scholarly journals Kinetic Model for Dissolution of Cement Copper in Sulfuric Acid Solutions Containing Cupric Ions

2021 ◽  
Vol 15 (3) ◽  
pp. 395-402
Author(s):  
Nizamettin Demirkıran ◽  
◽  
G. Deniz Turhan Özdemir ◽  
Keyword(s):  
Sulfuric Acid ◽  
Dissolution Rate ◽  
Copper Powder ◽  
Dissolution Kinetics ◽  
Reaction Model ◽  
Ion Concentration ◽  
Acid Solutions ◽  
Cupric Ion ◽  
Sulfuric Acid Solutions ◽  
Kinetics Of

In this paper, the dissolution kinetics of cement copper powder in sulfuric acid solutions containing cupric ions was examined. It was observed that the dissolution rate of copper increased with increasing the acid concentration, temperature, and stirring speed. It was determined that the dissolution rate of copper enhanced with increasing the cupric ion concentration up to 0.025 M. It was found that the temperature and concentration of cupric ion had more considerable effects on the dissolution of copper powder. The kinetic analysis of the process was performed, and it was observed that it fits the first order pseudo-homogenous reaction model. The activation energy was calculated to be 31.1 kJ/mol.

The Dissolution Kinetics of Tincal in Phosphoric Acid Solutions

2007 ◽  
Vol 5 (1) ◽  
Author(s):  
Yuksel Abali ◽  
Salih U Bayca ◽  
Ayse E Guler
Keyword(s):  
Particle Size ◽  
Phosphoric Acid ◽  
Dissolution Rate ◽  
Acid Concentration ◽  
Reaction Temperature ◽  
Dissolution Kinetics ◽  
Reaction Model ◽  
Acid Solutions ◽  
Liquid Ratio ◽  
Kinetics Of

In this study, the dissolution kinetics of tincal in phosphoric acid solutions was investigated. The effects of reaction temperature, acid concentration, solid to liquid ratio, particle size and stirring speed were determined in the experiments. The results showed that the dissolution rate increased with increasing acid concentration, reaction temperature, stirring speed and increased with decreasing particle size and solid to liquid ratio. The dissolution rate was found to be based on the first order pseudo homogenous reaction model. The activation energy of the tincal in phosphoric acid solution was determined as 42.28 kJ.mol-1.

Kinetics of reduction of U(VI) with zinc amalgam in sulfuric acid solutions

2015 ◽  
Vol 57 (1) ◽  
pp. 31-35 ◽  
Author(s):  
V. N. Momotov ◽  
E. A. Erin ◽  
V. M. Chistyakov
Keyword(s):  
Sulfuric Acid ◽  
Acid Solutions ◽  
Zinc Amalgam ◽  
Sulfuric Acid Solutions ◽  
Kinetics Of ◽  
Kinetics Of Reduction

scholarly journals Dissolution of Tunisian phosphate ore by a mixture of sulfuric and phosphoric acid: Kinetics study by means of differential reaction calorimetry

2019 ◽  
Vol 55 (1) ◽  
pp. 9-19
Author(s):  
Olfa Lachkar-Zamouri ◽  
Khemaies Brahim ◽  
Faten Bennour ◽  
Ismail Khattech
Keyword(s):  
Experimental Data ◽  
Particle Size ◽  
Dissolution Rate ◽  
Dissolution Kinetics ◽  
Reaction Model ◽  
Reaction Calorimetry ◽  
Phosphate Ore ◽  
Differential Reaction ◽  
Apparent Activation Energies ◽  
Kinetics Of

A mixture of phosphoric and sulfuric acid was used to investigate the dissolution kinetics of phosphate ore by Differential Reaction Calorimetry (DRC). The effect of the solid-to-iquid ratio, concentration, stirring speed, particle size and temperature of the reaction is examined. It was established that the dissolution rate increased with stirring speed and particle size. However, rising the olid-to-iquid ratio, temperature and concentration decreased the dissolution rate. It was determined that the dissolution rate fits in the first order of the pseudo-homogeneous reaction model. Two negative values of apparent activation energies were found in the range of 25 to 60?C. The experimental data were tested by graphical and statistical methods and it was found that the following models were best fitted for the experimental data and an empirical equation for the process was developed. -ln (1 ? x) = [2,2 E-09((S/L)0.75C -0.461G0.447(SS) 0.471exp (2671/T)]t. T? 40?C -ln (1 ? x) = [2,2 E-09((S/L)0.75C -0.461G0.447(SS) 0.471exp (6959/T)]t. T > 45?C

Kinetics of Molybdenum(VI) Oxide Dissolution in Sulfuric Acid Solutions

2004 ◽  
Vol 38 (3) ◽  
pp. 316-321 ◽  
Author(s):  
E. Yu. Nevskaya ◽  
I. G. Gorichev ◽  
A. D. Izotov ◽  
B. E. Zaitsev ◽  
K. M. Al'dieva ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Acid Solutions ◽  
Oxide Dissolution ◽  
Sulfuric Acid Solutions ◽  
Kinetics Of
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