Direct 3D printing of transparent magnesium aluminate spinel ceramics

2021 ◽  
Vol 33 (1) ◽  
pp. 012018
Author(s):  
John M. Pappas ◽  
Aditya R. Thakur ◽  
Edward C. Kinzel ◽  
Xiangyang Dong
Keyword(s):  
3D Printing ◽  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel

scholarly journals Direct 3D Printing of Silica Doped Transparent Magnesium Aluminate Spinel Ceramics

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4810
Author(s):  
John M. Pappas ◽  
Xiangyang Dong
Keyword(s):  
3D Printing ◽  
Crack Density ◽  
Secondary Phase ◽  
Optical Transmittance ◽  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel ◽  
Deposition Method ◽  
Direct Deposition ◽  
Dopant Level ◽  
Laser Direct Deposition

Transparent magnesium aluminate spinel ceramics were additively manufactured via a laser direct deposition method in this study. With a minimum porosity of 0.3% achieved, highly transparent spinel samples with the highest total optical transmittance of 82% at a wavelength of 632.8 nm, were obtained by a 3D printing approach. However, cracking was found to be a major issue affecting printed spinel samples. To control prevalent cracking, the effect of silica dopants was investigated. Increased silica dopants reduced average total crack length by up to 79% and average crack density by up to 71%. However, a high dopant level limited optical transmission, attributed to increased porosity and formation of secondary phase. Further investigation found that with decreased average fracture toughness, from 2.4 MPa·m1/2 to 1.9 MPa·m1/2, the obvious reduction in crack formation after doping was related to decreased grain size and introduction of softer secondary phase during deposition. The study demonstrated the feasibility of the proposed laser direct deposition method in directly fabricating transparent spinel ceramics while dopants showed potentials in addressing cracking issues.

scholarly journals Synthesis and characterization of a new ZIF-67@MgAl2O4 nanocomposite and its adsorption behaviour

RSC Advances ◽  
2021 ◽  
Vol 11 (22) ◽  
pp. 13245-13255
Author(s):  
Mehdi Davoodi ◽  
Fatemeh Davar ◽  
Mohammad R. Rezayat ◽  
Mohammad T. Jafari ◽  
Mehdi Bazarganipour ◽  
...  
Keyword(s):  
Room Temperature ◽  
Magnesium Aluminate ◽  
Synthesis And Characterization ◽  
Magnesium Aluminate Spinel ◽  
Adsorption Behaviour ◽  
Zeolitic Imidazolate Framework ◽  
Simple Method

New nanocomposite of zeolitic imidazolate framework-67@magnesium aluminate spinel (ZIF-67@MgAl2O4) has been fabricated by a simple method at room temperature with different weight ratios.

scholarly journals Optical glass-ceramics based on nanosized crystals of magnesium aluminate spinel doped with iron ions

2020 ◽  
Vol 1697 ◽  
pp. 012156
Author(s):  
V Bukina ◽  
O Dymshits ◽  
I Alekseeva ◽  
M Tsenter ◽  
S Zapalova ◽  
...  
Keyword(s):  
Optical Glass ◽  
Glass Ceramics ◽  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel ◽  
Iron Ions ◽  
Nanosized Crystals

Transparency of zirconia and magnesium aluminate spinel ceramics manufactured by SPS technique

Ifost ◽  
2013 ◽  
Author(s):  
Khasanov Oleg ◽  
Dvilis Edgar ◽  
Kachaev Artem ◽  
Khasanov Alexey ◽  
Polisadova Elena
Keyword(s):  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel

Flash-sintering of magnesium aluminate spinel (MgAl2O4) ceramics

2016 ◽  
Vol 100 (2) ◽  
pp. 554-562 ◽  
Author(s):  
Hidehiro Yoshida ◽  
Papiya Biswas ◽  
Roy Johnson ◽  
Mantravadi Krishna Mohan
Keyword(s):  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel ◽  
Flash Sintering ◽  
Spinel Mgal2o4

Performance Studies on In Situ Spinel Solid Solution Bonded Periclase Refractories

2014 ◽  
Vol 633 ◽  
pp. 245-248
Author(s):  
Xin Lin ◽  
Yong Li ◽  
Yan Jing Li ◽  
Jun Jie Zhang ◽  
Chang He Gao ◽  
...  
Keyword(s):  
Solid Solution ◽  
Phase Composition ◽  
Performance Studies ◽  
Magnesium Aluminate ◽  
Spinel Solid Solution ◽  
Magnesium Aluminate Spinel ◽  
Crushing Strength ◽  
Cold Crushing Strength ◽  
Shock Resistance

Specimens were prepared using iron-rich magnesia (3~1 mm、≤1 mm) and high purity magnesia (≤0.088 mm) as the main starting materials, adding tabular alumina at different size (3~2、2~1、≤1 mm) and content:3%、6%、9%、12%、15% to discover the influence of tabular alumina on sample performance. Phase composition and microstructure were also analyzed. The results show that specimen with content of 6% of corundum possessed the best comprehensive performance:apparent porosity 17%, bulk density 2.95 g·cm-3, cold crushing strength 74 MPa, refractoriness under load 1700 °C, heat shock resistance of up to 18 times. The formations of magnesium aluminate spinel and hercynite solid solution were enhanced by Fe ion at high temperatures in the iron-rich magnesia-corundum system at the presence of iron oxides, which are able to largely dissolved in periclase.

Low cost foam-gelcasting preparation and characterization of porous magnesium aluminate spinel (MgAl2O4) ceramics

2016 ◽  
Vol 42 (16) ◽  
pp. 18215-18222 ◽  
Author(s):  
Xiangong Deng ◽  
Junkai Wang ◽  
Jianghao Liu ◽  
Haijun Zhang ◽  
Lei Han ◽  
...  
Keyword(s):  
Low Cost ◽  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel ◽  
Porous Magnesium ◽  
Spinel Mgal2o4
Sign in / Sign up

Export Citation Format

Share Document