scholarly journals A study of the relationship between lithium ion transport and structure and dynamic behavior in polyethylene oxide-melt/LiClO4 battery electrolytes.

2009 ◽  
Author(s):  
James C. Selser
Keyword(s):  
Ion Transport ◽  
Dynamic Behavior ◽  
Polyethylene Oxide ◽  
Lithium Ion ◽  
Oxide Melt ◽  
The Relationship

scholarly journals Molecular Dynamics Study of Ion Transport in Polymer Electrolytes of All-Solid-State Li-Ion Batteries

Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1012
Author(s):  
Takuya Mabuchi ◽  
Koki Nakajima ◽  
Takashi Tokumasu
Keyword(s):  
Molecular Dynamics ◽  
Solid State ◽  
Ion Transport ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Li Ion Batteries ◽  
Transport Mechanisms ◽  
Li Ion ◽  
Dynamics Simulations ◽  
The Relationship

Atomistic analysis of the ion transport in polymer electrolytes for all-solid-state Li-ion batteries was performed using molecular dynamics simulations to investigate the relationship between Li-ion transport and polymer morphology. Polyethylene oxide (PEO) and poly(diethylene oxide-alt-oxymethylene), P(2EO-MO), were used as the electrolyte materials, and the effects of salt concentrations and polymer types on the ion transport properties were explored. The size and number of LiTFSI clusters were found to increase with increasing salt concentrations, leading to a decrease in ion diffusivity at high salt concentrations. The Li-ion transport mechanisms were further analyzed by calculating the inter/intra-hopping rate and distance at various ion concentrations in PEO and P(2EO-MO) polymers. While the balance between the rate and distance of inter-hopping was comparable for both PEO and P(2EO-MO), the intra-hopping rate and distance were found to be higher in PEO than in P(2EO-MO), leading to a higher diffusivity in PEO. The results of this study provide insights into the correlation between the nanoscopic structures of ion solvation and the dynamics of Li-ion transport in polymer electrolytes.

Lithium ion transport in a model of amorphous polyethylene oxide

1996 ◽  
Vol 3 (1-3) ◽  
pp. 385-402 ◽  
Author(s):  
P. T. Boinske ◽  
L. Curtiss ◽  
J. W. Halley ◽  
B. Lin ◽  
A. Sutjianto
Keyword(s):  
Ion Transport ◽  
Polyethylene Oxide ◽  
Lithium Ion

Selectively accelerated lithium ion transport to silicon anodes via an organogel binder

2015 ◽  
Vol 298 ◽  
pp. 8-13 ◽  
Author(s):  
Chihyun Hwang ◽  
Yoon-Gyo Cho ◽  
Na-Ri Kang ◽  
Younghoon Ko ◽  
Ungju Lee ◽  
...  
Keyword(s):  
Ion Transport ◽  
Lithium Ion ◽  
Silicon Anodes

scholarly journals Insights from Local Network Structures and Localized Diffusion on the Ease of Lithium Ion Transport in Two Mixed Glass-Former Systems

2017 ◽  
Vol 121 (33) ◽  
pp. 17641-17657 ◽  
Author(s):  
Kristina Sklepić ◽  
Radha D. Banhatti ◽  
Gregory Tricot ◽  
Petr Mošner ◽  
Ladislav Koudelka ◽  
...  
Keyword(s):  
Ion Transport ◽  
Lithium Ion ◽  
Local Network ◽  
Network Structures

scholarly journals Coral-like directional porosity lithium ion battery cathodes by ice templating

2018 ◽  
Vol 6 (30) ◽  
pp. 14689-14699 ◽  
Author(s):  
Chun Huang ◽  
Patrick S. Grant
Keyword(s):  
Ion Transport ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Transport Direction ◽  
Ice Templating

Thick cathodes with aligned pore arrays in the predominant ion transport direction made by ice templating provided high areal and gravimetric capacities.

Ion Transport in Alumina-Pillared Zirconium Phosphate

1992 ◽  
Vol 286 ◽  
Author(s):  
C. Criado ◽  
J.R. Ramos-Barrado ◽  
P. Maireles-Torres ◽  
P. Oliverapastor ◽  
A. Jimenez-Lopez ◽  
...  
Keyword(s):  
Ion Transport ◽  
Equivalent Circuit ◽  
Temperature Interval ◽  
Zirconium Phosphate ◽  
Lithium Ion ◽  
Charge Carriers ◽  
Impedance Method ◽  
Electrical Behaviour ◽  
Lithium Ions ◽  
Zirconium Phosphates

ABSTRACTA.c. conductivity of a novel large-pore alumina-pillared zirconium phosphate and some lithium ion exchanged samples have been measured by an impedance method. These materials have a conductivity in the range 10-5 to 10-9 Ω-1cm-1 higher than those of alumina-pillared tin phosphate and its lithium derivatives. The electrical behaviour of the pillared zirconium phosphates fits to an equivalent circuit composed by two subcircuits in parallel with a condenser. In a temperature interval (200-500°C), lithium ions are charge carriers and the conductivity increases when heating with activation energies between 0.99 and 1.22 eV.

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