scholarly journals EXPERIMENTAL RESEARCH OF CORROSION INITIATION CHLORIDE ION CONCENTRATION OF STAINLESS STEEL REINFORCING BAR IN CONCRETE

2009 ◽  
Vol 65 (4) ◽  
pp. 522-529
Author(s):  
Yutaka TADOKORO ◽  
Yui TSUKUDA ◽  
Toru YAMAJI ◽  
Tsuyoshi MARUYA ◽  
Junichiro NIWA
Keyword(s):  
Stainless Steel ◽  
Experimental Research ◽  
Chloride Ion ◽  
Ion Concentration ◽  
Reinforcing Bar ◽  
Corrosion Initiation

An Electrochemical Study Of Pitting Corrosion in Stainless Steels (Part 1—Pit Growth)

CORROSION ◽  
1959 ◽  
Vol 15 (1) ◽  
pp. 48-54 ◽  
Author(s):  
N. D. GREENE ◽  
M. G. FONTANA
Keyword(s):  
Stainless Steel ◽  
Pitting Corrosion ◽  
Stainless Steels ◽  
Chloride Ion ◽  
Corrosion Current ◽  
Ion Concentration ◽  
Solution Composition ◽  
Current Interruption ◽  
Percent Nickel ◽  
First Time

Abstract By means of a unique artificial pit specimen, pit growth on 18 percent chromium-8 percent nickel stainless steel has been measured and characterized. The effects of solution composition, agitation, atmosphere, corrosion current interruption, chloride ion concentration, and inhibitor additions have been investigated. Pit interaction during pit growth has also been determined. The autocatalytic nature of pitting has been verified, and evidence of ion screening at pit sites has been experimentally observed for the first time. 3.2.2

Influence of Chloride for SCC Susceptibility on 15Cr Stainless Steel at High Temperatures under CO2 Environment

2017 ◽  
Vol 741 ◽  
pp. 42-49
Author(s):  
Toshiyuki Sunaba ◽  
Susumu Hirano ◽  
Tadao Ishihara
Keyword(s):  
Stainless Steel ◽  
High Temperature ◽  
Stainless Steels ◽  
Anodic Polarization ◽  
Cathodic Polarization ◽  
Martensitic Stainless Steel ◽  
Chloride Ion ◽  
The Other ◽  
Ion Concentration ◽  
Martensitic Stainless Steels

The effects of chloride ion concentration on SCC susceptibility of 15Cr and 13Cr martensitic stainless steels were investigated at 180°C by SSRT. Transgranular SCC occurred in the environment containing CO2 and chloride ion. The increasing chloride ion concentration was significantly affected SCC susceptibility of 15Cr SS. In addition, the contribution of hydrogen to SCC was examined at high temperature by SSRT with electrochemically polarization. The cathodically charged specimens showed hydrogen embrittlement. The fracture surface was similar to that of high temperature SCC. On the other hand, the SCC was accelerated by anodic polarization and not by cathodic polarization. The SCC behavior of martensitic stainless steel at high temperature is affect by evolved hydrogen atom. It is concluded that hydrogen plays a key role in the crack propagation.

A Model to Predict Stress Corrosion Cracking of Welded Stainless Steel Canister

MRS Advances ◽  
2016 ◽  
Vol 1 (63-64) ◽  
pp. 4179-4184
Author(s):  
Gen Nakayama ◽  
Yohei Sakakibara ◽  
Tomomi Kouketsu ◽  
Kouji Arakawa ◽  
Yutaka Mizo ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Stress Corrosion ◽  
Stress Corrosion Cracking ◽  
Steel Structures ◽  
Chloride Ion ◽  
Storage Conditions ◽  
Residual Stress Distribution ◽  
Corrosion Cracking ◽  
Ion Concentration ◽  
Degree Of Sensitization

ABSTRACTFabricated stainless steel structures are susceptible to stress corrosion cracking (SCC), despite being placed in chloride-containing natural water or humid atmospheres. The present paper describes a model that can define the conditions under which SCC is initiated and propagated, based on analyses of actual SCC incidents induced at welded flanges of cylindrical stainless steel structures.Whenever the vitrified radioactive waste canister storage conditions deviate from normal and appropriate conditions due to earthquakes or tsunamis, the exposed canisters are expected to suffer SCC within 400 hours to 7 years, according to the analytical results obtained such as degree of sensitization, residual stress distribution, chloride ion concentration, and temperature.

scholarly journals First Attempts of the Use of 195Pt NMR of Phenylbenzothiazole Complexes as Spectroscopic Technique for the Cancer Diagnosis

Molecules ◽  
2019 ◽  
Vol 24 (21) ◽  
pp. 3970 ◽  
Author(s):  
Bruna T. L. Pereira ◽  
Mateus A. Gonçalves ◽  
Daiana T. Mancini ◽  
Kamil Kuca ◽  
Teodorico C. Ramalho
Keyword(s):  
Cancer Treatment ◽  
Cancer Diagnosis ◽  
Density Functional ◽  
Chemical Shifts ◽  
Chloride Ion ◽  
Platinum Complexes ◽  
Dft Method ◽  
Ion Concentration ◽  
Implicit Solvent ◽  
Early Cancer Diagnosis

Platinum complexes have been studied for cancer treatment for several decades. Furthermore, another important platinum characteristic is related to its chemical shifts, in which some studies have shown that the 195Pt chemical shifts are very sensitive to the environment, coordination sphere, and oxidation state. Based on this relevant feature, Pt complexes can be proposed as potential probes for NMR spectroscopy, as the chemical shifts values will be different in different tissues (healthy and damaged) Therefore, in this paper, the main goal was to investigate the behavior of Pt chemical shifts in the different environments. Calculations were carried out in vacuum, implicit solvent, and inside the active site of P13K enzyme, which is related with breast cancer, using the density functional theory (DFT) method. Moreover, the investigation of platinum complexes with a selective moiety can contribute to early cancer diagnosis. Accordingly, the Pt complexes selected for this study presented a selective moiety, the 2-(4′aminophenyl)benzothiazole derivative. More specifically, two Pt complexes were used herein: One containing chlorine ligands and one containing water in place of chlorine. Some studies have shown that platinum complexes coordinated to chlorine atoms may suffer hydrolyses inside the cell due to the low chloride ion concentration. Thus, the same calculations were performed for both complexes. The results showed that both complexes presented different chemical shift values in the different proposed environments. Therefore, this paper shows that platinum complexes can be a potential probe in biological systems, and they should be studied not only for cancer treatment, but also for diagnosis.

scholarly journals Broadband dielectric spectroscopy for monitoring temperature-dependent chloride ion motion in BiOCl plates

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Adrian Radoń ◽  
Dariusz Łukowiec ◽  
Patryk Włodarczyk
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Spectroscopy ◽  
Low Frequency ◽  
Chloride Ion ◽  
Ion Source ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Broadband Dielectric Spectroscopy ◽  
Free Chloride ◽  
Structure Rebuilding

AbstractThe dielectric properties and electrical conduction mechanism of bismuth oxychloride (BiOCl) plates synthesized using chloramine-T as the chloride ion source were investigated. Thermally-activated structure rebuilding was monitored using broadband dielectric spectroscopy, which showed that the onset temperature of this process was 283 K. This rebuilding was related to the introduction of free chloride ions into [Bi2O2]2+ layers and their growth, which increased the intensity of the (101) diffraction peak. The electrical conductivity and dielectric permittivity were related to the movement of chloride ions between plates (in the low-frequency region), the interplanar motion of Cl− ions at higher frequencies, vibrations of these ions, and charge carrier hopping at frequencies above 10 kHz. The influence of the free chloride ion concentration on the electrical conductivity was also described. Structure rebuilding was associated with a lower concentration of free chloride ions, which significantly decreased the conductivity. According to the analysis, the BiOCl plate conductivity was related to the movement of Cl− ions, not electrons.

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