Combined In Situ CO2 Generation and Chemical Flooding for Viscous Oil Recovery

Author(s):  
B.J. Ben Shiau ◽  
Tzu-Ping Hsu ◽  
Sang-Ho Bang ◽  
Bruce L. Roberts ◽  
Jeffrey H. Harwell
2018 ◽  
Vol 40 (2) ◽  
pp. 85-90
Author(s):  
Yani Faozani Alli ◽  
Edward ML Tobing ◽  
Usman Usman

The formation of microemulsion in the injection of surfactant at chemical flooding is crucial for the effectiveness of injection. Microemulsion can be obtained either by mixing the surfactant and oil at the surface or injecting surfactant into the reservoir to form in situ microemulsion. Its translucent homogeneous mixtures of oil and water in the presence of surfactant is believed to displace the remaining oil in the reservoir. Previously, we showed the effect of microemulsion-based surfactant formulation to reduce the interfacial tension (IFT) of oil and water to the ultralow level that suffi cient enough to overcome the capillary pressure in the pore throat and mobilize the residual oil. However, the effectiveness of microemulsion flooding to enhance the oil recovery in the targeted representative core has not been investigated.In this article, the performance of microemulsion-based surfactant formulation to improve the oil recovery in the reservoir condition was investigated in the laboratory scale through the core flooding experiment. Microemulsion-based formulation consist of 2% surfactant A and 0.85% of alkaline sodium carbonate (Na2CO3) were prepared by mixing with synthetic soften brine (SSB) in the presence of various concentration of polymer for improving the mobility control. The viscosity of surfactant-polymer in the presence of alkaline (ASP) and polymer drive that used for chemical injection slug were measured. The tertiary oil recovery experiment was carried out using core flooding apparatus to study the ability of microemulsion-based formulation to recover the oil production. The results showed that polymer at 2200 ppm in the ASP mixtures can generate 12.16 cP solution which is twice higher than the oil viscosity to prevent the fi ngering occurrence. Whereas single polymer drive at 1300 ppm was able to produce 15.15 cP polymer solution due to the absence of alkaline. Core flooding experiment result with design injection of 0.15 PV ASP followed by 1.5 PV polymer showed that the additional oil recovery after waterflood can be obtained as high as 93.41% of remaining oil saturation after waterflood (Sor), or 57.71% of initial oil saturation (Soi). Those results conclude that the microemulsion-based surfactant flooding is the most effective mechanism to achieve the optimum oil recovery in the targeted reservoir.


2018 ◽  
Vol 32 (1) ◽  
pp. 360-372 ◽  
Author(s):  
Chao-Yu Sie ◽  
Bradley Nguyen ◽  
Marco Verlaan ◽  
Orlando Castellanos-Diaz ◽  
Kelli Adiaheno ◽  
...  

2021 ◽  
Author(s):  
Vladimir Nikolaevich Kozhin ◽  
Andrey Valerevich Mikhailov ◽  
Konstantin Vasilievich Pchela ◽  
Ivan Ivanovich Kireev ◽  
Sergey Valerevich Demin ◽  
...  

Abstract The paper presents the results of lab and filtration studies aimed at improving the procedure of thermal/gas/chemical effect (TGCE) with the generation of thermogenic system in reservoir conditions, proposed as an alternative to the methods of increasing oil recovery, such as water-gas effect procedure and foam injection process. The objects of research were thermal/gas generating compositions at the basis of sodium salts of sulfamic and nitric acids. Moreover, the influence of the ionic composition of the aqueous solution and temperature on the surface properties of the attracted solutions of surfactants (surfactants) was also evaluated. Filtration tests have shown that the use of a thermal/gas generating composition leads to additional displacement of high-viscous oil. The introduction of surfactants in the thermal/gas generating composition promotes foaming in the porous medium of the reservoir model and prevents gas breakthrough that leads to an increase in the oil displacement factor up to 24 %.


2018 ◽  
Author(s):  
Bartek Vik ◽  
Abduljelil Kedir ◽  
Vegard Kippe ◽  
Kristian Sandengen ◽  
Tormod Skauge ◽  
...  

2016 ◽  
Vol 2016 ◽  
pp. 1-13 ◽  
Author(s):  
Yong Tang ◽  
Zhengyuan Su ◽  
Jibo He ◽  
Fulin Yang

This paper presents the numerical investigation and optimization of the operating parameters of the in situ generated CO2Huff-n-Puff method with compound surfactant on the performance of enhanced oil recovery. First, we conducted experiments of in situ generated CO2and surfactant flooding. Next, we constructed a single-well radial 3D numerical model using a thermal recovery chemical flooding simulator to simulate the process of CO2Huff-n-Puff. The activation energy and reaction enthalpy were calculated based on the reaction kinetics and thermodynamic models. The interpolation parameters were determined through history matching a series of surfactant core flooding results with the simulation model. The effect of compound surfactant on the Huff-n-Puff CO2process was demonstrated via a series of sensitivity studies to quantify the effects of a number of operation parameters including the injection volume and mole concentration of the reagent, the injection rate, the well shut-in time, and the oil withdrawal rate. Based on the daily production rate during the period of Huff-n-Puff, a desirable agreement was shown between the field applications and simulated results.


SPE Journal ◽  
2016 ◽  
Vol 22 (01) ◽  
pp. 130-137 ◽  
Author(s):  
Chuan Lu ◽  
Huiqing Liu ◽  
Wei Zhao ◽  
Keqin Lu ◽  
Yongge Liu ◽  
...  

Summary In this study, the effects of viscosity-reducer (VR) concentration, salinity, water/oil ratio (WOR), and temperature on the performance of emulsions are examined on the basis of the selected VR. Different VR-injection scenarios, including single-VR injection and coinjection of steam and VR, are conducted after steamflooding by use of single-sandpack models. The results show that high VR concentration, high WOR, and low salinity are beneficial to form stable oil/water emulsions. The oil recoveries of steamflooding for bitumen and heavy oil are approximately 31 and 52%, respectively. The subsequent VR flooding gives an incremental oil recovery of 5.2 and 6.4% for bitumen and heavy oil, respectively. Flooding by steam/VR induces an additional oil recovery of 8.4–11.0% for bitumen and 12.1% for heavy oil. High-temperature steam favors the peeling off of oil and improving its fluidity, as well as the in-situ emulsions. VR solution is beneficial for the oil dispersion and further viscosity reduction. The coinjection of high-temperature steam and VR is much more effective for additional oil production in viscous-oil reservoirs.


Fuel ◽  
2019 ◽  
Vol 247 ◽  
pp. 294-301 ◽  
Author(s):  
Chao-Yu Sie ◽  
Bradley Nguyen ◽  
Orlando Castellanos Diaz ◽  
Marco Verlaan ◽  
Quoc P. Nguyen

2019 ◽  
Vol 12 (1) ◽  
Author(s):  
Pratik Prashant Pawar ◽  
Annamma Anil Odaneth ◽  
Rajeshkumar Natwarlal Vadgama ◽  
Arvind Mallinath Lali

Abstract Background Recent trends in bioprocessing have underlined the significance of lignocellulosic biomass conversions for biofuel production. These conversions demand at least 90% energy upgradation of cellulosic sugars to generate renewable drop-in biofuel precursors (Heff/C ~ 2). Chemical methods fail to achieve this without substantial loss of carbon; whereas, oleaginous biological systems propose a greener upgradation route by producing oil from sugars with 30% theoretical yields. However, these oleaginous systems cannot compete with the commercial volumes of vegetable oils in terms of overall oil yields and productivities. One of the significant challenges in the commercial exploitation of these microbial oils lies in the inefficient recovery of the produced oil. This issue has been addressed using highly selective oil capturing agents (OCA), which allow a concomitant microbial oil production and in situ oil recovery process. Results Adsorbent-based oil capturing agents were employed for simultaneous in situ oil recovery in the fermentative production broths. Yarrowia lipolytica, a model oleaginous yeast, was milked incessantly for oil production over 380 h in a media comprising of glucose as a sole carbon and nutrient source. This was achieved by continuous online capture of extracellular oil from the aqueous media and also the cell surface, by fluidizing the fermentation broth over an adsorbent bed of oil capturing agents (OCA). A consistent oil yield of 0.33 g per g of glucose consumed, corresponding to theoretical oil yield over glucose, was achieved using this approach. While the incorporation of the OCA increased the oil content up to 89% with complete substrate consumptions, it also caused an overall process integration. Conclusion The nondisruptive oil capture mediated by an OCA helped in accomplishing a trade-off between microbial oil production and its recovery. This strategy helped in realizing theoretically efficient sugar-to-oil bioconversions in a continuous production process. The process, therefore, endorses a sustainable production of molecular drop-in equivalents through oleaginous yeasts, representing as an absolute microbial oil factory.


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