scholarly journals STRUCTURAL INTERACTIONS OF HYDROGEN WITH BULK AMORPHOUS MICROSTRUCTURES IN METALLIC SYSTEMS UNDERSTANDING THE ROLE OF PARTIAL CRYSTALLINITY ON PERMEATION AND EMBRITTLEMENT

2010 ◽  
Author(s):  
Kyle Brinkman ◽  
Elise Fox ◽  
Paul Korinko ◽  
Thad Adams
2010 ◽  
Vol 2010 ◽  
pp. 1-12 ◽  
Author(s):  
Gethin R. Owen ◽  
David L. Stokes

Desmosomes are a complex assembly of protein molecules that mediate adhesion between adjacent cells. Desmosome composition is well established and spatial relationships between components have been identified. Intercellular cell-cell adhesion is created by the interaction of extracellular domains of desmosomal cadherins, namely, desmocollins and desmogleins. High-resolution methods have provided insight into the structural interactions between cadherins. However, there is a lack of understanding about the architecture of the intact desmosomes and the physical principles behind their adhesive strength are unclear. Electron Tomography (ET) studies have offered three-dimensional visual data of desmosomal cadherin associations at molecular resolution. This review discusses the merits of two cadherin association models represented using ET. We discuss the possible role of sample preparation on the structural differences seen between models and the possibility of adaptive changes in the structure as a direct consequence of mechanical stress and stratification.


2011 ◽  
Vol 378 (1-2) ◽  
pp. 301-307 ◽  
Author(s):  
Kyle Brinkman ◽  
Elise Fox ◽  
Paul Korinko ◽  
David Missimer ◽  
Thad Adams ◽  
...  

2008 ◽  
Vol 1126 ◽  
Author(s):  
Kyle S. Brinkman ◽  
Elise B Fox ◽  
Paul Korinko ◽  
Thad Adams ◽  
Arthur Jurgensen

AbstractIt is recognized that hydrogen separation membranes are a key component of the emerging hydrogen economy. A potentially exciting material for membrane separations are bulk metallic glass materials due to their low cost, high elastic toughness and resistance to hydrogen ‘embrittlement’ as compared to crystalline Pd-based membrane systems. However, at elevated temperatures and extended operation times structural changes including partial crystallinity may appear in these amorphous metallic systems. A systematic evaluation of the impact of partial crystallinity/devitrification on the diffusion and solubility behavior in multi-component Metallic Glass materials would provide great insight into the potential of these materials for hydrogen applications. This study will report on the development of time and temperature crystallization mapping and their use for interpretation of ‘in-situ’ hydrogen permeation at elevated temperatures.


2001 ◽  
Vol 45 (12) ◽  
pp. 1439-1445 ◽  
Author(s):  
Pavel Protsenko ◽  
Anne Terlain ◽  
Vladimir Traskine ◽  
Nicolas Eustathopoulos
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