CIE 198-SP2:2018 Determination of Measurement Uncertainties in Photometry Supplement 2: Spectral measurements and derivative quantities

2018 ◽  
Author(s):  
J. Gardener ◽  
T. Bergen ◽  
U. Krueger ◽  
R. Young
Keyword(s):  
Spectral Measurements ◽  
Measurement Uncertainties

scholarly journals Development and Validation of Optical Methods for Zeta Potential Determination of Silica and Polystyrene Particles in Aqueous Suspensions

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 290
Author(s):  
Yannic Ramaye ◽  
Marta Dabrio ◽  
Gert Roebben ◽  
Vikram Kestens
Keyword(s):  
Zeta Potential ◽  
Particle Tracking ◽  
Colloidal Stability ◽  
Optical Methods ◽  
Intermediate Precision ◽  
Electrophoretic Light Scattering ◽  
Measurement Uncertainties ◽  
Development And Validation ◽  
Direct Implementation

Zeta potential is frequently used to examine the colloidal stability of particles and macromolecules in liquids. Recently, it has been suggested that zeta potential can also play an important role for grouping and read-across of nanoforms in a regulatory context. Although the measurement of zeta potential is well established, only little information is reported on key metrological principles such as validation and measurement uncertainties. This contribution presents the results of an in-house validation of the commonly used electrophoretic light scattering (ELS) and the relatively new particle tracking analysis (PTA) methods. The performance characteristics were assessed by analyzing silica and polystyrene reference materials. The ELS and PTA methods are robust and have particle mass working ranges of 0.003 mg/kg to 30 g/kg and 0.03 mg/kg to 1.5 mg/kg, respectively. Despite different measurement principles, both methods exhibit similar uncertainties for repeatability (2%), intermediate precision (3%) and trueness (4%). These results confirm that the developed methods can accurately measure the zeta potential of silica and polystyrene particles and can be transferred to other laboratories that analyze similar types of samples. If direct implementation is impossible, the elaborated methodologies may serve as a guide to help laboratories validating their own methods.

scholarly journals The Importance of Motions that Accompany Those Occurring Along the Reaction Coordinate

2015 ◽  
Vol 68 (8) ◽  
pp. 1202 ◽  
Author(s):  
Jeffrey R. Reimers
Keyword(s):  
Reaction Coordinate ◽  
Spectral Measurements ◽  
Visible Absorption ◽  
Photochemical Process ◽  
New Approach ◽  
Energy Devices ◽  
Adiabatic Theory ◽  
Core Theory ◽  
Basic Ideas

The reaction coordinate is a well known quantity used to define the motions critical to chemical reactions, but many other motions always accompany it. These other motions are typically ignored but this is not always possible. Sometimes it is not even clear as to which motions comprise the reaction coordinate: spectral measurements that one may assume are dominated by the reaction coordinate could instead be dominated by the accompanying modes. Examples of different scenarios are considered. The assignment of the visible absorption spectrum of chlorophyll-a was debated for 50 years, with profound consequences for the understanding of how light energy is transported and harvested in natural and artificial solar-energy devices. We recently introduced a new, comprehensive, assignment, the centrepiece of which was determination of the reaction coordinate for an unrecognized photochemical process. The notion that spectroscopy and reactivity are so closely connected comes directly from Hush’s adiabatic theory of electron-transfer reactions. Its basic ideas are reviewed, similarities to traditional chemical theories drawn, key analytical results described, and the importance of the accompanying modes stressed. Also highlighted are recent advances that allow this theory to be applied to general transformations including isomerization processes, hybridization, aromaticity, hydrogen bonding, and understanding why the properties of first-row molecules such as NH3 (bond angle 108°) are so different to those of PH3–BiH3 (bond angles 90–93°). Historically, the question of what is the reaction coordinate and what is just an accompanying motion has not commonly been at the forefront of attention. In our new approach in which all chemical processes are described using the same core theory, this question becomes thrust forward as always being the most important qualitative feature to determine.

scholarly journals Measurement Uncertainties Encountered During Gas Turbine Driven Compressor Field Testing

1998 ◽  
Author(s):  
Klaus Brun ◽  
Rainer Kurz
Keyword(s):  
Measurement Uncertainty ◽  
Gas Turbine ◽  
Field Test ◽  
Equations Of State ◽  
Accurate Determination ◽  
Field Testing ◽  
Significant Implication ◽  
Test Results ◽  
Measurement Uncertainties

Field testing of gas turbine compressor packages requires the accurate determination of efficiency, capacity, head, power and fuel flow in sometimes less than ideal working environments. Nonetheless, field test results have significant implication for the compressor and gas turbine manufacturers and their customers. Economic considerations demand that the performance and efficiency of an installation are verified to assure a project’s return on investment. Thus, for the compressor and gas turbine manufacturers, as well as for the end-user, an accurate determination of the field performance is of vital interest. This paper describes an analytic method to predict the measurement uncertainty and, thus, the accuracy, of field test results for gas turbine driven compressors. Namely, a method is presented which can be employed to verify the validity of field test performance results. The equations governing the compressor and gas turbine performance uncertainties are rigorously derived and results are numerically compared to actual field test data. Typical field test measurement uncertainties are presented for different sets of instrumentation. Test parameters that correlate to the most significant influence on the performance uncertainties are identified and suggestions are provided on how to minimize their measurement errors. The effect of different equations of state on the calculated performance is also discussed. Results show that compressor efficiency uncertainties can be unacceptably high when some basic rules for accurate testing are violated. However, by following some simple measurement rules and maintaining commonality of the gas equations of state, the overall compressor package performance measurement uncertainty can be limited and meaningful results can be achieved.

Determination of bulk and surface transport properties by photocurrent spectral measurements

2000 ◽  
Vol 71 (3) ◽  
pp. 305-310 ◽  
Author(s):  
A. Castaldini ◽  
D. Cavalcoli ◽  
A. Cavallini
Keyword(s):  
Transport Properties ◽  
Spectral Measurements ◽  
Surface Transport
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