alumina powder with grain size 15μm by the mass percent of 10%, 20%, 30%, respectively, melting properties of glaze were investigated. Slilica solution as binder, the anti-oxidation coating were prepared. Oxidation resistance was determined by coating to the surface of the Al2O3-C specimens. The results show that additives can raise flow temperature prominently, but has little influence on softening point and semi-sphere point; Glazing temperature ranges are obtained with different additive contents; Glazing temperature rises with addition of silicon; Glazing temperature range widens with silicon adding; Glazing temperature ranges were not strictly corresponding with softening temperature point and flow temperature point; But differences were not tremendous; glazing temperature ranges can be estimated from softening temperature point and flow temperature point. Alumina has not prominent influence on glazing temperature, but glaze forms smoothly with alumina, and oxidation resistance was good.

scholarly journals Pyrolysis of Mixed Plastic Waste: I. Kinetic Study

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4912
Author(s):  
Ibrahim Dubdub ◽  
Mohammed Al-Yaari
Keyword(s):  
Polymer Blends ◽  
Model Fitting ◽  
Polymer Mixtures ◽  
Pure Polymer ◽  
Master Plot ◽  
Thermogravimetric Analyzer ◽  
Global Environmental ◽  
Plastic Wastes ◽  
Temperature Ranges ◽  
Recycling Techniques

Plastic wastes have become one of the biggest global environmental issues and thus recycling such massive quantities is targeted. Low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (PP), and polystyrene (PS) are considered among the main types of plastic wastes. Since pyrolysis is one of the most promising recycling techniques, this work aims to build knowledge on the co-pyrolysis of mixed polymers using two model-fitting (Criado and Coats–Redfern) methods. Seventeen co-pyrolysis tests using a thermogravimetric analyzer (TGA) at 60 K/min for different mixed compositions of LDPE, HDPE, PP, and PS were conducted. It was observed that the pyrolysis of the pure polymer samples occurs at different temperature ranges in the following order: PS < PP < LDPE < HDPE. However, compared to pure polymer samples, the co-pyrolysis of all-polymer mixtures was delayed. In addition, the synergistic effect on the co-pyrolysis of polymer blends was reported. The Master plot of the Criado model was used to determine the most suitable reaction mechanism. Then, the Coats–Redfern model was used to efficiently obtain the kinetic parameters (R2 ≥ 97.83%) and the obtained values of the activation energy of different polymer blends were ranging from 104 to 260 kJ/mol. Furthermore, the most controlling reaction mechanisms were in the following orders: First order reaction (F1), Contracting sphere (R3), and then Contracting cylinder (R2).

Optical and Electrical Properties of Organic Conducting Polymers

2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon
Keyword(s):  
Electrical Properties ◽  
Conjugated Polymer ◽  
Polymeric Materials ◽  
Quantum Mechanical ◽  
Optical And Electrical Properties ◽  
Electrically Conducting ◽  
Temperature Ranges ◽  
Lithium Tetrafluoroborate ◽  
Absorbance Peak ◽  
Polymerization Method

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.

Specific volume and features of compressibility during the molding of powder-polymer mixtures with wax-polypropylene binder

2019 ◽  
pp. 25-33
Author(s):  
Alexander Muranov ◽  
Alexey Semenov ◽  
Anatoly Kutsbakh ◽  
Boris Semenov
Keyword(s):  
Phase Transition ◽  
Comparative Analysis ◽  
Powder Metallurgy ◽  
Injection Molding ◽  
Polymer Binder ◽  
Polymer Mixture ◽  
Powder Injection ◽  
Polymer Mixtures ◽  
Pvt Data ◽  
Mathematical Processing

The article discusses one of the modern areas of powder metallurgy – the technology of manufacturing shaped parts by the powder injection molding (PIM). For the powder-polymer mixture (feedstock) with a wax-polypropylene binder of the solvent-thermal type of removal by isobaric volume dilatometry, the dependence of PVT state parameters was studied. For each component of the polymer binder, the dependence of pressure on the temperature of phase transition was obtained. As a result of mathematical processing and analysis of PVT data for the feedstock of the studied type, a technological window of parameters has been determined that allows injection molding of «green parts» with minimal volume shrinkage. The results of a comparative analysis of the compaction of feedstock with a polymer binder catalytic and solution-thermal type of removal are presented.

SCHMELZMETALL HOVADUR CCZ

Alloy Digest ◽  
2020 ◽  
Vol 69 (9) ◽  
Keyword(s):  
Thermal Conductivity ◽  
Spot Welding ◽  
Zirconium Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Softening Temperature ◽  
Aged Condition ◽  
Heat Treated ◽  
High Softening Temperature ◽  
Made In

Abstract Schmelzmetall Hovadur CCZ is a heat-treatable, copper-chromium-zirconium alloy. In the solution heat-treated and artificially aged condition, this alloy exhibits high thermal and electrical conductivity along with high strength and a high softening temperature. Hovadur CCZ evolved from CuCr1 (CW105C), a precipitation-hardenable alloy first made in the 1930s for spot welding electrodes, for which strength and hardness at temperatures up to 500 °C (930 °F), as well as good electrical and thermal conductivity, are essential. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on forming, heat treating, machining, and joining. Filing Code: Cu-912. Producer or source: Schmelzmetall AG.

CARPENTER LOW EXPANSION 39

Alloy Digest ◽  
2004 ◽  
Vol 53 (10) ◽  
Keyword(s):  
Thermal Expansion ◽  
Physical Properties ◽  
Tensile Properties ◽  
Iron Alloy ◽  
Nickel Iron ◽  
Temperature Ranges ◽  
Technology Corporation ◽  
Carpenter Technology Corporation ◽  
Nickel Iron Alloy ◽  
Low Rate

Abstract Carpenter Low Expansion 39 alloy is a 39% nickel iron alloy with a low rate of thermal expansion useful to temperature ranges up to 316 deg C (600 deg F). This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on joining. Filing Code: FE-132. Producer or source: Carpenter Technology Corporation.

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