Numerical coupling strategy for the simulation of electromagnetic stirring

2017 ◽  
Vol 53 (3) ◽  
pp. 547-556
Keyword(s):  
Electromagnetic Stirring ◽  
Coupling Strategy

Numerical Simulation on Mold Electromagnetic Eccentric Stirring and Central Segregation of Round Bloom

2013 ◽  
Vol 652-654 ◽  
pp. 2450-2454
Author(s):  
Zhi Hong Zhang ◽  
Guo Guang Cheng
Keyword(s):  
Numerical Simulation ◽  
Mathematical Model ◽  
Electromagnetic Stirring ◽  
Center Line ◽  
Central Segregation

The paper describes multi-section round bloom casting using external MEMS, equipped with max section D600mm and min D280mm mold, the center line of D280mm mold not coincident with the axis of stirrer coils. it is exist eccentric electromagnetic stirring of mold which section less than max D600mm, a mathematical model of MEMS has been established, the index of central segregation of D280mm macrostructure had decreased less than 1.12 by optimized parameters of electromagnetic stirring and SEN immerse depth, in the end, the quality of round bloom had improved.

scholarly journals Microstructures and Macrosegregation of Al–Zn–Mg–Cu Alloy Billet Prepared by Uniform Direct Chill Casting

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 708
Author(s):  
Li Zhou ◽  
Yajun Luo ◽  
Zhenlin Zhang ◽  
Min He ◽  
Yinao Xu ◽  
...  
Keyword(s):  
Mold Wall ◽  
Direct Chill ◽  
Element Distribution ◽  
Direct Chill Casting ◽  
Electromagnetic Stirring ◽  
Alloying Elements ◽  
Alloying Element ◽  
Casting Method ◽  
Chill Casting ◽  
Cu Alloy

In this study, large-sized Al–Zn–Mg–Cu alloy billets were prepared by direct chill casting imposed with annular electromagnetic stirring and intercooling; a process named uniform direct chill casting. The effects of uniform direct chill casting on grain size and the alloying element distribution of the billets were investigated and compared with those of the normal direct chill casting method. The results show that the microstructures were refined and the homogeneity of the alloying elements distribution was greatly improved by imposing the annular electromagnetic stirring and intercooling. In uniform direct chill casting, explosive nucleation can be triggered, originating from the mold wall and dendrite fragments for grain refinement. The effects of electromagnetic stirring on macrosegregation are discussed with consideration of the centrifugal force that drives the movement of melt from the central part towards the upper-periphery part, which could suppress the macrosegregation of alloying elements. The refined grain can reduce the permeability of the melt in the mushy zone that can restrain macrosegregation.

scholarly journals Practical iridium-catalyzed direct α-arylation of N-heteroarenes with (hetero)arylboronic acids by H2O-mediated H2 evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Liang Cao ◽  
He Zhao ◽  
Rongqing Guan ◽  
Huanfeng Jiang ◽  
Pierre. H. Dixneuf ◽  
...  
Keyword(s):  
Structural Modification ◽  
Universal Access ◽  
Boronic Acids ◽  
Direct Access ◽  
Bidentate Ligands ◽  
H2 Evolution ◽  
Arylboronic Acids ◽  
Coupling Strategy ◽  
General Method ◽  
Operational Simplicity

AbstractDespite the widespread applications of 2-(hetero)aryl N-heteroarenes in numerous fields of science and technology, universal access to such compounds is hampered due to the lack of a general method for their synthesis. Herein, by a H2O-mediated H2-evolution cross-coupling strategy, we report an iridium(III)-catalyzed facile method to direct α-arylation of N-heteroarenes with both aryl and heteroaryl boronic acids, proceeding with broad substrate scope and excellent functional compatibility, oxidant and reductant-free conditions, operational simplicity, easy scalability, and no need for prefunctionalization of N-heteroarenes. This method is applicable for structural modification of biomedical molecules, and offers a practical route for direct access to 2-(hetero)aryl N-heteroarenes, a class of potential cyclometalated C^N ligands and N^N bidentate ligands that are difficult to prepare with the existing α-C-H arylation methods, thus filling an important gap in the capabilities of synthetic organic chemistry.

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