scholarly journals SVD-based principal component analysis of geochemical data

2005 ◽  
Vol 3 (4) ◽  
pp. 731-741 ◽  
Author(s):  
Petr Praus

AbstractPrincipal Component Analysis (PCA) was used for the mapping of geochemical data. A testing data matrix was prepared from the chemical and physical analyses of the coals altered by thermal and oxidation effects. PCA based on Singular Value Decomposition (SVD) of the standardized (centered and scaled by the standard deviation) data matrix revealed three principal components explaining 85.2% of the variance. Combining the scatter and components weights plots with knowledge of the composition of tested samples, the coal samples were divided into seven groups depending on the degree of their oxidation and thermal alteration.The PCA findings were verified by other multivariate methods. The relationships among geochemical variables were successfully confirmed by Factor Analysis (FA). The data structure was also described by the Average Group dendrogram using Euclidean distance. The found sample clusters were not defined so clearly as in the case of PCA. It can be explained by the PCA filtration of the data noise.

1990 ◽  
Vol 55 (1) ◽  
pp. 55-62 ◽  
Author(s):  
Drahomír Hnyk

The principal component analysis has been applied to a data matrix formed by 7 usual substituent constants for 38 substituents. Three factors are able to explain 99.4% cumulative proportion of total variance. Several rotations have been carried out for the first two factors in order to obtain their physical meaning. The first factor is related to the resonance effect, whereas the second one expresses the inductive effect, and both together describe 97.5% cumulative proportion of total variance. Their mutual orthogonality does not directly follow from the rotations carried out. With the help of these factors the substituents are divided into four main classes, and some of them assume a special position.


2010 ◽  
Vol 4 (1-2) ◽  
pp. 239-247 ◽  
Author(s):  
Emmanuel A. Ariyibi ◽  
Samuel L. Folami ◽  
Bankole D. Ako ◽  
Taye R. Ajayi ◽  
Adebowale O. Adelusi

2016 ◽  
Vol 19 (03) ◽  
pp. 382-390 ◽  
Author(s):  
Martina Siena ◽  
Alberto Guadagnini ◽  
Ernesto Della Rossa ◽  
Andrea Lamberti ◽  
Franco Masserano ◽  
...  

Summary We present and test a new screening methodology to discriminate among alternative and competing enhanced-oil-recovery (EOR) techniques to be considered for a given reservoir. Our work is motivated by the observation that, even if a considerable variety of EOR techniques was successfully applied to extend oilfield production and lifetime, an EOR project requires extensive laboratory and pilot tests before fieldwide implementation and preliminary assessment of EOR potential in a reservoir is critical in the decision-making process. Because similar EOR techniques may be successful in fields sharing some global features, as basic discrimination criteria, we consider fluid (density and viscosity) and reservoir-formation (porosity, permeability, depth, and temperature) properties. Our approach is observation-driven and grounded on an exhaustive database that we compiled after considering worldwide EOR field experiences. A preliminary reduction of the dimensionality of the parameter space over which EOR projects are classified is accomplished through principal-component analysis (PCA). A screening of target analogs is then obtained by classification of documented EOR projects through a Bayesian-clustering algorithm. Considering the cluster that includes the EOR field under evaluation, an intercluster refinement is then accomplished by ordering cluster components on the basis of a weighted Euclidean distance from the target field in the (multidimensional) parameter space. Distinctive features of our methodology are that (a) all screening analyses are performed on the database projected onto the space of principal components (PCs) and (b) the fraction of variance associated with each PC is taken as weight of the Euclidean distance that we determine. As a test bed, we apply our approach on three fields operated by Eni. These include light-, medium-, and heavy-oil reservoirs, where gas, chemical, and thermal EOR projects were, respectively, proposed. Our results are (a) conducive to the compilation of a broad and extensively usable database of EOR settings and (b) consistent with the field observations related to the three tested and already planned/implemented EOR methodologies, thus demonstrating the effectiveness of our approach.


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