scholarly journals Cobalt Doping on Zirconium Titanate as a Potential Photocatalyst with Visible-Light-Response

2020 ◽  
Vol 20 (4) ◽  
pp. 911
Author(s):  
Emilya Faridatul Sulaikhah ◽  
Rian Kurniawan ◽  
Mokhammad Fajar Pradipta ◽  
Wega Trisunaryanti ◽  
Akhmad Syoufian
Keyword(s):  
Visible Light ◽  
Sol Gel ◽  
Diffraction Method ◽  
Light Response ◽  
Zirconium Titanate ◽  
Titanium Tetraisopropoxide ◽  
X Ray ◽  
Visible Light Response ◽  
Vis Spectroscopy ◽  
Co Doped

Synthesis of cobalt-doped zirconium titanate (Co-doped ZrTiO4) as a potential photocatalyst with visible-light-response had been conducted. Materials used in this research were titanium tetraisopropoxide (TTIP) as a precursor of TiO2, ZrO2 as another semiconductor for coupling, and CoSO4·7H2O as the source of cobalt dopant. The composite was prepared by the sol-gel method with various cobalt contents and calcination temperatures. Composites with various Co dopant contents (0, 1, 3, 5, 7, and 9% (Co wt./Ti wt.)) were calcined at 500 °C for 4 h. In addition, the composite with 5% of dopant content was calcined at 700 and 900 °C to observe the influence of calcination temperature. All samples were characterized by using X-ray powder diffraction method (XRD), Fourier-transform infrared spectroscopy (FTIR), specular reflectance UV-Vis spectroscopy (SRUV), and scanning electron microscopy equipped with X-ray energy dispersive spectroscopy (SEM-EDS). Co-doped ZrTiO4 with the lowest bandgap (2.94 eV) was achieved in a sample containing 3% of cobalt content calcined at 500 °C.

N, Fe Co-Doped TiO2 Photocatalyst Preparation by Sol-Gel Method with Visible Light Response

2013 ◽  
Vol 726-731 ◽  
pp. 673-676 ◽  
Author(s):  
Ping Yu ◽  
Shan Shan Wang ◽  
Huan Huan Li ◽  
Wen Xiu Li
Keyword(s):  
Sol Gel ◽  
Light Response ◽  
X Ray Diffraction ◽  
Visible Spectroscopy ◽  
Gel Method ◽  
X Ray ◽  
Sol Gel Method ◽  
Visible Light Response ◽  
Ft Ir ◽  
Co Doped

N, Fe co-doped TiO2 photocatalyst was synthesized by sol-gel method. The catalyst prepared was characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Ultraviolet and visible spectroscopy (UV-vis). The results showed that the N, Fe co-doped TiO2 prepared had the anatase structure. The absorption edge of the photocatalyst shifted to longer wavelength and photocatalytic activity for degradation of Methylene blue (MB) under Xe-lamp (350 W) was much more active than un-doped TiO2, N-TiO2 Fe-TiO2 and P-25.

Ni-Bi co-doped TiO2 as highly visible light response nano-photocatalyst for CO2 photo-reduction in a batch photo-reactor

2020 ◽  
Vol 41 ◽  
pp. 101289
Author(s):  
Reza Nematollahi ◽  
Cyrus Ghotbi ◽  
Farhad Khorasheh ◽  
Afsanehsadat Larimi
Keyword(s):  
Visible Light ◽  
Light Response ◽  
Doped Tio2 ◽  
Visible Light Response ◽  
Co Doped

Preparation of C, N and P co-doped TiO2 and its photocatalytic activity under visible light

2019 ◽  
Vol 12 (04) ◽  
pp. 1950045 ◽  
Author(s):  
Lin Zhao ◽  
Yanzhao Xie ◽  
Qiuyu Lin ◽  
Rongze Zheng ◽  
Yong Diao
Keyword(s):  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Sol Gel ◽  
Soluble Starch ◽  
Doping Amount ◽  
X Ray ◽  
Composite Catalysts ◽  
One Step ◽  
Co Doped

A series of composite catalysts of C, N and P co-doped TiO2 were prepared by sol-gel method, using a biomass (soluble starch) dopant. The samples were characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (DRS), fourier transform infrared (FTIR) spectroscopy. The results show that TiO2 is co-doped with C, N and P by one step. The resulting composite exhibited higher specific surface area, wider visible-light absorption band with respect to the pure TiO2. The sample calcined at 400∘C for 2[Formula: see text]h with a doping amount of 6[Formula: see text]g soluble starch showed the best electrochemical performance. The C, N and P co-doped TiO2 was also used for the degradation of methylene blue (MB) and degradation ratio was up to 98% in 80[Formula: see text]min under visible light irradiation.

One-Pot Hydrothermal Synthesis of Sulfur-Doped SnO2 Nanoparticles and their Enhanced Photocatalytic Properties

NANO ◽  
2016 ◽  
Vol 11 (03) ◽  
pp. 1650035 ◽  
Author(s):  
Lin Ma ◽  
Limei Xu ◽  
Xuyao Xu ◽  
Xiaoping Zhou ◽  
Lingling Zhang
Keyword(s):  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Electrochemical Impedance ◽  
Sno2 Nanoparticles ◽  
Light Response ◽  
One Pot ◽  
X Ray ◽  
Transmission Electron ◽  
Light Region ◽  
Vis Spectroscopy

Sulfur-doped SnO2 nanoparticles with ultrafine sizes have been successfully prepared by a one-pot hydrothermal method. The obtained samples are characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (HRTEM), thermogravimetric (TG), analyzer UV-Vis spectroscopy, photoluminescence (PL) and electrochemical impedance spectroscopy (EIS). The experimental results indicate that the doping level of sulfur element as well as the bandgaps of SnO2 can be controlled to a certain extent by varying the amount of L-cysteine (L-cys). When evaluated as photocatalysts in the degradation of rhodamine B (RhB) and reduction of Cr(VI) under visible light region, the resultant sulfur-doped SnO2 nanoparticles demonstrate obviously enhanced photocatalytic activities due to the markedly improved visible light response and effective separation of the photo-generated electron–hole pairs.

A facile approach to synthesize N and B co-doped TiO2 nanomaterials with superior visible-light response

2010 ◽  
Vol 64 (15) ◽  
pp. 1728-1731 ◽  
Author(s):  
Guosheng Wu ◽  
Jiali Wen ◽  
Jingpeng Wang ◽  
Dan F. Thomas ◽  
Aicheng Chen
Keyword(s):  
Visible Light ◽  
Light Response ◽  
Doped Tio2 ◽  
Visible Light Response ◽  
Tio2 Nanomaterials ◽  
Co Doped

Preparation and Photocatalytic Properties of La, Ce and Nonmetal N Co-Doped TiO2

2016 ◽  
Vol 680 ◽  
pp. 193-197
Author(s):  
San Ti Yi ◽  
Si Qin Zhao
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Uv Light ◽  
Sol Gel ◽  
Light Response ◽  
Gel Method ◽  
X Ray ◽  
Sol Gel Method ◽  
Co Doped

TiO2, 1%La/TiO2, 1%Ce/TiO2 and a series of Laand Ce co-doped TiO2 photocatalysts were prepared by sol-gel method. Using sol-gel method combine with hydrothermal method prepared rare earth La, Ce and nitrogen co-doped TiO2 photocatalysts. The microstructure, spectroscopy performance and ion doped form of prepared samples were characterized by X-ray powder diffraction (XRD), UV-Vis diffuse reflectance spectroscopy techniques and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of doped TiO2 were examined by measuring the photodegradation of methyl orange. The results showed that the products were all anatase TiO2 nano powder, doping Laor Cehinder the growth of TiO2 particle, further more, doping Laand Cetogether hinder the growth of TiO2 particle more effective, doping N broaden the light response range of TiO2 photocatalyst. At the same time, the photocatalytic activity results indicated that the prepared samples showed superior UV light photocatalytic activity, the sample 1% (La:Ce,9:1)-N/TiO2 showed the highest UV-vis photocatalytic activity.

Metal ion and N co-doped TiO2 as a visible-light photocatalyst

2004 ◽  
Vol 19 (7) ◽  
pp. 2100-2108 ◽  
Author(s):  
Yoshiaki Sakatani ◽  
Hiroyuki Ando ◽  
Kensen Okusako ◽  
Hironobu Koike ◽  
Jun Nunoshige ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Metal Ion ◽  
Light Response ◽  
Complex Method ◽  
Visible Light Photocatalyst ◽  
X Ray ◽  
Visible Light Response ◽  
Spin Resonance ◽  
Photocatalytic Activities

Powders of TiO2 doped with a metal ion and N species were prepared by a polymerized complex method and the visible-light photocatalytic activities of the products are investigated. Of the metal ions studied (K+, Ca2+, Sr2+, Ba2+, Nb5+, Fe3+, Zn2+, and Al3+), the photocatalyst prepared with Sr2+ exhibits the highest activity for acetaldehyde decomposition under visible-light irradiation. Results obtained from x-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) analyses suggest that the doped N species reside at interstitial lattice positions in the catalyst. It was also found by XPS and ESR measurements that the doped N species combine with lattice oxygen to give rise to a paramagnetic property. The visible-light response of the catalyst is driven by the formation of paramagnetic N species at interstitial positions in the TiO2 lattice.

Preparation, Characterization, and Photocatalytic Property of N-La Co-Doped TiO2 with Visible Light Response

2012 ◽  
Vol 529 ◽  
pp. 537-540 ◽  
Author(s):  
Gui Hua Li ◽  
An Feng Wang
Keyword(s):  
Visible Light ◽  
Reaction Temperature ◽  
Catalyst Activity ◽  
Sol Gel ◽  
Photocatalytic Property ◽  
Light Response ◽  
Catalyst Amount ◽  
Doped Tio2 ◽  
Sol Gel Process ◽  
Co Doped

N-La co-doped TiO2 has been synthesized via sol-gel process. The XRD result showed that the structure of N-La co-doped TiO2 was anatase. Their performance of photocatalytic degradation of methylene blue under visible light were investigated. The combined effects of catalyst compsition, calcination temperature, catalyst amount and reaction temperature on catalyst activity were investigated. Experiment results depicted that activeness of catalyst N2.5La0.5/TiO2 calcinated at 500°C for 2h was highest. Using this catalyst, when the catalyst amount was 0.35 g/L, the reaction temperature was 40°C the degradation rate of mehylene blue in 4h could reach 96.5%.

scholarly journals Photocatalytic performance of Ag2S/ZnO/ZnS nanocomposites with high visible light response prepared via microwave-assisted hydrothermal two-step method

2018 ◽  
Vol 78 (8) ◽  
pp. 1802-1811 ◽  
Author(s):  
Jiwei Huang ◽  
Changlong Yang ◽  
Qiang Song ◽  
Dongxue Liu ◽  
Li Li
Keyword(s):  
Electron Microscopy ◽  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Light Response ◽  
Light Sources ◽  
Step Method ◽  
X Ray ◽  
Microwave Assisted ◽  
Visible Light Response

Abstract A series of different ratios of Ag2S/ZnO/ZnS nanocomposites with visible light response were prepared by a microwave-assisted hydrothermal two-step method, whose composition, crystalline structure, morphology and surface physicochemical properties were well-characterized via X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV–vis diffuse reflectance spectroscopy (UV–vis/DRS), photoluminescence spectrum (PL), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM) and N2 adsorption–desorption measurements. Results showed that as-composites mainly consisted of ZnS crystal phase, whose grain size increased obviously compared with non Ag2S samples. At the same time, due to the introduction of narrow band gap Ag2S, the synthesized composite can effectively increase the visible optical absorption of ZnO/ZnS composites. Among them, 1% Ag2S/ZnO/ZnS showed a mixed structure of nano-line and nano-particle, of which BET value increased significantly, and the morphology was more excellent. Photocatalytic activities of a series of Ag2S/ZnO/ZnS composites under different light sources were studied using methyl orange as a model molecule, and 1% Ag2S/ZnO/ZnS was taken as the best one. Meanwhile, 1% Ag2S/ZnO/ZnS also showed a good degradation effect on other dyes with different structures, and its degradation efficiency did not change significantly after three cycles, showing certain stability. In addition, composites with Ag2S loading of 1% possessed the highest hydrogen production ability of photolysis water, indicating that the introduction of Ag2S had significantly enhanced the catalytic performance.

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