Mineral solubility and hydrous melting relations in the deep earth: Analysis of some binary A H2O system pressure-temperature-composition topologies

2007 ◽  
Vol 307 (5) ◽  
pp. 833-855 ◽  
Author(s):  
A. C. Hack ◽  
J. Hermann ◽  
J. A. Mavrogenes
Keyword(s):  
Mineral Solubility ◽  
Hydrous Melting ◽  
System Pressure ◽  
Deep Earth ◽  
Melting Relations

A SYSTEM FOR PROTECTING AN OIL DIFFUSION PUMP AGAINST FAILURE OF THE MECHANICAL FORE PUMP, COOLING WATER, OR ELECTRICITY

1970 ◽  
Vol 28 ◽  
pp. 344-345
Author(s):  
W. C. Bigelow ◽  
F. B. Drogosz ◽  
S. Nitschke
Keyword(s):  
High Vacuum ◽  
Cooling Water ◽  
Effective Protection ◽  
Pump Line ◽  
Diffusion Pump ◽  
System Pressure ◽  
Control Relay ◽  
Vacuum Systems ◽  
Vacuum Gage ◽  
Pressure Switch

High vacuum systems with oil diffusion pumps usually have a pressure switch to protect against Insufficient cooling water; however, If left unattended for long periods of time, failure of the mechanical fore pump can occur with equally serious results. The device shown schematically in Fig. 1 has been found to give effective protection against both these failures, yet it is inexpensive and relatively simple to build and operate.With this system, pressure in the fore pump line is measured by thermocouple vacuum gage TVG (CVC G.TC-004) whose output is monitored by meter relay MRy (Weston 1092 Sensitrol) which is set to close if the pressure rises above about 0.2 torr. This energizes control relay CRy (Potter & Brumfield KA5Y 120VAC SPDT) cutting off power to solenoid-operated fore line valve Vf (Cenco 94280-4 Norm. Closed) which closes to prevent further leakage of air into the diffusion pump

Water Gas May Not Shift in Deep Earth

2020 ◽  
Author(s):  
Nore Stolte ◽  
Junting Yu ◽  
Zixin Chen ◽  
Dimitri A. Sverjensky ◽  
Ding Pan
Keyword(s):  
Formic Acid ◽  
Upper Mantle ◽  
Free Energy Calculations ◽  
Water Gas Shift ◽  
Ab Initio Molecular Dynamics ◽  
Water Gas Shift Reaction ◽  
Carbon Carrier ◽  
Deep Earth ◽  
Shift Reaction ◽  
Water Gas

The water-gas shift reaction is a key reaction in Fischer-Tropsch-type synthesis, which is widely believed to generate hydrocarbons in the deep carbon cycle, but is little known at extreme pressure-temperature conditions found in Earth’s upper mantle. Here, we performed extensive ab initio molecular dynamics simulations and free energy calculations to study the water-gas shift reaction. We found the direct formation of formic acid out of CO and supercritical water at 10∼13 GPa and 1400 K without any catalyst. Contrary to the common assumption that formic acid or formate is an intermediate product, we found that HCOOH is thermodynamically more stable than the products of the water-gas shift reaction above 3 GPa and at 1000∼1400 K. Our study suggests that the water-gas shift reaction may not happen in Earth’s upper mantle, and formic acid or formate may be an important carbon carrier, participating in many geochemical processes in deep Earth.<br>

Compressor Issues for Hydrogen Production and Transmission Through a Long Distance Pipeline Network

2008 ◽  
Vol 59 (4) ◽  
Author(s):  
Fred Starr ◽  
Calin-Cristian Cormos ◽  
Evangelos Tzimas ◽  
Stathis Peteves
Keyword(s):  
Pressure Ratio ◽  
High Strength Steels ◽  
High Strength ◽  
Energy System ◽  
Pipeline System ◽  
Hydrogen Energy ◽  
Long Distance ◽  
System Pressure ◽  
Production Of Hydrogen ◽  
Plant Exit

A hydrogen energy system will require the production of hydrogen from coal-based gasification plants and its transmission through long distance pipelines at 70 � 100 bar. To overcome some problems of current gasifiers, which are limited in pressure capability, two options are explored, in-plant compression of the syngas and compression of the hydrogen at the plant exit. It is shown that whereas in-plant compression using centrifugal machines is practical, this is not a solution when compressing hydrogen at the plant exit. This is because of the low molecular weight of the hydrogen. It is also shown that if centrifugal compressors are to be used in a pipeline system, pressure drops will need to be restricted as even an advanced two-stage centrifugal compressor will be limited to a pressure ratio of 1.2. High strength steels are suitable for the in-plant compressor, but aluminium alloy will be required for a hydrogen pipeline compressor.

scholarly journals Water–Gas Shift Reaction Produces Formate at Extreme Pressures and Temperatures in Deep Earth Fluids

2021 ◽  
pp. 4292-4298
Author(s):  
Nore Stolte ◽  
Junting Yu ◽  
Zixin Chen ◽  
Dimitri A. Sverjensky ◽  
Ding Pan
Keyword(s):  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Deep Earth ◽  
Shift Reaction ◽  
Water Gas

scholarly journals Diamond formation in an electric field under deep Earth conditions

2021 ◽  
Vol 7 (4) ◽  
pp. eabb4644
Author(s):  
Yuri N. Palyanov ◽  
Yuri M. Borzdov ◽  
Alexander G. Sokol ◽  
Yuliya V. Bataleva ◽  
Igor N. Kupriyanov ◽  
...  
Keyword(s):  
Electric Fields ◽  
Lithospheric Mantle ◽  
Isotope Fractionation ◽  
Diamond Formation ◽  
Mantle Minerals ◽  
Electrochemical Processes ◽  
Mantle Mineral ◽  
Deep Earth ◽  
Diamond Crystallization ◽  
Global Carbon

Most natural diamonds are formed in Earth’s lithospheric mantle; however, the exact mechanisms behind their genesis remain debated. Given the occurrence of electrochemical processes in Earth’s mantle and the high electrical conductivity of mantle melts and fluids, we have developed a model whereby localized electric fields play a central role in diamond formation. Here, we experimentally demonstrate a diamond crystallization mechanism that operates under lithospheric mantle pressure-temperature conditions (6.3 and 7.5 gigapascals; 1300° to 1600°C) through the action of an electric potential applied across carbonate or carbonate-silicate melts. In this process, the carbonate-rich melt acts as both the carbon source and the crystallization medium for diamond, which forms in assemblage with mantle minerals near the cathode. Our results clearly demonstrate that electric fields should be considered a key additional factor influencing diamond crystallization, mantle mineral–forming processes, carbon isotope fractionation, and the global carbon cycle.

Application of neural networks in predictions of brake wear particulate matter emission

2021 ◽  
pp. 095440702110363
Author(s):  
Saša Vasiljević ◽  
Jasna Glišović ◽  
Nadica Stojanović ◽  
Ivan Grujić
Keyword(s):  
Neural Network ◽  
Neural Networks ◽  
Particulate Matter ◽  
Traffic Control ◽  
World Health ◽  
Vehicle Speed ◽  
System Pressure ◽  
The Neural Network ◽  
Vehicle Systems ◽  
Brake Wear

According to the World Health Organization, air pollution with PM10 and PM2.5 (PM-particulate matter) is a significant problem that can have serious consequences for human health. Vehicles, as one of the main sources of PM10 and PM2.5 emissions, pollute the air and the environment both by creating particles by burning fuel in the engine, and by wearing of various elements in some vehicle systems. In this paper, the authors conducted the prediction of the formation of PM10 and PM2.5 particles generated by the wear of the braking system using a neural network (Artificial Neural Networks (ANN)). In this case, the neural network model was created based on the generated particles that were measured experimentally, while the validity of the created neural network was checked by means of a comparative analysis of the experimentally measured amount of particles and the prediction results. The experimental results were obtained by testing on an inertial braking dynamometer, where braking was performed in several modes, that is under different braking parameters (simulated vehicle speed, brake system pressure, temperature, braking time, braking torque). During braking, the concentration of PM10 and PM2.5 particles was measured simultaneously. The total of 196 measurements were performed and these data were used for training, validation, and verification of the neural network. When it comes to simulation, a comparison of two types of neural networks was performed with one output and with two outputs. For each type, network training was conducted using three different algorithms of backpropagation methods. For each neural network, a comparison of the obtained experimental and simulation results was performed. More accurate prediction results were obtained by the single-output neural network for both particulate sizes, while the smallest error was found in the case of a trained neural network using the Levenberg-Marquardt backward propagation algorithm. The aim of creating such a prediction model is to prove that by using neural networks it is possible to predict the emission of particles generated by brake wear, which can be further used for modern traffic systems such as traffic control. In addition, this wear algorithm could be applied on other vehicle systems, such as a clutch or tires.

scholarly journals Solubility Product of Vanadinite Pb5(VO4)3Cl at 25 °C—A Comprehensive Approach to Incongruent Dissolution Modeling

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 135
Author(s):  
Justyna Topolska ◽  
Bartosz Puzio ◽  
Olaf Borkiewicz ◽  
Julia Sordyl ◽  
Maciej Manecki
Keyword(s):  
Nuclear Waste ◽  
Solubility Product ◽  
Geochemical Modeling ◽  
Incongruent Dissolution ◽  
Mineral Solubility ◽  
Actual Application ◽  
Universal Approach ◽  
Solubility Constant ◽  
First Time

Although vanadinite (Pb5(VO4)3Cl) occurs in abundance in various terrestrial geochemical systems of natural and anthropogenic origin and is seriously considered as a potential nuclear waste sequestering agent, its actual application is severely limited by a lack of understanding of its basic thermodynamic parameters. In this regard, the greatest challenge is posed by its incongruent dissolution, which is a pivotal hurdle for effective geochemical modeling. Our paper presents an universal approach for geochemical computing of systems undergoing incongruent dissolution which, along with unique, long-term experiments on vanadinites’ stability, allowed us to determine the mineral solubility constant. The dissolution experiments were carried out at pH = 3.5 for 12 years. Vanadinite has dissolved incongruently, continuously re-precipitating into chervetite (Pb2V2O7) with the two minerals remaining in mutual equilibrium until termination of the experiments. The empirically derived solubility constant Ksp,V,298 = 10–91.89 ± 0.05 of vanadinite was determined for the first time. The proposed modeling method is versatile and can be adopted to other mineral systems undergoing incongruent dissolution.

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