scholarly journals PECULIARITIES OF METALIZATION OF PULLED POLYETHYLENE

2020 ◽  
Vol 3 (2) ◽  
pp. 140-145
Author(s):  
А. N. Kucherenko ◽  
◽  
S. О. Mankevych ◽  
М. Ya. Kuznetsova ◽  
V. S. Moravskyi ◽  
...  

The results of experimental studies of the peculiarities of metallization of granular polyethylene are presented. The influence of concentration factors on the metallization process of zinc-activated polyethylene granules of brand Liten PL-10 was investigated. It is established that by changing the concentration of copper sulfate and sodium hydroxide, as well as the degree of loading of polymeric raw materials, it is possible to effectively regulate the amount of recovered copper on granules of polyethylene, and therefore the thickness of the metal layer formed on them. The use of the method of preliminary processing of activated polyethylene granules in a solution of copper sulfate can significantly reduce the induction period and increase the rate of recovery of copper ions.

2019 ◽  
Vol 135 ◽  
pp. 03044
Author(s):  
Yuriy Dmitriyev ◽  
Eugene Yurchenko ◽  
Elena Yurchenko ◽  
Astkhyk Kakosyan ◽  
Elena Vorobei

Obtained artificial substrates, representing a porous glass (foam glass) with additives of 3 to 10% of the mass. copper ions. Glass raw materials were used as raw materials for the synthesis of substrates. In order to create open porosity, a carbonate blowing agent (chalk) was introduced into the initial mixture. Foaming additive served as sodium nitrate, a source of copper ions - copper sulfate (copper sulfate). A distinctive feature of the synthesis method was the combination of wetting the initial mixture and its rapid heating to maximum temperature. This mode was used to increase the porosity of the resulting structure. It was found that the water absorption of the obtained substrates increases with an increase in the concentration of copper ions in them. The resulting materials, due to the increased content of copper ions in them, may have a fungicidal effect. Perhaps their use in crop production, landscape design, the construction industry in conditions of high humidity.


Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


Author(s):  
S.V. Matsenko ◽  
◽  
V.M. Minko ◽  
A.A. Koshelev ◽  
V.Yu. Piven ◽  
...  

Violation of industrial safety rules during the operation of offshore facilities for the production, storage and transportation of the hydrocarbon raw materials leads in the most cases to pollution of the marine environment with oil and its components. The works on localization and elimination of such pollution are carried out with the help of vessels of the technical support fleet and booms. When developing oil spill response plans at such facilities, a calculated determination of the technical characteristics of vessels and booms is required that are sufficient to carry out the planned activities. The basic design principles for determining the towing capacity of the technical fleet vessels involved in the localization and elimination of oil and oil product spills by trawling methods are given in the article. The calculation is based on theoretical studies performed by the authors of the physical processes occurring during the movement of objects of a mobile trawling order in the sea area. The results obtained during the course of theoretical studies were confirmed by the experimental studies carried out by the authors personally using the real pieces of equipment in the actual development of tasks for training spill containment by trawling. As a result, the empirical dependencies were obtained and experimentally confirmed, which can be used to calculate technical characteristics of the ships as part of the mobile orders and anchor systems as part of stationary orders intended for the localization and elimination of oil pollution. These results can be used, among other things, for the calculated substantiation of the technical characteristics of the technical fleet vessels designed to ensure safety of the offshore facilities for production, storage, and transportation of the hydrocarbon raw materials.


Author(s):  
А.В. АКУЛИЧ ◽  
Л.А. ГОСТИНЩИКОВА

Исследованы закономерности внешнего массообмена при сушке ягодного сырья для различных способов энергоподвода. Установлено, что ягоды при сушке подвержены значительной объемной (72–81%) и линейной (35–43%) усадке, которую необходимо учитывать при расчете коэффициентов массоотдачи. Объекты исследования – ягоды черники, красной и черной смородины. Проведены экспериментальные исследования по сушке ягодного сырья при конвективном и конвективном с ИК-излучением способах энергоподвода. Исследования проведены при скорости сушильного агента хса1,2 м/с и температуре tса 70°С. Получены критериальные уравнения внешнего массоообмена при сушке ягод для периода постоянной скорости, учитывающие объемную усадку. Определено, что при сушке с конвективным энергоподводом объемная усадка при одном и том же значении критерия Рейнольдса оказывает на 12–20% большее влияние на интенсивность массоообмена для красной смородины по сравнению с черникой и черной смородиной. При сушке с конвективным энергоподводом, ИК-излучением и предварительным прокалыванием объемная усадка наиболее существенно влияет на массообмен для черной смородины, протекающий в 1,5–1,8 раза интенсивнее по сравнению с черникой и красной смородиной. Полученные критериальные уравнения могут быть использованы при расчете и проектировании установок для сушки ягодного сырья. The laws of external mass transfer during drying of berry raw materials for various methods of energy supply are investigated. It is established that the berries during drying are subject to significant volumetric (72–81%) and surface (35–43%) shrinkage, which must be taken into account when calculating the mass transfer coefficients. The objects of the study were various berries: blueberries, red and black currants. Experimental studies have been carried out on the drying of selected berries both in the case of convective and convective methods with IR radiation. Investigations were carried out at a drying agent velocity хса1,2 m/s and its temperature tca70°С. The criterion equations of external mass transfer during drying of berries for a period of constant speed, taking into account the volume shrinkage, are obtained. It was determined that during drying with convective energy supply, volume shrinkage with the same value of the Reynolds criterion on 12–20% has a greater effect on the mass transfer rate for red currants. When drying with convective energy supply, IR radiation and preliminary piercing, the volume shrinkage most significantly affects the mass transfer for black currants, which is 1,5–1,8 times more intense than blueberries and red currants. The obtained criterial equations can be used in the calculation and design of berries dryers.


Author(s):  
SHAPOVALOVA Nataliia ◽  
VEZHLIVTSEVA Svitlana ◽  
ANTIUSHKO Dmytro

Background. The deficiency of essential nutrients in the human body is the root cause of reduced efficiency, general resistance of the body to various diseases. That is an urgent problem in the context of the spread of coronavirus infection. In this regard, the search for opportunities to meet the needs of the population in food products that contain biologically active substances (BAS) through the use of high-value and at the same time available plant raw materials is extremely important. Marigolds attract special attention among such raw materials. The aim of the work is to study the chemical composition and evaluate the consumer properties of Tagetes L. varieties, zoned in the Kiev region, to prove the possibility of increasing the biological value of pasta by adding to their recipe powder from marigold inflorescences. Materials and methods. The object of research is pasta of B group (noodles). Inflorescences of marigolds of different varieties gathered during the flowering period in July-September 2019–2020 in the territory of Vasylkiv and Obukhiv districts of Kyiv region, Ukraine were used as enriching plant raw materials. The quality of finished pasta was assessed by organoleptic and physicochemical indexes (moisture content and titratable acidity). The content of mineral elements in the fine powder of marigold inflorescences was determined on the EXHERT-3L device, the quantitative composition and BAS identification – by spectrophotometric analysis on the device Specord-200 Analytic Jena UV-vis. The integrated quality index of pasta products was calculated taking into account the importance factors of individual indexes. Results. Comparing the obtained results, we can state that all the studied varieties – Gold Kopfen, Orange Flame, Hawaii, Equinox are characterized by high biological value, regardless of the area of collection. As a result of calculated and experimental studies it was determined that the addition of 7 % of the supplement does not provide the required supply of vitamins and minerals. Replacing the flour in the recipe by 20 % significantly improves the mineral composition, but deteriorates the taste and aromatic properties of pasta. The most optimal and rational amount of added additive is 15 %, as it improves the organoleptic properties of pasta and enriches their BAS. Conclusion. The usage of non-traditional vegetable raw materials, in particular powder from marigold inflorescences, which is rich in biologically active substances, allows not only to expand the range, improve the quality of finished products, but also increase the biological value of the product. The optimal amount of additive –powder from marigold inflorescences, was defined. It is 15 % by weight of flour in the production of noodles. This concentration allows not only to improve the organoleptic properties, but also to increase the content of biologically active substances – vitamins, micro- and macronutrients. The usage of non-traditional natural raw materials (powder from marigold inflorescences) allows to abandon artificial colorsand give the finished pasta a pleasant colorand aroma.


2021 ◽  
Vol 447 (3) ◽  
pp. 18-24
Author(s):  
D.B. Augaliev ◽  
M.K. Erkibaeva ◽  
A.O. Aidarova ◽  
S.А. Tungatarova ◽  
T.S. Baizhumanova

The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.


PEDIATRICS ◽  
1959 ◽  
Vol 23 (3) ◽  
pp. 617-617

Physicians should be aware that the accidental ingestion of Clinitest® tablets, now in common use for urine analysis, can cause severe stricture of the esophagus because of their content of sodium hydroxide; perhaps the copper sulfate contained in the tablets may play a secondary role. The author adds a report of a case to 4 cases previously recorded. It is important that both physicians and patients realize this hazard and keep Clinitest® tablets beyond the reach of small children.


2011 ◽  
Vol 298 ◽  
pp. 163-168 ◽  
Author(s):  
Yuan Yuan Lei ◽  
Guo Zheng ◽  
Yu Sun ◽  
Yong Zhou

In this paper, with fatty alcohol polyoxyethylene (AEO9), succinic anhydride (SA) and sodium hydroxide as raw materials, a new type of fatty alcohol polyoxyethylene carboxylate surfactants (SAE9C-Na) was obtained by esterification and neutralizing effect. The influencing factors were researched and its surface properties were studied. The optimum condition of synthesis was determined: molar ratio of alcohol to acid was 1:1.1, reaction temperature was 85°C, reaction time was 60 min, under this condition, the yield could reach up to 95.8%. The results received from this experiment showed that SAE9C-Na had excellent surface activity and foaming and foam stability, whose emulsification and solubility enhancement were improved greatly.


2018 ◽  
Vol 56 ◽  
pp. 03027
Author(s):  
Viktor Makienko ◽  
Igor Romanov ◽  
Pavel Sokolov ◽  
Alexander Atenyaev ◽  
Dmitry Pervakov

The results of the study of the possibility of using additional technological influence in the formation of doped coatings are presented. The distribution of thermal fields has been calculated, which makes it possible to estimate and predict the influence of additional influence on the formation of the coating in a simplified manner. Experimental studies have shown that additional technological influence promotes mixing of the melt, leading to an increase in the transition of alloying elements, as well as an increase in the mechanical properties and quality of the weld metal.


Author(s):  
D. F. Nurgaliev ◽  
V. M. Sizyakov ◽  
V. A. Utkov

The results of studies of the reduction of alkali metal oxides in nepheline sludge are presented. The alkali-containing phase is sodium hydroaluminosilicate. The methodology of the experimental studies involved the preparation of a water suspension with a given ratio W:T, mechanical stirring, heating, aging and separation of the pulp on a vacuum filter. A technology has been developed to reduce the alkali content by 21% of the initial amount of alkali, which has increased the melting temperature by 310 ° C. The obtained results are the basis for the design of a pilot plant and the development of refractory heat-insulating materials with the replacement of expensive mineral raw materials with non-deficient man-made waste. Ill. 2. Ref. 22. Tab. 1.


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