scholarly journals The enantioselective β-keto ester reductions by Saccharomyces cerevisiae

2006 ◽  
Vol 71 (8-9) ◽  
pp. 889-894 ◽  
Author(s):  
Nosrat Mahmoodi ◽  
Hassan Tajik ◽  
Khalil Tabatabaeian ◽  
Mahmood Shahbazi
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Calcium Phosphate ◽  
Potassium Dihydrogen Phosphate ◽  
Dihydrogen Phosphate ◽  
Ammonium Tartrate ◽  
Potassium Dihydrogen ◽  
Keto Ester ◽  
Keto Esters ◽  
Diammonium Salt ◽  
Hydroxy Esters

The enantioselective yeast reduction of aromatic ?-keto esters, by use of potassium dihydrogen phosphate, calcium phosphate (monobasic), magnesium sulfate and ammonium tartrate (diammonium salt) (10:1:1:50) in water at pH7 as a buffer for 72-120h with 45-90 % conversion to the corresponding aromatic ?-hydroxy esters was achieved by means of Saccharomyces cerevisiae.

Note on the loss of phosphoric acid during fusion with ammonium fluoride

1916 ◽  
Vol 8 (1) ◽  
pp. 136-138
Author(s):  
William A. Davis ◽  
James Arthur Prescott
Keyword(s):  
Calcium Phosphate ◽  
Alkali Metal ◽  
Phosphoric Acid ◽  
Potassium Dihydrogen Phosphate ◽  
Ammonium Fluoride ◽  
Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Disodium Hydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Considerable Loss

1. When salts or minerals containing phosphoric acid are ignited with ammonium fluoride as in the ordinary process of analysis of silicates, considerable loss of the phosphoric acid may occur. It is probable that the phosphorus is volatilised in the form of a phosphorus fluoride.2. The loss is least in the case of salts containing an alkali metal. It is less in the case of disodium hydrogen phosphate than in that of potassium dihydrogen phosphate, and is greatest in the case of phosphates of the alkali earth metals, such as calcium phosphate or apatite.

scholarly journals Optical Absorption Spectra of Vanadyl Ion (Impurities) in Three Host Crystal Compounds

1985 ◽  
Vol 40 (11) ◽  
pp. 1164-1166
Author(s):  
O. P. Agarwal ◽  
Prem Chand
Keyword(s):  
Optical Absorption ◽  
Potassium Dihydrogen Phosphate ◽  
Optical Data ◽  
Dihydrogen Phosphate ◽  
Host Crystal ◽  
Optical Absorption Study ◽  
Potassium Dihydrogen ◽  
Vanadyl Complexes ◽  
Vanadyl Ion ◽  
Magnesium Ammonium

Results of the optical absorption study of vanadyl ion doped in magnesium ammonium sulphate hexahydrate, rubidium sulphate and potassium dihydrogen phosphate single crystals at RT are reported. The nature of optical bands suggests a C4v symmetry of the Vanadyl complexes in conformity with the EPR results. Powder EPR data and optical data are correlated to obtain the MO coefficients.

scholarly journals The Strain Rate Sensitivity and Creep Behavior for the Tripler Plane of Potassium Dihydrogen Phosphate Crystal by Nanoindentation

Micromachines ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 369
Author(s):  
Jianhui Mao ◽  
Wenjun Liu ◽  
Dongfang Li ◽  
Chenkai Zhang ◽  
Yi Ma
Keyword(s):  
Strain Rate ◽  
Strain Rate Sensitivity ◽  
Creep Deformation ◽  
Potassium Dihydrogen Phosphate ◽  
Rate Sensitivity ◽  
Dislocation Nucleation ◽  
Machining Process ◽  
Dihydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Kdp Crystals

As an excellent multifunctional single crystal, potassium dihydrogen phosphate (KDP) is a well-known, difficult-to-process material for its soft-brittle and deliquescent nature. The surface mechanical properties are critical to the machining process; however, the characteristics of deformation behavior for KDP crystals have not been well studied. In this work, the strain rate effect on hardness was investigated on the mechanically polished tripler plane of a KDP crystal relying on nanoindentation technology. By increasing the strain rate from 0.001 to 0.1 s−1, hardness increased from 1.67 to 2.07 GPa. Hence, the strain rate sensitivity was determined as 0.053, and the activation volume of dislocation nucleation was 169 Å3. Based on the constant load-holding method, creep deformation was studied at various holding depths at room temperature. Under the spherical tip, creep deformation could be greatly enhanced with increasing holding depth, which was mainly due to the enlarged holding strain. Under the self-similar Berkovich indenter, creep strain could be reduced at a deeper location. Such an indentation size effect on creep deformation was firstly reported for KDP crystals. The strain rate sensitivity of the steady-state creep flow was estimated, and the creep mechanism was qualitatively discussed.

Assessment of Structural Stability of Dye-Doped Potassium Dihydrogen Phosphate Under Shocked Conditions

2021 ◽  
Author(s):  
A. Sivakumar ◽  
S. Sahaya Jude Dhas ◽  
P. Sivaprakash ◽  
Abdulrahman I. Almansour ◽  
Raju Suresh Kumar ◽  
...  
Keyword(s):  
Structural Stability ◽  
Potassium Dihydrogen Phosphate ◽  
Dihydrogen Phosphate ◽  
Potassium Dihydrogen
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