scholarly journals Synthetic approaches to coniine and other 2-alkyl piperidines

2013 ◽  
Vol 11 (1) ◽  
pp. 1-26 ◽  
Author(s):  
Marija Denic ◽  
Polina Blagojevic ◽  
Niko Radulovic

The first synthesis of coniine, a neurotoxic piperidine alkaloid found in poison hemlock (Conium maculatum L.), was performed back in 1886 by Ladenburg. Since that time, numerous different approaches to the synthesis of this and related alkaloids (2-alkylpiperidines) have been developed. Nowadays, the enantioselective/specific synthesis of coniine is taken as a paradigm of the usefulness of new chiral synthetic methodologies. This review aims to summarize and systematize recent progress in the synthesis of coniine and related compounds.

2020 ◽  
Vol 18 (6) ◽  
pp. 1046-1056 ◽  
Author(s):  
Weigang He ◽  
Pengyan Wang ◽  
Junhan Chen ◽  
Weiqing Xie

The recent synthetic approaches toward Strychnos alkaloids are summarized, including novel synthetic methodologies and strategies.


Synthesis ◽  
2021 ◽  
Author(s):  
Hee Nam Lim ◽  
Wan Pyo Hong ◽  
Inji Shin

AbstractThis short review summarizes the origins and recent progress in 1,4-azaborine research, focusing on synthetic methodologies. Academic laboratories have made significant efforts to generate boron-nitrogen-containing heteroaromatic compounds that mimic arenes. 1,2-, 1,3-, and 1,4-Azaborine motifs have provided breakthrough molecules in applications ranging from medicines to materials. Owing to recent advances in polyaromatic 1,4-azaborine synthesis and applications in industry, the research field is currently undergoing a renaissance. Photo- and electroluminescent properties driven by distinct structural variations are key components in the design of novel 1,4-azaborine structures. In this review, seminal reports on the synthesis of simple 1,4-azaborines to complex π-extended structures are briefly highlighted together along with key optoelectronic properties.1 Introduction2 Non-Fused 1,4-Azaborines3 Monobenzo-Fused 1,4-Azaborines4 Dibenzo-Fused 1,4-Azaborines and Their Derivatives5 Ladder-Type 1,4-Azaborines6 Complex 1,4-Azaborines7 Optoelectronic Properties of Key 1,4-Azaborines8 Conclusion and Outlook


2021 ◽  
Vol 9 ◽  
Author(s):  
Yue Cao ◽  
Jun-Jie Zhu

Halide perovskites are a rapidly developing class of solution-processable semiconductors which, to date, have a huge impact across several scientific communities. The remarkable photophysical attributes of halide perovskites illustrate their considerable potential in the electrochemiluminescence (ECL) realm. Over the past 4 years, great progress has been achieved in using halide perovskites as ECL emitters. In this mini-review, the basic characteristics, synthetic approaches, and ECL mechanisms for halide perovskite emitters are first introduced. To the best of our knowledge, most of the reported ECL-active halide perovskites and their disclosed unique features are detailly summarized. Stabilization and interface manipulation strategies for desirable ECL performance are further highlighted. The preliminary halide perovskites-related ECL applications are finally discussed, and prospects are also anticipated.


1985 ◽  
Vol 16 (31) ◽  
Author(s):  
S. TANIMOTO ◽  
H. TERAO ◽  
T. OIDA ◽  
H. IKEHIRA

2020 ◽  
Vol 26 (24) ◽  
pp. 2843-2858 ◽  
Author(s):  
Emília P.T. Leitão

This review summarizes the synthetic methodologies used in the last 25 years for the synthesis of chalcones, which are a class of flavonoids having a 1,3-diphenyl-2-propene-1-one backbone. These compounds are considered a hot topic in the field of medicinal chemistry, due to their pharmacological activity and because they are important precursors for the synthesis of heterocyclic compounds with therapeutic applications such as: flavones, flavanones, isoxazolines, benzothiazepines, pyrimidines and pyrazolines derivatives.


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4420
Author(s):  
Tse-Wei Chen ◽  
Palraj Kalimuthu ◽  
Ganesan Anushya ◽  
Shen-Ming Chen ◽  
Vinitha Mariyappan ◽  
...  

Presently, the global energy demand for increasing clean and green energy consumption lies in the development of low-cost, sustainable, economically viable and eco-friendly natured electrochemical conversion process, which is a significant advancement in different morphological types of advanced electrocatalysts to promote their electrocatalytic properties. Herein, we overviewed the recent advancements in oxygen evolution reactions (OERs), including easy electrode fabrication and significant action in water-splitting devices. To date, various synthetic approaches and modern characterization techniques have effectively been anticipated for upgraded OER activity. Moreover, the discussed electrode catalysts have emerged as the most hopeful constituents and received massive appreciation in OER with low overpotential and long-term cyclic stability. This review article broadly confers the recent progress research in OER, the general mechanistic approaches, challenges to enhance the catalytic performances and future directions for the scientific community.


2001 ◽  
Vol 194-199 ◽  
pp. 687-702 ◽  
Author(s):  
Nicolaas Stolwijk ◽  
G. Bösker ◽  
J. Pöpping

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