TEA CO2 Laser‐Induced Infrared Multiphoton Dissociation of Zirconium Tetra‐tert‐Butoxide: Reaction Mechanism and Dissociation Products

1992 ◽  
Vol 4 (1) ◽  
pp. 15-21
Author(s):  
Yoshiki Okada ◽  
Shuji Kato ◽  
Sakae Satooka ◽  
Kazuo Takeuchi
1981 ◽  
Vol 59 (9) ◽  
pp. 1307-1310 ◽  
Author(s):  
E. Weinberg ◽  
M. Gauthier ◽  
P. A. Hackett ◽  
C. Willis

Infrared multiphoton dissociation of pentafluoroiodoethane leads to a complex array of reaction products. For photolysis in the v4 band the reaction mechanism involves C2F5—I bond cleavage followed by thermal dissociation of C2F5 radicals. For irradiation within the v3 band at high fluence, efficient secondary photolysis of C2F5 radicals is postulated. At lower fluences the dissociation is isotopically selective leading to C4F10 enriched in carbon-13.


2004 ◽  
Vol 79 (7) ◽  
pp. 883-889 ◽  
Author(s):  
A. Yokoyama ◽  
H. Ohba ◽  
M. Hashimoto ◽  
K. Katsumata ◽  
H. Akagi ◽  
...  

1981 ◽  
Vol 78 (2) ◽  
pp. 273-276 ◽  
Author(s):  
R.S. Karve ◽  
S.K. Sarkar ◽  
K.V.S.Rama Rao ◽  
Jai P. Mittal

2002 ◽  
Vol 114 (6) ◽  
pp. 659-673 ◽  
Author(s):  
Manoj Kumar ◽  
Anant Deshpande ◽  
Chintan Gupta ◽  
A. K. Biswas ◽  
A. K. Nath

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