scholarly journals The interaction of microorganisms and the herbicides chlorthiamid and dichlobenil

1981 ◽  
Vol 53 (6) ◽  
pp. 341-390 ◽  
Author(s):  
Helvi Heinonen-Tanski
Keyword(s):  
Carbon Dioxide ◽  
Aromatic Ring ◽  
The Other ◽  
Arthrobacter Strain

The herbicides chlorthiamid and dichlobenil inhibited the growth of some actinomycetes in starch-casein medium. The effect of these herbicides on the other bacteria tested was insignificant. Chlorthiamid and dichlobenil arc slowly degradable herbicides. Bacteria such as Arthrobacter, unidentified coryneforms and Bacillus could degrade the herbicides by cometabolism. 2,6-Dichlorobenzamide, 2,6-dichlorobenzoic acid, carbon dioxide, chloride, a catechol compound and many unidentified compounds were found as metabolites. Arthrobacter strains capable for dechlorination could also cleave the aromatic ring, both processes occurring in aerated cultures. More than half of the chloride was liberated in three weeks at 28°C by the most active Arthrobacter strain.

Mechanism of decarboxylation of substituted salicylic acids. I. Kinetics in quinoline solution

1968 ◽  
Vol 46 (18) ◽  
pp. 2905-2909 ◽  
Author(s):  
G. E. Dunn ◽  
E. G. Janzen ◽  
W. Rodewald
Keyword(s):  
Carbon Dioxide ◽  
Aromatic Ring ◽  
Rate Constants ◽  
Substituent Effect ◽  
The Other ◽  
Carboxyl Group ◽  
Isokinetic Relationship ◽  
First Order ◽  
Hammett Relationship ◽  
Salicylic Acids

First-order rate constants for the decarboxylation of fourteen 4- and 5-substituted salicylic acids have been determined in quinoline solution in the temperature range 90–230 °C. Substituents have almost no effect on the rate constants, except those with large negative σ-constants: p-amino, p-hydroxy, p-ethoxy. The enthalpies and entropies of activation do not fit the isokinetic relationship, with the same three substituents deviating. It is suggested that the decarboxylation involves a preliminary ionization of the carboxyl group, followed by protonation of the aromatic ring of the anion so formed, and then loss of carbon dioxide. The isokinetic relationship fails because substituents affect all three steps differently, and the Hammett relationship fails because the substituent effect on the ionization is related to σ while that on the other two steps follows σ+. The three substituents which deviate are those for which σ and σ+ differ widely.

STUDIES ON THE BACTERIAL OXIDATION OF 2,3-BUTANEDIOL AND RELATED COMPOUNDS

1944 ◽  
Vol 22b (5) ◽  
pp. 140-153 ◽  
Author(s):  
R. Y. Stanier ◽  
Sybil B. Fratkin
Keyword(s):  
Carbon Dioxide ◽  
Aeromonas Hydrophila ◽  
The Other ◽  
Bacterial Oxidation ◽  
Aerobacter Aerogenes ◽  
Aerobic Conditions ◽  
Related Compounds

Aerobacter aerogenes, Aerobacillus polymyxa, and Aeromonas hydrophila, representatives of the three genera characterized by a butanediol fermentation, can all oxidize 2,3-butanediol under aerobic conditions. The configuration of the 2,3-butanediol has considerable bearing on its decomposability: Aerobacter aerogenes is inactive on the l-isomer, but attacks both meso- and d-isomers; Aeromonas hydrophila attacks the meso-isomer but not the l- and probably not the d-isomer; Aerobacillus polymyxa can oxidize both l- and meso-2,3-butanediol, but the rate with the former is many times greater than with the latter. Aerobacter aerogenes oxidizes both 2,3-butanediol and acetoin to carbon dioxide and water, a large part of the substrate being simultaneously assimilated. The other two organisms oxidize 2,3-butanediol to acetoin, but can further oxidize the acetoin thus formed only very slowly, if at all. Both Aerobacter aerogenes and Aerobacillus polymyxa are unable to attack 1,3-butanediol, 2-methyl-1,2-propanediol and 1,2-ethancdiol. However they can oxidize 1,2-propanediol to acetol.

Emergence Change of Carbon Dioxide from Artificial Skin by Titania Photocatalyst

2007 ◽  
Vol 544-545 ◽  
pp. 55-58
Author(s):  
Eiji Watanabe ◽  
Mitsuharu Fukaya ◽  
Hiroshi Taoda
Keyword(s):  
Carbon Dioxide ◽  
Visible Light ◽  
Uv Irradiation ◽  
Visible Light Irradiation ◽  
Human Body ◽  
Light Condition ◽  
The Other ◽  
Artificial Skin ◽  
Irradiation Condition ◽  
Titania Photocatalyst

The influence of the titania photocatalyst particle of the nanometer region on the human being and biology’s to be doubted. Removing the uneasiness will expand further uses for the photocatalyst nanoparticle. Then, we attempted to examine the effect of several titania photocatalyst nanoparticles to the artificial skin like the human body under the UV and visible light irradiation conditions. The decomposition degree of the artificial skin was evaluated from the monitoring of the amount of carbon dioxide generated from them by the titania photocatalyst nanoparticle activity. Under the UV irradiation condition, it was almost found the carbon dioxide emergence from the artificial skin by the activity of the titania photocatalyst nanoparticle. On the other hand, under visible light condition it was mostly detected.

scholarly journals IMPACT EVALUATION OF CARBON DIOXIDE (CO2) IN BHOPAL DUE TO INCREASE IN NUMBER OF PASSENGER CARS

2019 ◽  
Vol 7 (7) ◽  
pp. 422-431
Author(s):  
Niranjan Mudliar ◽  
Paramjeet Singh
Keyword(s):  
Carbon Dioxide ◽  
Public Transport ◽  
Income Group ◽  
The Other ◽  
State Governments ◽  
Passenger Cars ◽  
Lower Income Group ◽  
The Government ◽  
Carbon Dioxide Co2 ◽  
The City

India has been progressing steadily since last two decades in terms of affordability of commodity and purchasing power of the common man. This has given rise to demand which leads to the continuous economic growth. Of course, support from the Government of India as well as various state Governments has come in the form of reforms and infrastructure funding. However this growth has also seen the disadvantage of erratic consumption by wealthy persons as compared to the economically weaker sections, for example on one side there is heavy demand of passenger cars by the higher income group who uses it sparingly but on the other side people of the lower income group who are more in numbers have to rely on public transport. This imbalance creates a wider gap between public affordability to consume a particular commodity like passenger cars. On one side there are persons who buy the latest model introduced by the manufacturer in spite of having sufficient numbers at their disposal and on the other side basic lowest level model are out of reach of some persons in the society, who rely on two-wheeler or public transport which is not reliable. This has not only created a huge gap in public expenditure but has also impact the environment. With year on year increase in number of vehicles in tier 2 cities like Bhopal, there is tremendous influence on the carbon dioxide (CO2) in and around the city. Past decade saw increase in maximum temperatures during summer rise by 3 – 4 degrees above normal in Bhopal and there is clear effect on the monsoon pattern too which has become inconsistent with rains reaching 120 mm in three days. Earlier this quantity was spread over a month. The last major season of winter is seen getting reduced to two months only from the earlier four, again with temperatures dropping suddenly below normal etc. This effect must be the result of increasing number of passenger vehicles in the city apart from other factors which also need detailed study for their influence.

Inhibition of δ-Aminolevulinic Acid Synthesis by Glyphosate

Weed Science ◽  
1981 ◽  
Vol 29 (5) ◽  
pp. 571-577 ◽  
Author(s):  
Lynn M. Kitchen ◽  
William W. Witt ◽  
Charles E. Rieck
Keyword(s):  
Carbon Dioxide ◽  
Zea Mays ◽  
Aminolevulinic Acid ◽  
Higher Plants ◽  
Acid Synthesis ◽  
The Other ◽  
Porphyrin Ring ◽  
Fresh Weight ◽  
Ring Compounds ◽  
Site Of Action

The effect of glyphosate [N-(phosphonomethyl) glycine] on barley (Hordeum vulgareL.) and corn (Zea maysL.) shoot δ-aminolevulinic acid (ALA) production was examined by monitoring ALA content in the tissue and measuring incorporation of14C precursors into ALA and chlorophylla. Barley shoot ALA content was significantly decreased by 1 mM glyphosate after 9, 11, and 15 h of illumination. ALA production by treated barley shoots was 30 nmoles•g fresh weight-1•h-1at each interval tested, compared with 75 to 120 nmoles•g fresh weight-1•h-1for the control. In corn shoots, ALA content was reduced 32, 45, and 58% by 0.1, 1.0, and 10.0 mM glyphosate, respectively, after 12 h illumination. Incorporation studies with14C-glutamate,14C-α-ketoglutarate, and14C-glycine into ALA showed a 77, 92, and 91% inhibition, respectively, in barley shoots treated with 1 mM glyphosate. Incorporation of14C-ALA into chlorophyllawas not affected by 1 mM glyphosate. Thus, the site of action of glyphosate may involve two enzyme pathways:one controlling the conversion of α-ketoglutarate to ALA, and the other controlling the condensation of glycine with succinyl CoA to form ALA and carbon dioxide. Inhibition of ALA synthesis blocks synthesis of chlorophyll, as well as all other porphyrin ring compounds found in higher plants. Thus, inhibition of ALA synthesis may be an integral component of the herbicidal mode of action of glyphosate.

scholarly journals Supersonic dispersion in gases

1934 ◽  
Vol 146 (856) ◽  
pp. 56-71 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Experimental Work ◽  
High Frequency ◽  
Response Curve ◽  
Wave Length ◽  
Soap Film ◽  
The Other ◽  
Rapid Degradation ◽  
Compressional Waves ◽  
Point Electrode

The rapid degradation of intensity suffered by compressional waves of high frequency in gases was first observed by pierce in carbon dioxide for frequencies in the neighbourhood of 2.10 5 cycles/sec. Although in the last few years a considerable number of measurements of the velocity of supersonic waves have been made, less experimental work has been done on the absorption . This present paper describes some work aimed at elucidating the mechanism of the phenomenon. Consideration was first given to the establishment of a source of vibrations of the requisite frequency. The possible apparatus reduces itself to four types: (1) edge-tones, (2) electric sparks, (3) small resonators of gas, (4) solid resonators; both of the latter types to be maintained by oscillating circuits incorporating valves. The frequency of an edge-tone depends directly on the velocity of the blast, and inversely on the distance from the blower to the edge, so that it should be possible to produce supersonic waves by making the former very large and the latter very small; in fact, Hartmann has already used such a source. The difficulty of maintaining constant blast velocity and the complications which the blast introduces in the propagation of such waves would, however, have made such a source unmanageable in the present work. Nekle-pajev has used sparks as sources in the examination of the absorption in air. But here again the frequency is difficult to measure or to maintain constant. Some success was obtained by the author with gaseous resonators consisting of short brass tubes terminated at one end by a brass stopper, and at the other end by a soap film, the distance between the two being half the wave-length at the frequency of excitation. The resonator was maintained in vibration by a valve oscillator, of which the plate was connected to a point electrode just above the soap film, while the grid was connected to the brass tube itself. Response of the resonator due to electrostatic attraction of the film was observed by the image of a glowing filament reflected from the slightly concave film on to a scale. By varying the tuning of the oscillator the response curve of the little resonator could be obtained.

THE ESTIMATION OF FREE AMINO ACIDS USING A MICRODIFFUSION TECHNIQUE

1952 ◽  
Vol 30 (7) ◽  
pp. 522-528 ◽  
Author(s):  
W. B. McConnell
Keyword(s):  
Carbon Dioxide ◽  
Amino Acids ◽  
Free Amino Acids ◽  
Free Amino ◽  
The Other ◽  
Routine Analysis ◽  
Average Deviation ◽  
Substantial Saving ◽  
Ionic Concentrations ◽  
The Mean

The carbon dioxide evolved when α-amino acids were heated for one hour at 85 °C. with ninhydrin was determined in a partially evacuated microdiffusion cell. Distillation of solvent from one chamber to the other was minimized by keeping the ionic concentrations of the reaction mixture and absorbing mixture approximately equal. The method was useful for samples of amino acids which liberated from 0.06 to 0.3 mgm. of carbon dioxide. The average deviation from the mean was somewhat less than 1% for samples liberating 0.2 mgm. of carbon dioxide. Use of the method for routine analysis of enzymatic digests resulted in substantial saving of time and material.

scholarly journals Thermodynamic modeling of solid solubility in supercritical carbon dioxide: Comparison between mixing rules

2013 ◽  
Vol 19 (3) ◽  
pp. 389-398 ◽  
Author(s):  
Hadi Baseri ◽  
Ali Haghighi-Asl ◽  
Nader Lotfollahi
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Thermodynamic Modeling ◽  
Pressure Range ◽  
The Other ◽  
Mixing Rules ◽  
Calculation Results ◽  
Temperature And Pressure ◽  
Robinson Equation ◽  
Supercritical Carbon

In this paper, Peng Robinson equation of state is used for thermodynamic modeling of the solubility of various solid components in the supercritical carbon dioxide. Moreover, the effects of three mixing rules of Van der Waals mixing rules, Panagiotopoulos and Reid mixing rules and modified Kwak and Mansoori mixing rules on the accuracy of calculation results were studied. Good correlations between calculated and experimental data were obtained in the wide temperature and pressure range. A comparison between used models shows that modified Kwak and Mansoori mixing rules give better correlations in comparison with the other mixing rules.

The effects of varying the nitrogen, sulphur, and phosphorus content of organic matter on its decomposition

1960 ◽  
Vol 11 (3) ◽  
pp. 317 ◽  
Author(s):  
NJ Barrow
Keyword(s):  
Carbon Dioxide ◽  
Organic Matter ◽  
Organic Compounds ◽  
Phosphorus Content ◽  
Nitrogen Supply ◽  
The Other ◽  
Organic Mixture ◽  
Carbon Nitrogen Ratio ◽  
Phosphorus Mineralization ◽  
Nitrogen Ratio

The decomposition of a mixture of organic compounds was studied by measuring the evolution of carbon dioxide, and changes in the concentration of ammonium, sulphate, and phosphate. In one experiment the nitrogen supply was varied by varying the proportion of glycine in the mixture of organic compounds; in another the sulphur supply was varied by varying the proportion of cysteine; and in a third the phosphorus supply was varied by varying the proportion of sodium ß-glycerophosphate. Mineralization of an element depended on the concentration of that element in the organic mixture. Mineralization of nitrogen did not occur until respiration had lowered the carbon/nitrogen ratio to about 5 and mineralization of sulphur did not occur until respiration had lowered the carbon/sulphur ratio to about 50. On the other hand mineralization of phosphorus occurred before the carbon/phosphorus ratio had been reduced to any consistent figure. This may not be a characteristic of phosphorus mineralization but may have been caused by suboptimal supply of nitrogen. Mineralization of an element also depended on the concentration of other elements and, in general, reduced supplies of one element caused increased mineralization of others.

Carbon Dioxide Evolution from High-Moisture Shelled Corn Treated with Iprodione†

1995 ◽  
Vol 58 (6) ◽  
pp. 673-677 ◽  
Author(s):  
SLAVEN ALJINOVIC ◽  
CARL J. BERN ◽  
PRINCE N. DUGBA ◽  
MANJIT K. MISRA
Keyword(s):  
Carbon Dioxide ◽  
Untreated Control ◽  
Dry Matter ◽  
Storage Life ◽  
The Other ◽  
High Moisture ◽  
Carbon Dioxide Evolution ◽  
Dry Matter Loss

Carbon dioxide evolution was used to determine the storage life of 22.7% moisture shelled corn. Four iprodione fungicide treatments plus an untreated control were tested. The fungicide was tested on corn having three levels of mechanical kernel damage: 7% (hand shelled), 25% (combine harvested), and 16% (a blend of the other two damage levels). All iprodione treatments significantly increased storage life. Corn samples with higher levels of kernel damage took shorter times to reach the 0.5% dry-matter loss (DML) level. For combine-shelled corn, the fungicide increased storage life 17% at 15 mg/kg of corn and 46% at 20 mg/kg of corn.

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