Electron Spin Resonance and Pulse Radiolysis Studies of Irradiated Aqueous Solutions of 5-Nitrouracils. Oxidative Denitration by OH Radicals

1973 ◽  
Vol 54 (1) ◽  
pp. 35 ◽  
Author(s):  
P. Neta ◽  
C. L. Greenstock
Keyword(s):  
Electron Spin Resonance ◽  
Aqueous Solutions ◽  
Electron Spin ◽  
Pulse Radiolysis ◽  
Oh Radicals ◽  
Spin Resonance

Correlation of optical and electron spin resonance spectra for alkali metal solutions in ethylamine and tetrahydrofuran

1976 ◽  
Vol 54 (19) ◽  
pp. 3110-3113 ◽  
Author(s):  
R. Catterall ◽  
J. Slater ◽  
W. A. Seddon ◽  
J. W. Fletcher
Keyword(s):  
Electron Spin Resonance ◽  
Optical Absorption ◽  
Alkali Metal ◽  
Electron Spin ◽  
Hyperfine Splitting ◽  
Pulse Radiolysis ◽  
Optical Absorption Spectra ◽  
Monomeric Species ◽  
Spin Resonance ◽  
Sodium Tetraphenylboron

The band maxima of transient optical absorption spectra observed by pulse radiolysis in ethylamine (EA)/tetrahydrofuran (THF) mixtures containing sodium tetraphenylboron are correlated with electron spin resonance (esr) hyperfine splitting constants obtained in potassium/EA/THF solutions. The data suggest that the optical spectra can be attributed to the same 'monomeric' species as observed by esr in alkali metal solutions.

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