Properties and Applications of Bulk High Temperature Superconductors. Possibility of a High-Tc Superconducting Bulk Magnet for Maglev Trains in the Future.

Author(s):  
Hiroyuki FUJIMOTO
MRS Bulletin ◽  
1990 ◽  
Vol 15 (6) ◽  
pp. 60-67 ◽  
Author(s):  
M. Brian Maple

Since the discovery of high temperature superconductivity in layered copper-oxide compounds in the latter part of 1986, an enormous amount of research has been carried out on these remarkable materials. Prior to 1989, the prevailing view was that the charge carriers responsible for superconductivity in these materials were holes that move through conducting CuO2 planes. The CuO2 planes are the basic building blocks of the crystal structures of all the presently known oxides with superconducting critical temperatures Tc greater than ~30 K. Recently, new superconducting materials have been discovered in Japan and the United States in which the charge carriers involved in the superconductivity appear to be electrons, rather than holes, that reside within the conducting CuO2 planes. These findings could have important implications regarding viable theories of high temperature superconductivity as well as strategies for finding new high temperature superconductors.The new electron-doped materials have the chemical formula Ln2-xMxCuO4-y and exhibit superconductivity with superconducting critical temperatures Tc as high as ~25 K for x ≍ 0.15 and y ≍ 0.02. Superconductivity has been discovered for M = Ce and Ln = Pr, Nd, Sm, and Eu, and for M = Th and Ln = Pr, Nd, and Sm. A related compound with the identical crystal structure, Nd2CuO4-x-y Fx, has also been found to display superconductivity withTc ≍ 25 K. Recently, it has been observed that superconductivity with Tc ≍ 25 K can even be induced in nonsuperconducting Nd2-xCexCuO4-y compounds by substituting Ga or In for Cu. Thus, it appears that the CuO2 planes can be doped with electrons, rendering the Ln2CuO4-y parent compounds metallic and superconducting, by substituting electron donor elements at sites within, as well as outside, the CuO2 planes; i.e., by substituting (1) Ce4+ or Th4+ ions for Ln3+ ions; (2) F1- ions for O2- ions; and (3) Ga3+ or In3+ ions for Cu2+ ions.


1995 ◽  
Vol 09 (21) ◽  
pp. 2811-2820
Author(s):  
VALERY A. CHERENKOV

The multilayered (N-S(D)-N)-types structures have been observed: there are the traditional Niobium low-temperature superconductors and new high-temperature superconductors. The main attention had been directed to the anisotropy, defectively and the stimulation of the superconductivity in the multilayered structures.


2003 ◽  
Vol 17 (13) ◽  
pp. 2609-2622 ◽  
Author(s):  
N. Charoenthai ◽  
P. Winotai ◽  
R. Suryanarayanan ◽  
I. M. Tang

We report here on the structural and superconducting properties of RE 1 - 2x Pr x Ca x Sr 0.8 Ba 1.2 Cu 3 O 7 - δ (RE = Er and Gd, 0 ≤ x ≤ 0.2) high temperature superconductors. The transition temperature (Tc) of these compounds decreases when the Pr and Ca concentrations are increased. At constant Pr and Ca concentrations, the Tc of Er 1 - 2x Pr x Ca x Sr 0.8 Ba 1.2 Cu 3 O 7 - δ superconductor system is higher than that observed for the Gd 1 - 2x Pr x Ca x Sr 0.8 Ba 1.2 Cu 3 O 7 - δ system. For the Gd 0.8 Pr 0.1 Ca 0.1 Sr 0.8 Ba 1.2 Cu 3 O 7 - δ sample, after heating in argon followed by oxygen annealing, the orthorhombicity increases accompanied by 10 K increase in Tc. These results show that though our data indicate an ion-size effect, the Tc suppression rate dTc/dx depends very much on the heat treatment adopted to prepare the samples.


2005 ◽  
Vol 19 (01n03) ◽  
pp. 193-197
Author(s):  
L. KRUSIN-ELBAUM ◽  
T. SHIBAUCHI ◽  
G. BLATTER

Recent Nernst and interlayer transport experiments in Bi 2 Sr 2 CaCu 2 O 8+y (BSCCO) high temperature superconductors report hugely different limiting magnetic fields. We demonstrate that both fields convert to the same pseudogap energy scale T* upon transformation as orbital and Zeeman critical fields, respectively. We suggest a consistent interpretation of this finding based on separation of spin and charge degrees of freedom residing in different regions of a truncated Fermi surface.


2017 ◽  
Vol 30 (7) ◽  
pp. 075002 ◽  
Author(s):  
S Calatroni ◽  
E Bellingeri ◽  
C Ferdeghini ◽  
M Putti ◽  
R Vaglio ◽  
...  

1988 ◽  
Vol 02 (06) ◽  
pp. 1331-1379 ◽  
Author(s):  
B. N. GOSHCHITSKII ◽  
V. L. KOZHEVNIKOV ◽  
M. V. SADOVSKII

This review reports the main experimental results on superconducting lattice and electron properties of high-temperature superconductors of the type La 2−x Sr x CuO 4 and YBa 2 Cu 3 O 7 obtained at three institutes of the Ural Branch of the USSR Academy of Sciences in Sverdlovsk. Special attention is paid to investigations of structural phase transitions, heat capacity, optic and magnetic properties, NMR relaxation and the role of radiation disordering under the influence of fast neutron irradiation. In conclusion, a brief review of possible theories to explain high-temperature superconductivity in metal oxides is given.


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