scholarly journals Scaling resistance of special high performance composites with burnt clay additive

Author(s):  
P. Reiterman
2016 ◽  
Vol 41 (1) ◽  
pp. 54-64 ◽  
Author(s):  
Anton Trník ◽  
Lenka Scheinherrová ◽  
Tereza Kulovaná ◽  
Pavel Reiterman ◽  
Eva Vejmelková ◽  
...  

1996 ◽  
Vol 23 (6) ◽  
pp. 1260-1271
Author(s):  
Richard Gagné ◽  
Yvon Latreille ◽  
Jacques Marchand

In Canada, high-performance concretes (HPCs) are increasingly used in construction and repair, particularly for its durability, which is distinctly superior compared with ordinary concrete. The current tendency is to provide for a spacing factor of air bubbles lower than 230 μm in all HPCs that are subjected to freeze–thaw cycles. This choice is basically the outcome of an ongoing controversy as to the necessity of providing a good network of entrained air bubbles to protect HPCs against freeze–thaw cycles. In the future, the optimal use of HPC will depend, among other factors, on a better understanding of minimal requirements regarding the characteristics of air voids to ensure a good behavior of HPCs under freeze–thaw cycles. The results of the investigation reported herein show that a spacing factor lower than approximately 500 μm can be sufficient to ensure a good resistance of HPCs to scaling. It is also shown that surface trawling, slump, and set-retarding agents have only secondary effects on the scaling resistance of HPCs. Silica fume and membrane curing have allowed to improve significantly the scaling resistance of the HPCs under investigation. Key words: high-performance concrete, durability, scaling, set-retarding agent, silica fume, surface finishing, curing, pumping, entrained air, spacing factor.


1996 ◽  
Vol 23 (5) ◽  
pp. 1070-1080 ◽  
Author(s):  
J. Marchand ◽  
M. Pigeon ◽  
R. Gagné ◽  
S. Jacobsen ◽  
E. J. Sellevold

A literature survey of the frost resistance of high-performance concrete (HPC) is presented in this paper. Various aspects of HPC behaviour to frost, such as ice formation, resistance to internal microcracking and scaling, and air entrainment were discussed. The survey clearly indicates that the volume of ice formed in the 0 to −20 °C range is significantly reduced by the low porosity of HPC. This reduction is often accompanied by a significant improvement of the scaling resistance. Some studies even reveal the existence of a critical water/binder ratio below which air entrainment would not be required as a protection against this type of deterioration. However, this critical water/binder ratio would not apply to internal cracking. In many instances, HPC with no air entrainment were resistant to scaling but susceptible to internal microcracking. The behaviour of HPC to frost is discussed from both theoretical and applied points of view. Key words: frost resistance, high-performance concrete, ice formation, internal microcracking, scaling.


Author(s):  
A. V. Crewe ◽  
M. Isaacson ◽  
D. Johnson

A double focusing magnetic spectrometer has been constructed for use with a field emission electron gun scanning microscope in order to study the electron energy loss mechanism in thin specimens. It is of the uniform field sector type with curved pole pieces. The shape of the pole pieces is determined by requiring that all particles be focused to a point at the image slit (point 1). The resultant shape gives perfect focusing in the median plane (Fig. 1) and first order focusing in the vertical plane (Fig. 2).


Author(s):  
N. Yoshimura ◽  
K. Shirota ◽  
T. Etoh

One of the most important requirements for a high-performance EM, especially an analytical EM using a fine beam probe, is to prevent specimen contamination by providing a clean high vacuum in the vicinity of the specimen. However, in almost all commercial EMs, the pressure in the vicinity of the specimen under observation is usually more than ten times higher than the pressure measured at the punping line. The EM column inevitably requires the use of greased Viton O-rings for fine movement, and specimens and films need to be exchanged frequently and several attachments may also be exchanged. For these reasons, a high speed pumping system, as well as a clean vacuum system, is now required. A newly developed electron microscope, the JEM-100CX features clean high vacuum in the vicinity of the specimen, realized by the use of a CASCADE type diffusion pump system which has been essentially improved over its predeces- sorD employed on the JEM-100C.


Author(s):  
John W. Coleman

In the design engineering of high performance electromagnetic lenses, the direct conversion of electron optical design data into drawings for reliable hardware is oftentimes difficult, especially in terms of how to mount parts to each other, how to tolerance dimensions, and how to specify finishes. An answer to this is in the use of magnetostatic analytics, corresponding to boundary conditions for the optical design. With such models, the magnetostatic force on a test pole along the axis may be examined, and in this way one may obtain priority listings for holding dimensions, relieving stresses, etc..The development of magnetostatic models most easily proceeds from the derivation of scalar potentials of separate geometric elements. These potentials can then be conbined at will because of the superposition characteristic of conservative force fields.


Author(s):  
J W Steeds ◽  
R Vincent

We review the analytical powers which will become more widely available as medium voltage (200-300kV) TEMs with facilities for CBED on a nanometre scale come onto the market. Of course, high performance cold field emission STEMs have now been in operation for about twenty years, but it is only in relatively few laboratories that special modification has permitted the performance of CBED experiments. Most notable amongst these pioneering projects is the work in Arizona by Cowley and Spence and, more recently, that in Cambridge by Rodenburg and McMullan.There are a large number of potential advantages of a high intensity, small diameter, focussed probe. We discuss first the advantages for probes larger than the projected unit cell of the crystal under investigation. In this situation we are able to perform CBED on local regions of good crystallinity. Zone axis patterns often contain information which is very sensitive to thickness changes as small as 5nm. In conventional CBED, with a lOnm source, it is very likely that the information will be degraded by thickness averaging within the illuminated area.


Author(s):  
Klaus-Ruediger Peters

A new generation of high performance field emission scanning electron microscopes (FSEM) is now commercially available (JEOL 890, Hitachi S 900, ISI OS 130-F) characterized by an "in lens" position of the specimen where probe diameters are reduced and signal collection improved. Additionally, low voltage operation is extended to 1 kV. Compared to the first generation of FSEM (JE0L JSM 30, Hitachi S 800), which utilized a specimen position below the final lens, specimen size had to be reduced but useful magnification could be impressively increased in both low (1-4 kV) and high (5-40 kV) voltage operation, i.e. from 50,000 to 200,000 and 250,000 to 1,000,000 x respectively.At high accelerating voltage and magnification, contrasts on biological specimens are well characterized1 and are produced by the entering probe electrons in the outmost surface layer within -vl nm depth. Backscattered electrons produce only a background signal. Under these conditions (FIG. 1) image quality is similar to conventional TEM (FIG. 2) and only limited at magnifications >1,000,000 x by probe size (0.5 nm) or non-localization effects (%0.5 nm).


Author(s):  
G.K.W. Balkau ◽  
E. Bez ◽  
J.L. Farrant

The earliest account of the contamination of electron microscope specimens by the deposition of carbonaceous material during electron irradiation was published in 1947 by Watson who was then working in Canada. It was soon established that this carbonaceous material is formed from organic vapours, and it is now recognized that the principal source is the oil-sealed rotary pumps which provide the backing vacuum. It has been shown that the organic vapours consist of low molecular weight fragments of oil molecules which have been degraded at hot spots produced by friction between the vanes and the surfaces on which they slide. As satisfactory oil-free pumps are unavailable, it is standard electron microscope practice to reduce the partial pressure of organic vapours in the microscope in the vicinity of the specimen by using liquid-nitrogen cooled anti-contamination devices. Traps of this type are sufficient to reduce the contamination rate to about 0.1 Å per min, which is tolerable for many investigations.


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