scholarly journals PRELIMINARY STUDY OF THE UTILIZATION OF THE FLY ASH FROM COAL-FIRED POWER PLANT FOR IMMOBILIZATION OF RADIOACTIVE WASTE

2011 ◽  
Vol 11 (3) ◽  
pp. 258-266 ◽  
Author(s):  
Herry Poernomo

Preliminary study of the utilization of the fly ash from coal-fired power plant for immobilizing simulated radioactive waste has been done. The objective of this research was to study characteristics of pozzolanic material of the fly ash from coal-fired power plant as substitute of compactor material for immobilizing simulated radioactive waste. The experiment was carried out by mixing of the compactor materials such as (cement + lime), (cement + fly ash), (cement + fly ash + lime), (fly ash + lime) with Na2SO4 225 g/L and KCl 4.6 g/L as simulation of evaporator concentrate according to reference waste form no. 1 on characterization of low and medium-level radioactive waste forms in the EUR 9423-EN. Each mixture of compactor materials solidified for 14 days, 21 days, and 28 days. Solidified result was monolith, and then its compressive strength, water absorption, and porosity were tested. The experiment result showed that the best of the compactor materials on the immobilizing simulated radioactive waste was cement of 30% (wt), fly ash of 20% (wt), and lime of 20% (wt) with compressive strength of monolith of 1512.7 N/cm2. The condenser substance on the weight ratio of fly ash/lime of 20/50 - 60/10 % (wt) as pozzolanic substance could be used for immobilizing simulated radioactive waste by compressive strength of monoliths of 345 - 610.4 N/cm2. Minimum compressive strength of monolith from radioactive waste cementation according to IAEA is 320 N/cm2, hence compressive strength of monoliths from this experiment can be expressed enough well.

2009 ◽  
Vol 620-622 ◽  
pp. 221-224
Author(s):  
Woo Teck Kwon ◽  
Byung Ik Kim ◽  
Y. Kim ◽  
Soo Ryong Kim ◽  
Sang Wook Ha

In this work, the physical & chemical properties of bottom ash generated from power plant are analyzed. Characteristic mortar property and thermal conductivity for building material were investigated with content of added bottom ash. According to the analytic result of bottom ash, chemical compositions of bottom ash is similar to those of fly ash and compressive strength after 7days related to pozzolanic activity shows 2.5N/cm2 and it is confirmed that bottom ash possess a certain amount of moisture activity. Although the fluidity of cement mortar is rapidly decreased with increasing addition of bottom ash, compressive strength for 3 and 7days is increased. The thermal conductivity is not sensitive to the addition of bottom ash.


2015 ◽  
Vol 804 ◽  
pp. 129-132
Author(s):  
Sumrerng Rukzon ◽  
Prinya Chindaprasirt

This research studies the potential for using waste ash from industrial and agricultural by-products as a pozzolanic material. Classified fly ash (FA) and ground rice husk ash (RA) were the materials used. Water requirement, compressive strength and porosity of cement mortar were investigated. Test results indicated that FA and RA (waste ash) have a high potential to be used as a good pozzolanic material. The water requirement of mortar mix decreases with the increases in fly ash content. For ground rice husk ash (RA), the water requirement of mortar mix increases with the increases in rice husk ash content. In addition, the reduction in porosity was associated with the increase in compressive strength.


2019 ◽  
Vol 2 (1) ◽  
pp. 50
Author(s):  
Andrie Harmaji ◽  
Claudia Claudia ◽  
Lia Asri ◽  
Bambang Sunendar ◽  
Ahmad Nuruddin

Abstract:. Suralaya power plant produces fly ash about 219.000 ton per year. Fly ash contents of silica and alumina as major components that can be used as precursors for geopolymer, a three dimensional networks aluminosilicate polymers. This research aim is to utilize fly ash for geopolymer made by mixing fly ash, fine aggregate, and alkali activator in a cubic mould and curing was carried out at room temperature for 7 and 28 days. After 28 days of curing the compressive strength of geopolymer reached 41.70 MPa. XRD characterization shows Albite (NaAlSi3O8) formation which has similarity to geopolymer compound. Fourier Transform Infra Red spectra show siloxo and sialate bond. These are typical functional groups that are found in geopolymer materials.Keyword: geopolymer, fly ash, aluminosilicate, alkali activator, albite, siloxo, sialateAbstrak: Pembangkit Listrik Tenaga Uap (PLTU) Suralaya menghasilkan fly ash (abu terbang) sekitar 219.000 ton per tahun. Fly ash memiliki silika dan alumina sebagai komponen utama yang dapat digunakan sebagai prekursor untuk geopolimer, suatu material polimer aluminosilikat tiga dimensi. Penelitian ini bertujuan untuk memanfaatkan fly ash untuk geopolimer yang dibuat dengan mencampur fly ash, agregat halus, dan aktivator alkali dalam cetakan kubik dan pengawetan dilakukan pada suhu kamar selama 7 dan 28 hari. Setelah 28 hari curing kekuatan tekan geopolimer mencapai 41,70 MPa. Karakterisasi XRD menunjukkan pembentukan Albite (NaAlSi3O8) yang memiliki kemiripan dengan senyawa geopolimer. Hasil spektroskopi Fourier Transform Infra Red (FTIR) menunjukkan ikatan siloxo dan sialate yang merupakan gugus fungsional khas yang ditemukan dalam geopolimer.Kata Kunci: geopolimer, abu terbang, aluminosilikat, alkali aktivator, albite, siloxo, sialate


2019 ◽  
Vol 2 (2) ◽  
pp. 65
Author(s):  
Purwanto P. ◽  
Himawan Indarto

Portland cement production process which is the conventional concrete constituent materials always has an impact on producing carbon dioxide (CO2) which will damage the environment. To maintain the continuity of development, while maintaining the environment, Portland cement substitution can be made with more environmentally friendly materials, namely fly ash. The substitution of fly ash material in concrete is known as geopolymer concrete. Fly ash is one of the industrial waste materials that can be used as geopolymer material. Fly ash is mineral residue in fine grains produced from coal combustion which is mashed at power plant power plant [15]. Many cement factories have used fly ash as mixture in cement, namely Portland Pozzolan Cement. Because fly ash contains SiO2, Al2O3, P2O3, and Fe2O3 which are quite high, so fly ash is considered capable of replacing cement completely.This study aims to obtain geopolymer concrete which has the best workability so that it is easy to work on (Workable Geopolymer Concrete / Self Compacting Geopolymer Concrete) and obtain the basic characteristics of geopolymer concrete material in the form of good workability and compressive strength. In this study, geopolymer concrete is composed of coarse aggregate, fine aggregate, fly ash type F, and activators in the form of NaOH and Na2SiO3 Be52. In making geopolymer concrete, additional ingredients such as superplastizer are added to increase the workability of geopolymer concrete. From this research, the results of concrete compressive strength above fc' 25 MPa and horizontal slump values reached 60 to 80 centimeters.


2019 ◽  
Vol 958 ◽  
pp. 111-115
Author(s):  
V.A.S. Schein ◽  
G. Conte ◽  
Marilena Valadares Folgueras ◽  
L.V.O. Dalla Valentina ◽  
M.R. Medeiros

This paper discusses an environmentally-friendly destination for the residual ashes resulting from the firing of biomass (wood wastes) at the Engie Brasil Cogeneration Power Plant located in Lages, Santa Catarina, Brazil. The study proposes reusing the residue as a substitution for crushed stones in the production of concrete. Environmental, physical, and chemical analyses were performed for characterization of the ashes. Specimens prepared with ash and subjected to testing presented a compressive strength of around 18.63 Mpa (2700 psi), which is in compliance with the ACI-213R and ASTM C330-5 specifications. With pretreatment and proper mixing ratios, biomass ashes may be employed as an aggregate in the manufacture of lightweight structural concrete.


2018 ◽  
Vol 195 ◽  
pp. 01023 ◽  
Author(s):  
Ari Widayanti ◽  
Ria Asih Aryani Soemitro ◽  
Hitapriya Suprayitno ◽  
Januarti Jaya Ekaputri

Fly ash is a by-product obtained from coal combustion process. Some of the utilization of fly ash is to produce geopolymer products which have high compressive strength, fire, chemical resistance. This paper proposes fly ash from unit 1-7 Suralaya Power Plant Indonesia. The aims of this study are to obtain characterization of fly ash and mechanical properties of geopolymer paste based on variations of the alkali activator ratio. The method was based on previous research and laboratory investigation. XRF and compressive strength were analysed in this study. Alkali activator was obtained from NaOH and Na2SiO3 mixture. The ratio of Na2SiO3 to NaOH was in the range of 0.5-2.5. Geopolymer paste was casted in acrylic cylinders with a diameter of 2 cm and a height of 4 cm. The curing was conducted at room temperature until the day for the compressive strength test at 28 days. The result showed that the fly ash is classified as F class. Increasing the alkali activator ratio influenced the strength. The best composition of geopolymer paste is made with NaOH 8M, and the mass ratio of Na2SiO3 to NaOH is 2.5. This composition produced compressive strength of 98.6 MPa.


2010 ◽  
Vol 5 (3) ◽  
pp. 302-308
Author(s):  
Herry Poernomo ◽  
Noor Anis Kundari ◽  
Burhani J W

An investigation of the contribution of fly ash in the fly ash-zeolite mixture as the backfill material on the shallow land burial of radioactive waste has been done. The experiment objective is to know the effect of zeolite particle size and fly ash-zeolite weight ratio on physical properties such as permeability (K) and dispersion characteristic such as effective dispersion coefficient (De) in the fly ash-zeolite form as backfill material. The experiment was carried out by the fixed bed method in the column filled by the fly ash-zeolite mixture with a fly ash-to-zeolite weight percent ratio of 100/0, 80/20, 60/40, 40/60, 20/80, 0/100 in the water saturated condition flown by uranyl nitrate solution at concentration (Co) of 500 ppm. The concentration of uranium in the effluents in interval 15 minutes represented as Ct was analyzed by spectrophotometer, then using Co and Ct, data effective dispersion coefficient (De) in the backfill material were determined. The experiment data showed that -400 mesh fly ash and -70+80 mesh zeolite on fly ash-to-zeolite with weight percent ratio of 40/60 with K = 5.00x10-5cm/second and De = 1.11.10-5 cm2/second can be used as backfill material. Keywords: backfill material, fly ash, radioactive waste, zeolite


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6890
Author(s):  
Muhammad Ibraheem ◽  
Faheem Butt ◽  
Rana Muhammad Waqas ◽  
Khadim Hussain ◽  
Rana Faisal Tufail ◽  
...  

The purpose of this research is to study the effects of quarry rock dust (QRD) and steel fibers (SF) inclusion on the fresh, mechanical, and microstructural properties of fly ash (FA) and ground granulated blast furnace slag (SG)-based geopolymer concrete (GPC) exposed to elevated temperatures. Such types of ternary mixes were prepared by blending waste materials from different industries, including QRD, SG, and FA, with alkaline activator solutions. The multiphysical models show that the inclusion of steel fibers and binders can enhance the mechanical properties of GPC. In this study, a total of 18 different mix proportions were designed with different proportions of QRD (0%, 5%, 10%, 15%, and 20%) and steel fibers (0.75% and 1.5%). The slag was replaced by different proportions of QRD in fly ash, and SG-based GPC mixes to study the effect of QRD incorporation. The mechanical properties of specimens, i.e., compressive strength, splitting tensile strength, and flexural strength, were determined by testing cubes, cylinders, and prisms, respectively, at different ages (7, 28, and 56 days). The specimens were also heated up to 800 °C to evaluate the resistance of specimens to elevated temperature in terms of residual compressive strength and weight loss. The test results showed that the mechanical strength of GPC mixes (without steel fibers) increased by 6–11%, with an increase in QRD content up to 15% at the age of 28 days. In contrast, more than 15% of QRD contents resulted in decreasing the mechanical strength properties. Incorporating steel fibers in a fraction of 0.75% by volume increased the compressive, tensile, and flexural strength of GPC mixes by 15%, 23%, and 34%, respectively. However, further addition of steel fibers at 1.5% by volume lowered the mechanical strength properties. The optimal mixture of QRD incorporated FA-SG-based GPC (QFS-GPC) was observed with 15% QRD and 0.75% steel fibers contents considering the performance in workability and mechanical properties. The results also showed that under elevated temperatures up to 800 °C, the weight loss of QFS-GPC specimens persistently increased with a consistent decrease in the residual compressive strength for increasing QRD content and temperature. Furthermore, the microstructure characterization of QRD blended GPC mixes were also carried out by performing scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS).


2018 ◽  
Vol 30 (5) ◽  
pp. 993-997
Author(s):  
Y. Prawiyanto ◽  
A. Shofiyani ◽  
T.A. Zaharah

Sign in / Sign up

Export Citation Format

Share Document