Effect of octahedrally coordinated aluminum ions on the uptake of Au(III) chloro-hydroxy complexes in Al-Si systems

2015 ◽  
Vol 49 (4) ◽  
pp. 343-350
Author(s):  
Tsubasa Otake ◽  
Takushi Yokoyama ◽  
Paul C. M. Francisco ◽  
Koichiro Watanabe
Keyword(s):  
Aluminum Ions

scholarly journals Direct Ink Writing of Highly Conductive MXene Frames for Tunable Electromagnetic Interference Shielding and Electromagnetic Wave-Induced Thermochromism

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Xinyu Wu ◽  
Tingxiang Tu ◽  
Yang Dai ◽  
Pingping Tang ◽  
Yu Zhang ◽  
...  
Keyword(s):  
Electromagnetic Wave ◽  
Electromagnetic Interference ◽  
High Performance ◽  
Normal Operation ◽  
List Type ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Direct Ink Writing ◽  
Aluminum Ions ◽  
Wave Induced

Highlights 3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated. Highly conductive MXene frames are reinforced by cross-linking with aluminum ions. Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns. Abstract The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25–80 dB with the highest electrical conductivity of 5323 S m−1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.

Hydrogel optical fibers functionalized with lumogallion as aluminum ions sensing platform

Optik ◽  
2021 ◽  
Vol 240 ◽  
pp. 166875
Author(s):  
Fenghong Chu ◽  
Pengfei Han ◽  
Shi Feng ◽  
Shuangjiao Wei ◽  
Huyong Ma ◽  
...  
Keyword(s):  
Optical Fibers ◽  
Aluminum Ions ◽  
Sensing Platform

scholarly journals Selective Membrane Sensor for Aluminum Determination in Food Products, Real Samples and Standard Alloys

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 504
Author(s):  
Sabry Khalil ◽  
Ashraf Y. Elnaggar
Keyword(s):  
Liquid Membrane ◽  
Food Products ◽  
Ion Selective Electrodes ◽  
Real Samples ◽  
Membrane Sensor ◽  
Aluminum Ion ◽  
Electrode Response ◽  
Aluminum Ions ◽  
Selective Membrane ◽  
Ph Range

The study involves the fabrication of an aluminum liquid membrane sensor based on the association of aluminum ions with the cited reagent 2,9-dimethyl-4,11-diphenyl -1,5,8,12-tetraaza cyclote tradeca-1,4,8,11-tetraene [DDTCT]. The characteristics slope (58 mV), rapid and linear response for aluminum ion was displayed by the proposed sensor within the concentration range 2.5 × 10−7–1.5 × 10−1 M, the detection limit (1.6 × 10−7) M, the selectivity behavior toward some metal cations, the response time 10 s), lifetime (150 days), the effect of pH on the suggested electrode potential and the requisite analytical validations were examined. The suitable pH range was (5.0–8.0 ), in this range the proposed electrode response is independent of pH. The suggested electrode was applied to detect the aluminum ions concentration in food products, real samples and standard alloys. The resulting data by the suggested electrode were statistically analyzed, and compared with the previously reported aluminum ion-selective electrodes in the literature.

scholarly journals Acylated Anthocyanins from Red Cabbage and Purple Sweet Potato Can Bind Metal Ions and Produce Stable Blue Colors

2021 ◽  
Vol 22 (9) ◽  
pp. 4551
Author(s):  
Julie-Anne Fenger ◽  
Gregory T. Sigurdson ◽  
Rebecca J. Robbins ◽  
Thomas M. Collins ◽  
M. Mónica Giusti ◽  
...  
Keyword(s):  
Metal Ions ◽  
Sweet Potato ◽  
Metal Binding ◽  
Metal Ion ◽  
High Resolution Mass Spectrometry ◽  
Large Set ◽  
Water Addition ◽  
Red Cabbage ◽  
Aluminum Ions ◽  
Purple Sweet Potato

Red cabbage (RC) and purple sweet potato (PSP) are naturally rich in acylated cyanidin glycosides that can bind metal ions and develop intramolecular π-stacking interactions between the cyanidin chromophore and the phenolic acyl residues. In this work, a large set of RC and PSP anthocyanins was investigated for its coloring properties in the presence of iron and aluminum ions. Although relatively modest, the structural differences between RC and PSP anthocyanins, i.e., the acylation site at the external glucose of the sophorosyl moiety (C2-OH for RC vs. C6-OH for PSP) and the presence of coordinating acyl groups (caffeoyl) in PSP anthocyanins only, made a large difference in the color expressed by their metal complexes. For instance, the Al3+-induced bathochromic shifts for RC anthocyanins reached ca. 50 nm at pH 6 and pH 7, vs. at best ca. 20 nm for PSP anthocyanins. With Fe2+ (quickly oxidized to Fe3+ in the complexes), the bathochromic shifts for RC anthocyanins were higher, i.e., up to ca. 90 nm at pH 7 and 110 nm at pH 5.7. A kinetic analysis at different metal/ligand molar ratios combined with an investigation by high-resolution mass spectrometry suggested the formation of metal–anthocyanin complexes of 1:1, 1:2, and 1:3 stoichiometries. Contrary to predictions based on steric hindrance, acylation by noncoordinating acyl residues favored metal binding and resulted in complexes having much higher molar absorption coefficients. Moreover, the competition between metal binding and water addition to the free ligands (leading to colorless forms) was less severe, although very dependent on the acylation site(s). Overall, anthocyanins from purple sweet potato, and even more from red cabbage, have a strong potential for development as food colorants expressing red to blue hues depending on pH and metal ion.

Synthesis of nano-pore size Al(III)-imprinted polymer for the extraction and preconcentration of aluminum ions

2012 ◽  
Vol 10 (4) ◽  
pp. 669-676 ◽  
Author(s):  
Farid Shakerian ◽  
Shayessteh Dadfarnia ◽  
Ali Mohammad Haji Shabani
Keyword(s):  
Pore Size ◽  
Imprinted Polymer ◽  
Aluminum Ions

Electrical properties of chemically doped graphene with Aluminum ions

2016 ◽  
Author(s):  
Prashant Jain ◽  
Cheng Zhang ◽  
Jiang'ao Huang ◽  
Kamal Ahmad ◽  
Dan Xie ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Aluminum Ions ◽  
Doped Graphene

Toxicity of Aluminum Ions to Daphnia magna Straus Depending on the Hardness of Natural and Artificial Water

2020 ◽  
Vol 75 (4) ◽  
pp. 231-236
Author(s):  
O. V. Vorobieva ◽  
E. F. Isakova ◽  
M. A. Zaec ◽  
A. Yu. Merzelikin ◽  
T. A. Samoilova
Keyword(s):  
Daphnia Magna ◽  
Aluminum Ions ◽  
Artificial Water
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