The Reaction of Phenols with Tertiary Butyl Chloride

Microwave Spectrum of Tertiary Butyl Chloride. A Comparison of Tertiary Butyl Structures

The Journal of Chemical Physics ◽

10.1063/1.1776910 ◽

1963 ◽

Vol 38 (7) ◽

pp. 1504-1507 ◽

Cited By ~ 45

Author(s):

David R. Lide ◽

May Jen

Keyword(s):

Microwave Spectrum ◽

Butyl Chloride ◽

Tertiary Butyl

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Ionization and Dissociation by Electron Impact: Normal Propyl Chloride and Tertiary Butyl Chloride

Journal of the American Chemical Society ◽

10.1021/ja01264a015 ◽

1942 ◽

Vol 64 (12) ◽

pp. 2766-2768 ◽

Cited By ~ 19

Author(s):

D. P. Stevenson ◽

John A. Hipple

Keyword(s):

Electron Impact ◽

Butyl Chloride ◽

Tertiary Butyl

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ChemInform Abstract: Improved Synthesis of 1-Chloroadamantane by Hydride Transfer Induced by Tertiary Butyl Chloride.

ChemInform ◽

10.1002/chin.199011114 ◽

1990 ◽

Vol 21 (11) ◽

Cited By ~ 1

Author(s):

R. JALAL ◽

R. GALLO

Keyword(s):

Hydride Transfer ◽

Butyl Chloride ◽

Tertiary Butyl

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The effect of heterogenous doping on heterogeneous catalysis: Dehydrohalogenation of tertiary butyl chloride

Solid State Ionics ◽

10.1016/0167-2738(90)90176-r ◽

1990 ◽

Vol 40-41 ◽

pp. 1017-1020 ◽

Cited By ~ 8

Author(s):

J MAIER ◽

P MURUGARAJ

Keyword(s):

Heterogeneous Catalysis ◽

Butyl Chloride ◽

Tertiary Butyl

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The Rate and Mechanism of Hydrolysis and Alcoholysis of Tertiary Butyl Chloride. An Application to the Transition State Theory of Solvent Effects

Journal of the American Chemical Society ◽

10.1021/ja01291a048 ◽

1937 ◽

Vol 59 (12) ◽

pp. 2644-2647 ◽

Cited By ~ 11

Author(s):

A. R. Olson ◽

R. S. Halford

Keyword(s):

Transition State ◽

Solvent Effects ◽

Transition State Theory ◽

State Theory ◽

Butyl Chloride ◽

Tertiary Butyl ◽

Mechanism Of Hydrolysis

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Preparation of tertiary butyl chloride

Journal of Chemical Education ◽

10.1021/ed007p313 ◽

1930 ◽

Vol 7 (2) ◽

pp. 313

Author(s):

P. M. Ginnings

Keyword(s):

Butyl Chloride ◽

Tertiary Butyl

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Kinetics of reaction of some anion-radicals with tertiary butyl chloride

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00854272 ◽

1973 ◽

Vol 22 (5) ◽

pp. 1130-1131

Author(s):

R. Nasirov ◽

S. P. Solodovnikova

Keyword(s):

Butyl Chloride ◽

Tertiary Butyl ◽

Kinetics Of Reaction ◽

Kinetics Of ◽

Anion Radicals

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The Temperature Dependence of Band Maxima Molar Absorptivities of the Carbon-Halogen Stretching Mode in Tertiary Butyl Chloride, Bromide, and Iodide in the Liquid Phase

Applied Spectroscopy ◽

10.1366/0003702874449084 ◽

1987 ◽

Vol 41 (3) ◽

pp. 468-471 ◽

Cited By ~ 5

Author(s):

J. E. Katon ◽

Stanislaus R. Lobo ◽

J. C. Simpson

Keyword(s):

Mathematical Model ◽

Liquid Phase ◽

Temperature Dependence ◽

Linear Relationship ◽

Molar Absorptivity ◽

Absolute Temperature ◽

Significant Error ◽

Butyl Chloride ◽

Tertiary Butyl ◽

Relationship Of

The absorbances at the peak maxima of the carbon-halogen stretching mode of t-butyl chloride, bromide, and iodide have been measured as a function of temperature. With the use of corrected concentration and pathlengths, these data have been converted into molar absorptivities at the respective peak maxima. The data have then been analyzed statistically for the purpose of developing a mathematical model for the dependency of molar absorptivity, at these peak maxima, on the absolute temperature. In all three cases, a linear relationship of the form e = XT + Y was found to satisfactorily fit the data. The molar absorptivity of all three band maxima decreases approximately 1% per Kelvin. This result indicates that attempts to apply Beer's law at temperatures other than that used to derive the constants will lead to significant error if the temperatures differ by more than a few degrees.

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