scholarly journals Water Absorption Behavior and Impact Strength of PVC/Wood Flour Composites

2010 ◽  
Vol 4 (3) ◽  
pp. 225-229 ◽  
Author(s):  
Gisele Iulianelli ◽  
◽  
Maria Bruno Tavares ◽  
Leandro Luetkmeyer ◽  
◽  
...  

PVC/wood flour composites were prepared by compression molding using sapwood and heartwood from Angelin Pedra as filler. The composites specimens were subjected to water immersion and impact tests. The results showed that the water absorption of all composites increased slightly with increasing immersion time and wood content. However, the values were considerably low compared with control sample, common solid woods and wood plastic composites reported in literature. PVC/sapwood composites showed slightly higher values for moisture absorption ability due to the difference in chemical constituents’ ratio. PVC compound and PVC/sapwood composite containing 10 phr of wood flour exhibited maximum water absorption in 63 days and it corresponded to 0.25 % and 0.58 % weight gain, respectively. In relation to impact test, the results indicated that impact property was affected by wood content and less by wood type. Composites containing 10 phr of wood content showed greater impact strength (decreased by around 60 %) than those prepared with 25 and 40 phr of wood flour content (decreased approximately by 75 %). In general the composites prepared with 10 phr of wood flour content exhibited a better performance in both parameters measured in this study.

BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 9584-9595
Author(s):  
Mustafa Zor

The friction welding method has been an effective criterion in determining the mechanical performance of wood joints in wood industry applications compared to traditional methods. Although it is used in structural applications, joints from linear vibration are quite sensitive to water. In this study, the water resistance of the heat-treated woods, iroko (Chlorophora excelsa), ash (Fraxinus excelsior L.), tulip wood (Liriodendron tulipifera) and ayous (Triplochiton scleroxylon), were investigated by friction linear welding. The weld line density profiles were examined. The resistance of heat-treated welded wood joints to water remarkably decreased compared to the control sample, depending on water immersion time. The highest shear strength loss was found in tulip wood (60% to 65%) and the lowest shear strength loss was found in ash wood (3%) for the heat-treated group and in Iroko wood (17%) for the control. The heat-treated samples increased in density with welding but had a slightly lower density than the control group. According to the TGA results, it was found that the thermal degradation of untreated welded woods was lower than that of heat-treated welded woods. This difference could be due to the chemical constituents of hardwood and tropical wood. X-ray computed tomography (CT-scanning) is feasible and usable for welding line density change.


Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3698
Author(s):  
Ter-Zakaryan K. A. ◽  
Zhukov A. D. ◽  
Bobrova E. Yu. ◽  
Bessonov I. V. ◽  
Mednikova E. A.

The application of foamed polymers as one of the components of insulating coatings allows to solve the problems of energy saving and creation of optimal operating conditions for constructions. The systems of application of energy-efficient heat-insulating materials must consider both the particularities of the insulating materials and the functional orientation of the constructions. The implementation of the concept of seamless insulating coatings implies the achievement of thermal effect and reduction in air permeability both by means of the application of thermal insulation with low thermal conductivity and the minimization of junctions between separate elements of the insulating coating, which is achieved using elastic foamed polymers and, first of all, polyethylene foam. Construction of seamless insulating coatings creates practically impermeable heat, vapor, and water barriers along the outer perimeter of the insulated object. Multilayer products based on polyethylene foam represent a relatively new material—a fact that requires examination of their properties, as well as under various operating conditions, and development of a methodology for evaluation of the operational resistance of these materials in structures of different purposes, including cold conservation. The performed tests have shown that the compressive strength at 10% deformation is determined by the function of load application area and varies from 70 kPa during the test of cube samples of 10 × 10 × 10 in size to 260 kPa for areas exceeding 100 m2. The longitudinal tensile strength amounts to 80–92 kPa, and the strength of the weld seam is equal to 29–32 kPa. It has been established that the values of thermal conductivity of polyethylene foam with an average density of 18–20 kg/m3 amounts to 0.032–0.034 W/(m·K), diffusion moisture absorption is equal to 0.44 kg/m2 without a metallized coating and 0.37 kg/m2 with a metallized coating; water absorption after partial immersion in water for 24 h amounts to 0.013 kg/m2; water absorption by volume after complete water immersion for 28 days is equal to 0.96%. The material does not practically change its properties under conditions of long-term temperature alteration from −60 to +70 °C. The developed and implemented insulation systems for protective surfaces of framed construction objects, rubbhalls and frameless structures, floating floors, indoor ice rinks, and snow conservation systems are presented.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Amuthakkannan Pandian ◽  
Manikandan Vairavan ◽  
Winowlin Jappes Jebbas Thangaiah ◽  
Marimuthu Uthayakumar

The study of mechanical properties of fibre reinforced polymeric materials under different environmental conditions is much important. This is because materials with superior ageing resistance can be satisfactorily durable. Moisture effects in fibre reinforced plastic composites have been widely studied. Basalt fibre reinforced unsaturated polyester resin composites were subjected to water immersion tests using both sea and normal water in order to study the effects of water absorption behavior on mechanical properties. Composites specimens containing woven basalt, short basalt, and alkaline and acid treated basalt fibres were prepared. Water absorption tests were conducted by immersing specimens in water at room temperature for different time periods till they reached their saturation state. The tensile, flexural, and impact properties of water immersed specimens were conducted and compared with dry specimens as per the ASTM standard. It is concluded that the water uptake of basalt fibre is considerable loss in the mechanical properties of the composites.


2011 ◽  
Vol 264-265 ◽  
pp. 457-462 ◽  
Author(s):  
T.A. Lenda ◽  
S. Mridha

Hybrid jute-carbon/ epoxy composites, fabricated by hand lay-up method with fiber volume fractions of 0.47, 0.58 and 0.68 were used to investigate water absorption behavior as a function of immersion time and fiber content. The effect of moisture content on impact strength and failure modes was also studied. Results show that the moisture absorption increased with increasing the immersion time in water and it was more with higher fiber fraction specimens. Maximum moisture contents of 0.45%, 0.52% and 0.61% were recorded for the specimens containing fiber volume fractions of 0.47, 0.58 and 0.68, respectively. The impact strength reduced with increasing moisture absorption in all specimens containing different fiber fractions. Composites with higher fiber content gave reduced impact strength under all test conditions. Composites of different fiber fractions and of highest moisture content produced impact strengths about 20 to 28% less than those strengths obtained without water immersion. The 47 vol% fiber specimen was least affected by water immersion and impact strength reduction was only 17% after immersion till saturation. Failure occurred by mainly by delamination and it was evident in all fractured specimens. Results of the effect of impact energy on moisture content have been evaluated using ANOVA ANALYSIS and the results gave errors of 1%, 0.6 % and 0.8 % for 0.47, 0.58 and 0.68 fiber volume fraction specimens, respectively.


2020 ◽  
pp. 089270572093073
Author(s):  
Elham Nadali ◽  
Reza Naghdi

This study emphasizes on closed-loop recycling of wood flour/poly (vinyl chloride) composites, since there is normally a considerable amount of material waste in wood plastic production lines. Composite materials were produced and subjected to four times reprocessing cycles under industrial conditions. Detailed analytical methods including bending strength, modulus of elasticity, impact strength, scanning electron microscopy, fiber length, water absorption, contact angle, Fourier transform infrared, and dynamic mechanical thermal analysis (DMTA) were conducted to evaluate the effects of recycling on the mentioned composites. Results demonstrated that the recycled composites, except for the four-time recycled ones, had lower bending strength, modulus of elasticity, and impact strength due to fiber-chain scission/fracture resulting from shear stress during reprocessing; however, impact strength remained almost unchanged after the first recycling cycle. Results also revealed that generally the reprocessed composites showed lower water absorption rates due to better fiber wetting and encapsulation. There was also a reduction in hemicellulose hydroxyl groups, rendering the recycled composites less hydrophilic. DMTA results showed an increase in mechanical loss factor (tan δ) for all the reprocessed composites showing a more viscous than elastic nature. The glass transition temperature of Rec4 composites increased due to polymer dehydrochlorination and the resulting cross-linking, which restricted the molecular mobility of the polymer chains.


2018 ◽  
Vol 917 ◽  
pp. 42-46 ◽  
Author(s):  
Akshay Kakar ◽  
Elammaran Jayamani ◽  
Muhammad Khusairy bin Bakri ◽  
Soon Kok Heng

The goal of this study was to investigate the influence of cyclic hot and cold water absorption and desorption on the flexural and impact strengths of luffa – PLA biocomposites. PLA was reinforced with heat treated luffa fibers with the fiber loadings: 5 vol.%, 10 vol.%, 15 vol.% and 20 vol.%. Based on the test results the biocomposite with the highest flexural and impact strengths was selected for water absorption and desorption cycles. The biocomposites were subjected to 56 cycles of hot and cold water absorption and desorption. The biocomposites were tested for their strengths after every 14 cycles. The absorption and desorption decreased the flexural and impact strengths, affecting the impact strength more than the flexural strength.


BioResources ◽  
2011 ◽  
Vol 6 (1) ◽  
pp. 584-593
Author(s):  
Behzad Kord ◽  
Saeed Ismaeilimoghadam ◽  
Behrouz Malekian

Polypropylene/wood flour/organoclay hybrid nanocomposites were melt-compounded in an internal mixer at 190 oC and 60 rpm rotor speed. Then samples were fabricated by injection molding. Effects of immersion temperature on the water uptake of hybrid nanocomposite were investigated. To meet this objective, water absorption of samples was determined after 24 h immersion in distilled water at different temperatures (25, 50, 75, and 100 °C). Results indicated that immersion temperature had a significant influence on the water absorption of composites. By increasing the temperature, water absorption increases as well. The maximum water absorption of composite is decreased by increasing the nanoclay and compatibilizer content. The morphology of nanoclay was determined by X-ray diffraction (XRD) and transmission electron microscopy. The effect of morphology on water absorption was also evaluated. Due to inadequate compatibilizer, exfoliated morphology of nanoclay was not obtained, but there was evidence of intercalation. The order of intercalation for samples containing 3 phc was higher than that of 6 phc at the same PP-g-MA content due to some agglomerations of organoclay.


2016 ◽  
Vol 10 (4s) ◽  
pp. 595-600 ◽  
Author(s):  
Witold Brostow ◽  
◽  
Haley E. Hagg Lobland ◽  

The property of brittleness for polymers and polymer-based materials (PBMs) is an important factor in determining the potential uses of a material. Brittleness of polymers may also impact the ease and modes of polymer processing, thereby affecting economy of production. Brittleness of PBMs can be correlated with certain other properties and features of polymers; to name a few, connections to free volume, impact strength, and scratch recovery have been explored. A common thread among all such properties is their relationship to chemical composition and morphology. Through a survey of existing literature on polymer brittleness specifically combined with relevant reports that connect additional materials and properties to that of brittleness, it is possible to identify chemical features of PBMs that are connected with observable brittle behavior. Relations so identified between chemical composition and structure of PBMs and brittleness are described herein, advancing knowledge and improving the capacity to design new and to choose among existing polymers in order to obtain materials with particular property profiles.


Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2212
Author(s):  
Worawat Poltabtim ◽  
Ekachai Wimolmala ◽  
Teerasak Markpin ◽  
Narongrit Sombatsompop ◽  
Vichai Rosarpitak ◽  
...  

The potential utilization of wood/polyvinyl chloride (WPVC) composites containing an X-ray protective filler, namely bismuth oxide (Bi2O3) particles, was investigated as novel, safe, and environmentally friendly X-ray shielding materials. The wood and Bi2O3 contents used in this work varied from 20 to 40 parts per hundred parts of PVC by weight (pph) and from 0 to 25, 50, 75, and 100 pph, respectively. The study considered X-ray shielding, mechanical, density, water absorption, and morphological properties. The results showed that the overall X-ray shielding parameters, namely the linear attenuation coefficient (µ), mass attenuation coefficient (µm), and lead equivalent thickness (Pbeq), of the WPVC composites increased with increasing Bi2O3 contents but slightly decreased at higher wood contents (40 pph). Furthermore, comparative Pbeq values between the wood/PVC composites and similar commercial X-ray shielding boards indicated that the recommended Bi2O3 contents for the 20 pph (40 ph) wood/PVC composites were 35, 85, and 40 pph (40, 100, and 45 pph) for the attenuation of 60, 100, and 150-kV X-rays, respectively. In addition, the increased Bi2O3 contents in the WPVC composites enhanced the Izod impact strength, hardness (Shore D), and density, but reduced water absorption. On the other hand, the increased wood contents increased the impact strength, hardness (Shore D), and water absorption but lowered the density of the composites. The overall results suggested that the developed WPVC composites had great potential to be used as effective X-ray shielding materials with Bi2O3 acting as a suitable X-ray protective filler.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1261
Author(s):  
Catarina S. P. Borges ◽  
Alireza Akhavan-Safar ◽  
Eduardo A. S. Marques ◽  
Ricardo J. C. Carbas ◽  
Christoph Ueffing ◽  
...  

Short fiber reinforced polymers are widely used in the construction of electronic housings, where they are often exposed to harsh environmental conditions. The main purpose of this work is the in-depth study and characterization of the water uptake behavior of PBT-GF30 (polybutylene terephthalate with 30% of short glass fiber)as well as its consequent effect on the mechanical properties of the material. Further analysis was conducted to determine at which temperature range PBT-GF30 starts experiencing chemical changes. The influence of testing procedures and conditions on the evaluation of these effects was analyzed, also drawing comparisons with previous studies. The water absorption behavior was studied through gravimetric tests at 35, 70, and 130 °C. Fiber-free PBT was also studied at 35 °C for comparison purposes. The effect of water and temperature on the mechanical properties was analyzed through bulk tensile tests. The material was tested for the three temperatures in the as-supplied state (without drying or aging). Afterwards, PBT-GF30 was tested at room temperature following water immersion at the three temperatures. Chemical changes in the material were also analyzed through Fourier-transform infrared spectroscopy (FTIR). It was concluded that the water diffusion behavior is Fickian and that PBT absorbs more water than PBT-GF30 but at a slightly higher rate. However, temperature was found to have a more significant influence on the rate of water diffusion of PBT-GF30 than fiber content did. Temperature has a significant influence on the mechanical properties of the material. Humidity contributes to a slight drop in stiffness and strength, not showing a clear dependence on water uptake. This decrease in mechanical properties occurs due to the relaxation of the polymeric chain promoted by water ingress. Between 80 and 85 °C, after water immersion, the FTIR profile of the material changes, which suggests chemical changes in the PBT. The water absorption was simulated through heat transfer analogy with good results. From the developed numerical simulation, the minimum plate size to maintain the water ingress unidirectional was 30 mm, which was validated experimentally.


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