scholarly journals Thermal and Hydraulic Effects of Coke Deposit in Hydrocarbon Pyrolysis Process

2012 ◽  
Vol 26 (1) ◽  
pp. 57-65 ◽  
Author(s):  
N. Gascoin ◽  
G. Abraham ◽  
P. Gillard
Keyword(s):  
Pyrolysis Process ◽  
Coke Deposit ◽  
Hydrocarbon Pyrolysis

Unit for modeling hydrocarbon pyrolysis process

1975 ◽  
Vol 11 (10) ◽  
pp. 789-792
Author(s):  
V. A. Men'shikov ◽  
Yu. G. Fal'kovich ◽  
T. N. Mukhina
Keyword(s):  
Pyrolysis Process ◽  
Hydrocarbon Pyrolysis

Mathematical Modeling of the Unsteady Hydrocarbon Pyrolysis Process

2019 ◽  
Vol 59 (2) ◽  
pp. 151-159 ◽  
Author(s):  
F. A. Samedov ◽  
A. Yu. Morozov ◽  
N. A. Samoilov ◽  
T. R. Prosochkina
Keyword(s):  
Mathematical Modeling ◽  
Pyrolysis Process ◽  
Hydrocarbon Pyrolysis

Valorisation of by-Products/Waste of Agro-Food Industry by the Pyrolysis Process

2016 ◽  
Vol 3 (1) ◽  
pp. 1-11 ◽  
Author(s):  
D. Fino ◽  
◽  
Y.S. Camacho ◽  
S Bensaid ◽  
B. Ruggeri ◽  
...  
Keyword(s):  
Food Industry ◽  
Pyrolysis Process ◽  
By Products

Theoretical Computations on the Pyrolysis of Alkyl (dithio)acetates

2020 ◽  
Vol 17 (3) ◽  
pp. 224-233
Author(s):  
Xun Zhu ◽  
Chen Jian ◽  
Xiuqin Zhou ◽  
Abdullah M. Asiri ◽  
Khalid A. Alamry ◽  
...  
Keyword(s):  
Transition States ◽  
Membered Ring ◽  
Pyrolysis Process ◽  
Alkyl Esters ◽  
Charge Distributions ◽  
Theoretical Analyses

The pyrolysis of methyl alkyl esters I to III and dithioesters IV to VI were theoretically calculated. All possible pyrolysis paths were considered. Both esters and dithioesters presented three potential paths via six-, four- and five-membered ring transition states, respectively. The calculation processes were calculated using MP2/6-31G(d) set. In-depth theoretical analyses were also presented, including NBO related analyses, synchronicities, and charge distributions, to reveal the detailed pyrolysis process.

Jellyfish-like few-layer graphene nanoflakes: high paramagnetic response alongside increased interlayer interaction

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Alexander Ulyanov ◽  
Dmitrii Stolbov ◽  
Serguei Savilov
Keyword(s):  
Photoelectron Spectroscopy ◽  
High Sensitivity ◽  
Paramagnetic Centers ◽  
Interlayer Interaction ◽  
Paramagnetic Resonance ◽  
X Ray ◽  
Graphene Nanoflakes ◽  
Few Layer Graphene ◽  
Electron Paramagnetic ◽  
Hydrocarbon Pyrolysis

Abstract Jellyfish-like graphene nanoflakes (GNF), prepared by hydrocarbon pyrolysis, are studied with electron paramagnetic resonance (EPR) method. The results are supported by X-ray photoelectron spectroscopy (XPS) data. Oxidized (GNFox) and N-doped oxidized (N-GNFox) flakes exhibit an extremely high EPR response associated with a large interlayer interaction which is caused by the structure of nanoflakes and layer edges reached by oxygen. The GNFox and N-GNFox provide the localized and mobile paramagnetic centers which are silent in the pristine (GNF p ) and N-doped (N-GNF) samples. The change in the relative intensity of the line corresponding to delocalized electrons is parallel with the number of radicals in the quaternary N-group. The environment of localized and mobile electrons is different. The results can be important in GNF synthesis and for explanation of their features in applications, especially, in devices with high sensitivity to weak electromagnetic field.

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