scholarly journals Experimental study on combustion of CH4/NH3 fuel blends in an industrial furnace operated in flameless conditions

2020 ◽  
Vol 24 (6 Part A) ◽  
pp. 3625-3635
Author(s):  
Rafal Slefarski ◽  
Pawel Czyzewski ◽  
Michal Golebiewski

This paper presents the results of an experimental study on the combustion process of methane mixed with NH3 in flameless mode. At a time of striving for CO2-free power, NH3 became a potential energy storage carrier fuel from renewable sources. Flameless combustion features low emissions and is a very efficient technology used in the power sector, as well as steel production, ceramics, etc. Industrial furnaces were tested in the context of pure methane combustion with an addition of NH3, up to 5%. Flameless combustion conditions were achieved with a regenerative gas burner system (high regenerative system). The burner consists of four ceramic regenerators allowing for continuous preheating of air, even up to 50 K lower than the temperature of the combustion chamber wall. Constant power of the introduced fuel was kept at 150 kW and the fuel-air equivalence ratio ranged from 0.75 to 0.95. The results have shown a growth of molar fraction of NO in flue gases when NH3 content in the fuel rose. The increase is more significant for the tests with a higher amount of oxygen in the combustion chamber (a lower fuel-air equivalence ratio). An addition of 5% of NH3 into the fuel caused an emission of NO at the levels of 113 ppmv and 462 ppmv (calculated to O2 = 0%), respectively for low and high fuel-air equivalence ratios.

Vestnik IGEU ◽  
2021 ◽  
pp. 14-22
Author(s):  
I.I. Komarov ◽  
D.M. Kharlamova ◽  
A.N. Vegera ◽  
V.Y. Naumov

Studying closed gas turbine cycles on supercritical carbon dioxide is currently a promising issue in the development of power energy sector in terms of increasing energy efficiency and minimizing greenhouse gas emissions into the atmosphere. Combustion of methane with oxygen in the combustion chamber occurs not in the nitrogen environment, but in the environment of carbon dioxide, that is the working fluid of the cycle, which is an inhibitor of chemical reactions. A large mass content of such a diluent of the reaction mixture in the volume of the chamber leads to the risks of significant chemical underburning, efficiency decrease of the combustion chamber and the cycle as a whole. The aim of the research is to study the kinetic parameters of the combustion of methane with oxygen in a supercritical CO2 diluent medium to ensure reliable and stable combustion of fuel by assessing the degree of the inhibitory effect of CO2 and determining its permissible amount in the active combustion zone of the combustion chamber. The research method is a numerical simulation of turbulent-kinetic processes of methane combustion in the combustion chamber using the reduced methane combustion mechanism. Ansys Fluent software package has been used. The authers have studied the impact of CO2 diluent on fuel cоmbustion in methane-oxygen combustion chambers. It is found that the combustor flame stabilization takes place if the content of СО2 diluent supplied to the mixture with oxidizer is 0,46–0,5 of mass fraction; additional СО2 diluent forms local low temperature zones which slow down the combustion process. When this happens, adding cooling СО2 into the flame stabilization zone should be eliminated. The study has found that no more than 20 % of the total carbon dioxide content should be supplied to the combustion chamber; to stabilize the flame and reduce its length, it is necessary to install blades to swirl the fuel and oxidizer mixed with CO2 at the inlet of the combustion chamber; CO2 supply for cooling should be carried out not less than 130 mm away from the burner mouth.


1999 ◽  
Author(s):  
Toshio Shudo ◽  
Yasuo Nakajima ◽  
Takayuki Futakuchi

Abstract Hydrogen has higher flame velocity and smaller quenching distance than hydrocarbon fuels, and is supposed to have special characteristics in combustion process of internal combustion engines. In this research, contributors to thermal efficiency in a hydrogen premixed spark ignition engine were analyzed and compared with methane combustion. Results showed hydrogen combustion had higher cooling loss to combustion chamber wall, and thermal efficiency of hydrogen combustion was mainly dominated by both cooling loss to combustion chamber wall and degree of constant volume combustion.


Author(s):  
Francesco Fantozzi ◽  
Paolo Laranci ◽  
Michele Bianchi ◽  
Andrea De Pascale ◽  
Michele Pinelli ◽  
...  

Micro gas turbines could be profitably used, for distributed energy production, also exploiting low calorific value biomass-derived fuels, obtained by means of integrated pyrolysis and/or gasification processes. These synthesis gases show significant differences with respect to natural gas (in terms of composition, low calorific value, hydrogen content, tar and particulate matter content) that may turn into ignition problems, combustion instabilities, difficulties in emission control and fouling. CFD simulation of the combustion chamber is a key instrument to identify main criticalities arising when using these gases, in order to modify existing geometries and to develop new generation combustion chambers for use with low calorific value gases. This paper describes the numerical activity carried out to analyze the combustion process occurring inside an existing microturbine annular combustor. A CFD study of the combustion process performed with different computational codes is introduced and some preliminary results are reported in the paper. A comparison of results obtained with the different codes is provided, for the reference case of methane combustion. A first evaluation of the pollutant emissions and a comparison with the available experimental data is also provided in the paper, showing in particular a good matching of experimental data on NOx emissions at different load conditions. Moreover, the carried out investigation concerns the case of operation with a syngas fuel derived from pyrolysis of biomass and finally the case of syngas and natural gas co-firing. This combustion condition is simulated with a simple reduced chemical kinetic scheme, in order to assess only the key issues rising with this fuel in comparison with the case of methane combustion. The analysis shows that in case of syngas operation the combustor internal temperature hot spots are reduced and the primary zone flame tends to stabilize closer to the injector, with possible implications on the emission release.


2020 ◽  
Vol 19 (1) ◽  
pp. 72
Author(s):  
B. P. Trevisan ◽  
W. M. C. Dourado

The evaluation, validation and development of the models used in computation fluid dynamics requires the availability of experimental data for which the boundary conditions, especially the conditions of the inlet flow, are well defined. Laser diagnostics techniques provide experimental data used in computational fluid dynamics and are a powerful tool for measurements of the mean properties and fluctuations of the turbulent flow because they are non-intrusive methods, with high repetition rate and high spatial and temporal resolution. Therefore, in the present work an experimental study of the inlet flow (inert and combusting flows) in a non-premixed combustion chamber is presented. The velocity measurements were carried out using a laser Doppler velocimeter at the entrance region of the combustion chamber. An asymmetry on the mean flow and an increase on the total velocity fluctuations with the increase of the equivalence ratio was observed. The major effect on the increase of the equivalence ratio was a presence of a coherent movement on large scales associated to the flame brush dynamics.


Author(s):  
Adam Kasani ◽  
Mazlan Abdul Wahid ◽  
Ahmad Dairobi Ghazali ◽  
Mohammed Bashir Abdulrahman

This paper presents the experimental results of a simple cylindrical shaped, liquid fuelled flameless combustor which utilizes ultra-high swirl flow in the combustion process. 4 different swirl generator inlet configurations were tested in this work. Ethanol fuel were used during flameless mode. The experiments were conducted at equivalence ratio (F=1), with the flow rate of fuel set at 4.48*104 kg/s, and flow rate of air at 3.854*103 kg/s. The results revealed that by using all 12 tangential air inlets (swirl generator injectors), the swirl strength was reduced through evenly distributing the position of the injectors circumferentially. As a result, the combustor successfully suppressed the emission of NOx and CO to zero ppm for both gasses. It was also reported that flameless mode was established in all configurations, regardless of the swirl strength.


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 662
Author(s):  
Joanna Jójka ◽  
Rafał Ślefarski

This paper details the experimental and numerical analysis of a combustion process for atmospheric swirl burners using methane with added ammonia as fuel. The research was carried out for lean methane–air mixtures, which were doped with ammonia up to 5% and preheated up to 473 K. A flow with internal recirculation was induced by burners with different outflow angles from swirling blades, 30° and 50°, where tested equivalence ratio was 0.71. The NO and CO distribution profiles on specified axial positions of the combustor and the overall emission levels at the combustor outlet were measured and compared to a modelled outcome. The highest values of the NO emissions were collected for 5% NH3 and 50° (1950 ppmv), while a reduction to 1585 ppmv was observed at 30°. The doubling of the firing rates from 15 kW up to 30 kW did not have any great influence on the overall emissions. The emission trend lines were not proportional to the raising share of the ammonia in the fuel. 3D numerical tests and a kinetic study with a reactor network showed that the NO outlet concentration for swirl flame depended on the recirculation ratio, residence time, wall temperature, and the mechanism used. Those parameters need to be carefully defined in order to get highly accurate NO predictions—both for 3D simulations and simplified reactor-based models.


Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2729
Author(s):  
Ireneusz Pielecha ◽  
Sławomir Wierzbicki ◽  
Maciej Sidorowicz ◽  
Dariusz Pietras

The development of internal combustion engines involves various new solutions, one of which is the use of dual-fuel systems. The diversity of technological solutions being developed determines the efficiency of such systems, as well as the possibility of reducing the emission of carbon dioxide and exhaust components into the atmosphere. An innovative double direct injection system was used as a method for forming a mixture in the combustion chamber. The tests were carried out with the use of gasoline, ethanol, n-heptane, and n-butanol during combustion in a model test engine—the rapid compression machine (RCM). The analyzed combustion process indicators included the cylinder pressure, pressure increase rate, heat release rate, and heat release value. Optical tests of the combustion process made it possible to analyze the flame development in the observed area of the combustion chamber. The conducted research and analyses resulted in the observation that it is possible to control the excess air ratio in the direct vicinity of the spark plug just before ignition. Such possibilities occur as a result of the properties of the injected fuels, which include different amounts of air required for their stoichiometric combustion. The studies of the combustion process have shown that the combustible mixtures consisting of gasoline with another fuel are characterized by greater combustion efficiency than the mixtures composed of only a single fuel type, and that the influence of the type of fuel used is significant for the combustion process and its indicator values.


Author(s):  
Chun K. Kwok ◽  
Matthew M. Asada ◽  
Jonathan R. Mita ◽  
Weilin Qu

This paper presents an experimental study of single-phase heat transfer characteristics of binary methanol-water mixtures in a micro-channel heat sink containing an array of 22 microchannels with 240μm × 630μm cross-section. Pure water, pure methanol, and five methanol-water mixtures with methanol molar fraction of 16%, 36%, 50%, 63% and 82% were tested. Key parametric trends were identified and discussed. The experimental study was complemented by a three-dimensional numerical simulation. Numerical predictions and experimental data are in good agreement with a mean absolute error (MAE) of 0.87%.


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