scholarly journals The current distribution in an electrochemical cell. Part V: The determination of the depth of the current line penetration between the edges of the electrodes and the side walls of the cell

1999 ◽  
Vol 64 (12) ◽  
pp. 795-800 ◽  
Author(s):  
Konstantin Popov ◽  
Slavisa Pesic ◽  
Tanja Kostic
Keyword(s):  
Current Distribution ◽  
Electrochemical Cell ◽  
Polarization Curves ◽  
Current Line ◽  
Plane Parallel ◽  
Electrode Arrangement ◽  
A Cell ◽  
Side Walls ◽  
Parallel Electrode

A method for the calculation of the depth of the current line penetration between the edges of the electrodes and the side walls of the cell in a cell with plane parallel electrode arrangement is proposed. The method is verified by the calculation of the polarization curves for the cells in which the electrode edges do not touch the side walls of the cell. The agreement between the calculated and the measured values was fair.

scholarly journals The current distribution in an electrochemical cell. Part VI: The quantitative treatment for cells with three plane parallel electrode arrangements

2001 ◽  
Vol 66 (7) ◽  
pp. 491-498 ◽  
Author(s):  
K.I. Popov ◽  
S.M. Pesic ◽  
P.M. Zivkovic
Keyword(s):  
Quantitative Determination ◽  
Density Distribution ◽  
Current Distribution ◽  
Current Density ◽  
Electrochemical Cell ◽  
Current Density Distribution ◽  
Plane Parallel ◽  
Parallel Electrode ◽  
Quantitative Treatment

Amethod for the quantitative determination of the current density distribuion in cells with a three plane parallel electrode arrangement is proposed. It is shown that the current density distribution can be determined using the data obtained by simple polarization measurements. The relation to the Haring-Blum cell with P = 2 is discussed.

scholarly journals The current distribution in an electrochemical cell. Part VII. Concluding remarks

2002 ◽  
Vol 67 (4) ◽  
pp. 273-278 ◽  
Author(s):  
Konstantin Popov ◽  
S.M. Pesic ◽  
Predrag Zivkovic
Keyword(s):  
Process Parameters ◽  
Current Distribution ◽  
Current Density ◽  
Electrochemical Cell ◽  
Side Wall ◽  
Cell Geometry ◽  
Electrode Edge ◽  
Side Walls ◽  
In Cells

Anew method for the determination of the ability of an electrolyte to distribute uniformly current density in an electrochemical cell is proposed. It is based on the comparison of the current in cells in which the electrode edges touch the cell side walls with the current in cells with different electrode edge ? cell side wall distances. The effects of cell geometry process parameters and current density are discussed and illustrated using the results presented in the previous papers from this series.

scholarly journals The current distribution in an electrochemical cell. Part IV. The relation to the haring-blum method

1999 ◽  
Vol 64 (5-6) ◽  
pp. 341-347
Author(s):  
Konstantin Popov ◽  
Slavisa Pesic ◽  
Tanja Kostic
Keyword(s):  
Current Distribution ◽  
Current Density ◽  
Parallel Plate ◽  
Electrochemical Cell ◽  
Cell Voltage ◽  
A Cell ◽  
Side Walls ◽  
In Cells

It was shown that the current density-cell voltage curves recorded in a cell with parallel plate electrodes for different distances between the edges of the electrodes and side walls of the cell can be used to determine the current distribution in cells of the Haring-Blum type.

scholarly journals A new current line division concept for the determination of the current distribution in electrochemical cells. Part I: Theoretical background of the “corner weakness” effect in electroforming

2000 ◽  
Vol 65 (12) ◽  
pp. 905-914 ◽  
Author(s):  
K.I. Popov ◽  
R.M. Stevanovic
Keyword(s):  
Current Distribution ◽  
Deposition Process ◽  
Theoretical Background ◽  
Theoretical Explanation ◽  
Electrochemical Kinetics ◽  
Electrochemical Cells ◽  
Current Line ◽  
New Approach ◽  
Basic Equations

A new approach to the determination of the current distribution in electrochemical cells, the current line division concept, is introduced. The new concept, based on the basic equations of electrics and electrochemical kinetics, was employed for a theoretical explanation of the phenomenon known in electroforming as ?corner weakness?. It was shown that this phenomenon depends on the kind of control of the deposition process, being the largest in the case of pure ohmic control and disappearing in the case of pure activation control.

scholarly journals Experimental study of the interaction range and association rate of surface-attached cadherin 11

1998 ◽  
Vol 95 (16) ◽  
pp. 9256-9261 ◽  
Author(s):  
Anne Pierres ◽  
Hélène Feracci ◽  
Véronique Delmas ◽  
Anne-Marie Benoliel ◽  
Jean-Paul Thiery ◽  
...  
Keyword(s):  
Adhesion Molecules ◽  
Bond Formation ◽  
Slow Motion ◽  
Classical Type ◽  
Association Rate ◽  
Interaction Range ◽  
A Cell ◽  
Coated Surfaces ◽  
The Relationship

We describe a method allowing quantitative determination of the interaction range and association rate of individual surface-attached molecules. Spherical beads (1.4 μm radius) were coated with recombinant outer domains of the newly described classical type II cadherin 11, a cell adhesion molecule. Beads were driven along cadherin-coated surfaces with a hydrodynamic force of ≈1 pN, i.e., much less than the mechanical strength of many ligand-receptor bonds. Spheres displayed periods of slow motion interspersed with arrests of various duration. Particle position was monitored with 50 Hz frequency and 0.025 μm accuracy. Nearly 1 million positions were recorded and processed. Comparison between experimental and computer-simulated trajectories suggested that velocity fluctuations might be related quantitatively to Brownian motion perpendicular to the surface. The expected amplitude of this motion was of order of 100 nm. Theoretical analysis of the relationship between sphere acceleration and velocity allowed simultaneous determination of the wall shear rate and van der Waals attraction between spheres and surface. The Hamaker constant was estimated at 2.9 × 10−23 J. The frequency of bond formation was then determined as a function of sphere velocity. Experimental data were consistent with the view that the rate of association between a pair of adhesion molecules was ≈1.2 × 10−3 s−1 and the interaction range was ≈10 nm. It is concluded that the presented methodology allows sensitive measurement of sphere-to-surface interactions (with ≈10 fN sensitivity) as well as the effective range and rate of bond formation between individual adhesion molecules.

Non-contact-based determination of membrane permeability to water and dimethyl sulfoxide of cells virtually trapped in a self-induced micro-vortex

Lab on a Chip ◽  
2021 ◽  
Author(s):  
Hsiu-Yang Tseng ◽  
Chiu-Jen Chen ◽  
Zong-Lin Wu ◽  
Yong-Ming Ye ◽  
Guo-Zhen Huang
Keyword(s):  
Cell Membrane ◽  
Dimethyl Sulfoxide ◽  
Membrane Permeability ◽  
Cell Membrane Permeability ◽  
Cell Type ◽  
Cryoprotective Agents ◽  
A Cell

Cell-membrane permeability to water (Lp) and cryoprotective agents (Ps) of a cell type is a crucial cellular information for achieving optimal cryopreservation in the biobanking industry. In this work, a...

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