Thermodynamic Model For Reaction Rim Growth: Interface Reaction and Diffusion Control

2011 ◽  
Vol 311 (6) ◽  
pp. 517-527 ◽  
Author(s):  
R. Abart ◽  
E. Petrishcheva
Keyword(s):  
Thermodynamic Model ◽  
Interface Reaction ◽  
Diffusion Control ◽  
Growth Interface ◽  
Rim Growth ◽  
And Diffusion ◽  
Reaction And Diffusion

Effect of interface reaction and diffusion on stress-oxidation coupling at high temperature

2018 ◽  
Vol 123 (15) ◽  
pp. 155301 ◽  
Author(s):  
Mengkun Yue ◽  
Xuelin Dong ◽  
Xufei Fang ◽  
Xue Feng
Keyword(s):  
High Temperature ◽  
Interface Reaction ◽  
And Diffusion ◽  
Reaction And Diffusion ◽  
Oxidation Coupling

Interfacial reaction and diffusion control between SiC and F82H steel

2010 ◽  
Vol 85 (7-9) ◽  
pp. 992-997 ◽  
Author(s):  
Zhihong Zhong ◽  
Tatsuya Hinoki ◽  
Yi-Hyun Park ◽  
Akira Kohyama
Keyword(s):  
Interfacial Reaction ◽  
Diffusion Control ◽  
And Diffusion ◽  
Reaction And Diffusion

Solid-State Reaction and Diffusion Behaviors of CaFe2O4 and TiO2 at 1373 K to 1473 K

2021 ◽  
Author(s):  
Mingrui Yang ◽  
Junyi Xiang ◽  
Chenguang Bai ◽  
Xuangeng Zhou ◽  
Zhongci Liu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
And Diffusion ◽  
Diffusion Behaviors ◽  
Reaction And Diffusion

Decoupling Electrochemical Reaction and Diffusion Processes in Ionically-Conductive Solids on the Nanometer Scale

ACS Nano ◽  
2010 ◽  
Vol 4 (12) ◽  
pp. 7349-7357 ◽  
Author(s):  
Nina Balke ◽  
Stephen Jesse ◽  
Yoongu Kim ◽  
Leslie Adamczyk ◽  
Ilia N. Ivanov ◽  
...  
Keyword(s):  
Diffusion Processes ◽  
Electrochemical Reaction ◽  
Nanometer Scale ◽  
And Diffusion ◽  
Reaction And Diffusion

Oxidation of Copper Sulfides in Aqueous Ammonia. III. Kinetic Characteristics

1979 ◽  
Vol 32 (12) ◽  
pp. 2597 ◽  
Author(s):  
AO Filmer ◽  
AJ Parker ◽  
BW Clare ◽  
LGB Wadley
Keyword(s):  
Aqueous Ammonia ◽  
Sulfide Oxidation ◽  
Metal Sulfide ◽  
Diffusion Control ◽  
Sulfate Ions ◽  
Kinetics Of Oxidation ◽  
Copper Sulfides ◽  
Shrinking Core ◽  
Kinetics Of ◽  
And Diffusion

The kinetics of oxidation with oxygen of chalcocite, Cu2S, to CuS in buffered aqueous ammonia at pH 10.5 at 30� can be modeled approximately by a shrinking core of Cu2S within a thickening shell of CuxS (x ≥ 1). The Cu2S core offers partial cathodic protection to the CuxS and diffusion of Cu+ through CuxS controls the rate of reaction. The kinetics of oxidation of covellite, CuS, to Cu2+, sulfur and sulfate ions in the same solvent can be modeled by a shrinking core of CuS surrounded by a shrinking sphere of CuyS (y < 1) which is much less effectively protected cathodically by the CuS core. Oxidation of CuS is subject to mixed chemical and diffusion control. Rates of oxidation of NiS and of CuS, in the presence and absence of tetrachloroethene and ammonium sulfate, show that, whether sulfur is a major oxidation product or not, the presence of sulfur has very little, if any, influence on the rate or mechanism of oxidation. This is contrary to current ideas on metal sulfide oxidation.

scholarly journals Reaction-Diffusion Systems: Self-Balancing Diffusion and the Use of the Extent of Reaction as a Descriptor of Reaction Kinetics

2019 ◽  
Author(s):  
Miloslav Pekař
Keyword(s):  
Reaction Kinetics ◽  
Reaction Diffusion ◽  
Reaction Diffusion Systems ◽  
Diffusion Systems ◽  
And Diffusion ◽  
Reaction And Diffusion

Self-balancing diffusion is a concept which restricts the introduction of extents of reactions. This concept is analyzed in detail for mass- and molar-based balances of reaction-diffusion mixtures, in relation to non-self-balancing cases, and with respect to its practical consequences. A note on a recent generalization of the concept of reaction and diffusion extents is also included.<br>

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