Hydroxyl Formation Mechanisms and Models in High-Altitude Hypersonic Flows

AIAA Journal ◽  
2003 ◽  
Vol 41 (7) ◽  
pp. 1323-1331 ◽  
Author(s):  
N. E. Gimelshein ◽  
D. A. Levin ◽  
S. F. Gimelshein
Author(s):  
Federico Bianchi ◽  
Victoria A. Sinclair ◽  
Diego Aliaga ◽  
Qiaozhi Zha ◽  
Wiebke Scholz ◽  
...  

AbstractThis paper presents an introduction to the Southern hemisphere high altitude experiment on particle nucleation and growth (SALTENA). This field campaign took place between December 2017 and June 2018 (wet to dry season) at Chacaltaya (CHC), a GAW (Global Atmosphere Watch) station located at 5240 m a.s.l. in the Bolivian Andes. Concurrent measurements were conducted at two additional sites in El Alto (4000 m a.s.l.) and La Paz (3600 m a.s.l.). The overall goal of the campaign was to identify the sources, understand the formation mechanisms and transport, and characterize the properties of aerosol at these stations. State-of-the-art instruments were brought to the station complementing the ongoing permanent GAW measurements, to allow a comprehensive description of the chemical species of anthropogenic and biogenic origin impacting the station and contributing to new particle formation. In this overview we first provide an assessment of the complex meteorology, air mass origin, and boundary layer – free troposphere interactions during the campaign using a 6-month high-resolution WRF (Weather Research and Forecasting) simulation coupled with FLEXPART (FLEXible PARTicle dispersion model). We then show some of the research highlights from the campaign, including i) chemical transformation processes of anthropogenic pollution while the air masses are transported to the CHC station from the metropolitan area of La Paz/El Alto, ii) volcanic emissions as an important source of atmospheric sulfur compounds in the region, iii) the characterization of the compounds involved in new particle formation, and iv) the identification of long-range transported compounds from the Pacific or the Amazon basin. We conclude the article with a presentation of future research foci. The SALTENA dataset highlights the importance of comprehensive observations in strategic high-altitude locations, especially the undersampled Southern Hemisphere.


1994 ◽  
Vol 144 ◽  
pp. 365-367
Author(s):  
E. V. Kononovich ◽  
O. B. Smirnova ◽  
P. Heinzel ◽  
P. Kotrč

AbstractThe Hα filtergrams obtained at Tjan-Shan High Altitude Observatory near Alma-Ata (Moscow University Station) were measured in order to specify the bright rims contrast at different points along the line profile (0.0; ± 0.25; ± 0.5; ± 0.75 and ± 1.0 Å). The mean contrast value in the line center is about 25 percent. The bright rims interpretation as the bases of magnetic structures supporting the filaments is suggested.


Author(s):  
D. M. Davies ◽  
R. Kemner ◽  
E. F. Fullam

All serious electron microscopists at one time or another have been concerned with the cleanliness and freedom from artifacts of thin film specimen support substrates. This is particularly important where there are relatively few particles of a sample to be found for study, as in the case of micrometeorite collections. For the deposition of such celestial garbage through the use of balloons, rockets, and aircraft, the thin film substrates must have not only all the attributes necessary for use in the electron microscope, but also be able to withstand rather wide temperature variations at high altitude, vibration and shock inherent in the collection vehicle's operation and occasionally an unscheduled violent landing.Nitrocellulose has been selected as a film forming material that meets these requirements yet lends itself to a relatively simple clean-up procedure to remove particulate contaminants. A 1% nitrocellulose solution is prepared by dissolving “Parlodion” in redistilled amyl acetate from which all moisture has been removed.


Author(s):  
B. Cunningham ◽  
D.G. Ast

There have Been a number of studies of low-angle, θ < 4°, [10] tilt boundaries in the diamond lattice. Dislocations with Burgers vectors a/2<110>, a/2<112>, a<111> and a<001> have been reported in melt-grown bicrystals of germanium, and dislocations with Burgers vectors a<001> and a/2<112> have been reported in hot-pressed bicrystals of silicon. Most of the dislocations were found to be dissociated, the dissociation widths being dependent on the tilt angle. Possible dissociation schemes and formation mechanisms for the a<001> and a<111> dislocations from the interaction of lattice dislocations have recently been given.The present study reports on the dislocation structure of a 10° [10] tilt boundary in chemically vapor deposited silicon. The dislocations in the boundary were spaced about 1-3nm apart, making them difficult to resolve by conventional diffraction contrast techniques. The dislocation structure was therefore studied by the lattice-fringe imaging technique.


Author(s):  
Eal H. Lee ◽  
Helmut Poppa

The formation of thin films of gold on mica has been studied in ultra-high vacuum (5xl0-10 torr) . The mica substrates were heat-treated for 24 hours at 375°C, cleaved, and annealed for 15 minutes at the deposition temperature of 300°C prior to deposition. An impingement flux of 3x1013 atoms cm-2 sec-1 was used. These conditions were found to give high number densities of multiple twin particles and are based on a systematic series of nucleation experiments described elsewhere. Individual deposits of varying deposition time were made and examined by bright and dark field TEM after "cleavage preparation" of highly transparent specimens. In the early stages of growth, the films generally consist of small particles which are either single crystals or multiply twinned; a strong preference for multiply twinned particles was found whenever the particle number densities were high. Fig. 1 shows the stable cluster density ns and the variation with deposition time of multiple twin particle and single crystal particle densities, respectively. Corresponding micrographs and diffraction patterns are shown in Fig. 2.


1966 ◽  
Vol 118 (2) ◽  
pp. 132-138 ◽  
Author(s):  
J. S. Sanders
Keyword(s):  

Author(s):  
Renato Contini ◽  
Rudolfs Drillis ◽  
Lawrence Slote
Keyword(s):  

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