scholarly journals Phase topology of a NR/BR elastomer blend with active filler

2003 ◽  
Vol 57 (11) ◽  
pp. 568-572
Author(s):  
Milenko Plavsic ◽  
Ivana Pajic-Lijakovic ◽  
Branislav Cubric ◽  
Radivoj Popovic ◽  
Branko Bugarski ◽  
...  
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Weight Ratio ◽  
Dispersed Phase ◽  
Phase Coupling ◽  
Strain Relationship ◽  
Series Type ◽  
The Individual ◽  
Active Carbon Black ◽  
Elastomer Blend

The relations between the structure and mechanical properties of a polymer blend of natural (NR) and polybutadiene (BR) rubber (i.e. a NR/BR blend with the weight ratio of the components 70/30) filled with active carbon black were analysed. The properties of the individual phases in the blend were resolved by modeling the stress-strain relationship according to the Bauer procedure for high extensions. The obtained results indicated that BR is the dispersed phase, having a higher modulus, which was also confirmed by the much better fit of the experimental data to the series type of phase coupling according to the Takanayagy theory.

Study of potential curves by UHF type methods. CH4 molecule and its dissociation products

1986 ◽  
Vol 51 (4) ◽  
pp. 731-737
Author(s):  
Viliam Klimo ◽  
Jozef Tiňo
Keyword(s):  
Experimental Data ◽  
Quantum Chemistry ◽  
High Energy ◽  
Basis Set ◽  
Electronic Correlation ◽  
Exact Methods ◽  
Energy Parameters ◽  
Bond Functions ◽  
The Individual ◽  
Potential Curves

Geometry and energy parameters of the individual dissociation intermediate steps of CH4 molecule, parameters of the barrier to linearity and singlet-triplet separation of the CH2 molecule have been calculated by means of the UMP method in the minimum basis set augmented with the bond functions. The results agree well with experimental data except for the geometry of CH2(1A1) and relatively high energy values of CH(2II) and CH2(1A1) where the existence of two UHF solutions indicates a necessity of description of the electronic correlation by more exact methods of quantum chemistry.

scholarly journals An Additive Model to Predict the Rheological and Mechanical Properties of Polypropylene Blends Made by Virgin and Reprocessed Components

Recycling ◽  
2021 ◽  
Vol 6 (1) ◽  
pp. 2
Author(s):  
Francesco Paolo La Mantia ◽  
Maria Chiara Mistretta ◽  
Vincenzo Titone
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Additive Model ◽  
Industrial Process ◽  
Theoretical Predictions ◽  
Experimental Values ◽  
Polypropylene Blends ◽  
Polypropylene Sample

In this work, an additive model for the prediction of the rheological and mechanical properties of monopolymer blends made by virgin and reprocessed components is proposed. A polypropylene sample has been reprocessed more times in an extruder and monopolymer blends have been prepared by simulating an industrial process. The scraps are exposed to regrinding and are melt reprocessed before mixing with the virgin polymer. The reprocessed polymer is, then, subjected to some thermomechanical degradation. Rheological and mechanical experimental data have been compared with the theoretical predictions. The results obtained showed that the values of this simple additive model are a very good fit for the experimental values of both rheological and mechanical properties.

Stress Optical Behavior of Rubber Networks at Large Deformations

1966 ◽  
Vol 39 (5) ◽  
pp. 1436-1450
Author(s):  
K. J. Smith ◽  
D. Puett
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Statistical Theory ◽  
Natural Rubber ◽  
Large Deformations ◽  
Strong Support ◽  
Theoretical Development ◽  
Statistical Parameters ◽  
Strain Behavior ◽  
Optical Behavior

Abstract The birefringence of natural rubber networks at large deformations has been investigated experimentally and compared with the simultaneously determined stress—strain behavior. Our data is analyzed using a statistical theory of flexibly jointed chains, derived herein, which is believed to be more significant for the particular range of deformation used than the theories of Treloar and of Kuhn and Grün. In addition, the experimental data of Saunders is commented on in light of our theoretical development. We find that for network extensions exceeding those of the Gaussian region there is little correlation between the observed and theoretical behavior of the stress and birefringence (based upon the theory of flexibly jointed chains) and this lack of agreement is attributed to the fact that the statistical parameters needed for the description of the optical chain properties differ in magnitude from those required for the mechanical properties. Furthermore, by considering the points of incipient crystallization the strain behavior of the stress-optical coefficient is highly indicative of nonGaussian behavior rather than crystallization, and therefore yields strong support for the position that nonGaussian behavior does exist in rubber networks.

Mathematical Model of the Sintering Process of Iron-Copper Bearings

2007 ◽  
Vol 23 ◽  
pp. 119-122
Author(s):  
Cristina Teișanu ◽  
Stefan Gheorghe ◽  
Ion Ciupitu
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Mathematical Model ◽  
Regression Analysis ◽  
Function Optimization ◽  
Chemical Compositions ◽  
Sintering Process ◽  
Molybdenum Disulphide ◽  
Iron Copper ◽  
Antifriction Properties

The most important features of the self-lubricating bearings are the antifriction properties such as friction coefficient and wear resistence and some mechanical properties such as hardness, tensile strength and radial crushing strength. In order to improve these properties new antifriction materials based on iron-copper powders with several additional components (tin, lead and molybdenum disulphide) have been developed by PM techniques. To find the optimal relationship between chemical compositions, antifriction and mechanical properties, in this paper a mathematical model of the sintering process is developed, which highlighted the accordance of the model with data by regression analysis. For the statistical processing of the experimental data the VH5 hardness values of the studied materials were considered. The development of mathematical model includes the enunciation of the model, the establishment of the performance function (optimization) and the establishment of the model equations and verifying. The accordance of the model with experimental data has been highlighted by regression analysis

Tests on Mechanical Properties and Anti-Penetration Performance of Steel-Fiber Reactive Powder Concrete

2013 ◽  
Vol 671-674 ◽  
pp. 1761-1765
Author(s):  
Yong Liu ◽  
Chun Ming Song ◽  
Song Lin Yue
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Fracture Toughness ◽  
Compressive Strength ◽  
Reinforced Concrete ◽  
Steel Fiber ◽  
Reactive Powder Concrete ◽  
Calculation Results ◽  
Reactive Powder ◽  
Penetration Tests

In order to get mechanical properties ,some RPC samples with 5% steel fiber are tested, many groups data were obtained such as compressive strength, shear strength and fracture toughness. And a group of tests on RPC with 5% steel-fiber under penetration were also conducted to validate the performance to impact. The penetration tests are carried out by the semi-AP projectiles with the diameter of 57 mm and earth penetrators with the diameter of 80 mm, and velocities of the two kinds of projectiles are 300～600 m/s and 800～900 m/s, respectively. By contrast between the experimental data and the calculation results of C30 reinforced concrete by using experiential formula under penetration, it shows that the resistance of steel-fiber RPC to penetration is 3 times as that of general C30 reinforced concrete.

Morphology and Mechanical Properties of Poly(Lactic Acid) and Propylene-Ethylene Copolymer Blends: Effect of Organoclay Types

2017 ◽  
Vol 737 ◽  
pp. 269-274
Author(s):  
Sirirat Wacharawichanant ◽  
Chaninthon Ounyai ◽  
Ployvaree Rassamee
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Tensile Properties ◽  
Polymer Matrix ◽  
Poly Lactic Acid ◽  
Dispersed Phase ◽  
Copolymer Blends ◽  
Morphology Analysis ◽  
Ethylene Copolymer ◽  
Morphology And Mechanical Properties

The effects of four types of organoclay on morphology and mechanical properties of poly(lactic acid) (PLA)/propylene-ethylene copolymer (PEC) blends were investigated. The ratio of PLA and PEC was 80/20 by weight and the organoclay content was 5 phr. The morphology analysis showed that the addition of all oganocaly types could improve the miscibility of PLA and PEC blends due to the decreased of the domain sizes of PEC dispersed phase in the polymer matrix. The tensile properties showed Young’s modulus of the PLA/PEC blends was improved after adding clay treated surface with 25-30 wt% trimethyl stearyl ammonium.

A correlation to predict the performance characteristics of centrifugal pumps handling slurries

1997 ◽  
Vol 211 (2) ◽  
pp. 147-157 ◽  
Author(s):  
K A Kazim ◽  
B Maiti ◽  
P Chand
Keyword(s):  
Experimental Data ◽  
Particle Size ◽  
Suspended Solids ◽  
Reduction Factor ◽  
Performance Characteristics ◽  
Centrifugal Pumps ◽  
Pump Performance ◽  
New Correlation ◽  
Effect Of Particle Size ◽  
The Individual

Centrifugal pumps are being used increasingly for transportation of slurries through pipelines. To design a slurry handling system it is essential to have a knowledge of the effects of suspended solids on the pump performance. A new correlation to predict the head reduction factor for centrifugal pumps handling solids has been developed. This correlation takes into account the individual effect of particle size, particle size distribution, specific gravity and concentration of solids on the centrifugal pump performance characteristics. The range of validity of the correlation has been verified by experiment and by using experimental data available from the literature. The present correlation shows better agreement with the experimental data than existing correlations.

scholarly journals Fabrication and Characterization of Electrospun Polycaprolactone Blended with Chitosan-Gelatin Complex Nanofibrous Mats

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Yongfang Qian ◽  
Zhen Zhang ◽  
Laijiu Zheng ◽  
Ruoyuan Song ◽  
Yuping Zhao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Weight Ratio ◽  
Degree Of Crystallinity ◽  
X Ray Diffraction ◽  
Tissue Engineering Scaffolds ◽  
Elongation At Break ◽  
Nanofibrous Scaffolds ◽  
Two Peaks

Design and fabrication of nanofibrous scaffolds should mimic the native extracellular matrix. This study is aimed at investigating electrospinning of polycaprolactone (PCL) blended with chitosan-gelatin complex. The morphologies were observed from scanning electron microscope. As-spun blended mats had thinner fibers than pure PCL. X-ray diffraction was used to analyze the degree of crystallinity. The intensity at two peaks at 2θof 21° and 23.5° gradually decreased with the percentage of chitosan-gelatin complex increasing. Moreover, incorporation of the complex could obviously improve the hydrophilicity of as-spun blended mats. Mechanical properties of as-spun nanofibrous mats were also tested. The elongation at break of fibrous mats increased with the PCL content increasing and the ultimate tensile strength varied with different weight ratios. The as-spun mats had higher tensile strength when the weight ratio of PCL to CS-Gel was 75/25 compared to pure PCL. Both as-spun PCL scaffolds and PCL/CS-Gel scaffolds supported the proliferation of porcine iliac endothelial cells, and PCL/CS-Gel had better cell viability than pure PCL. Therefore, electrospun PCL/Chitosan-gelatin nanofibrous mats with weight ratio of 75/25 have better hydrophilicity mechanical properties, and cell proliferation and thus would be a promising candidate for tissue engineering scaffolds.

Quantitative Analysis of Pre-Strain Effect on Mechanical Properties of the Austenitic Stainless Steel

2014 ◽  
Author(s):  
Zhiwei Chen ◽  
Caifu Qian ◽  
Guoyi Yang ◽  
Xiang Li
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Tensile Strength ◽  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Yield Strength ◽  
Tensile Testing ◽  
Control Mode ◽  
Strain Effect ◽  
Strain Control

The test of austenitic stainless steel specimens with strain control mode of pre-strain was carried out. The range of pre-strain is 4%, 5%, 6%, 7%, 8%, 9% and 10% on austenitic stainless steel specimens, then tensile testing of these samples was done and their mechanical properties after pre-strain were gotten. The results show that the pre-strain has little effect on tensile strength, and enhances the yield strength more obviously. According to the experimental data, we get a relational expression of S30408 between the value of yield strength and pre-strain. We can obtain several expressions about different kinds of austenitic stainless steel by this way. It is convenient for designers to get the yield strength of austenitic stainless steel after pre-strain by the value of pre-strain and the above expression.

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