scholarly journals The Influence of MSI (Metal-Support Interactions) and the Solvent in Liquid-Phase Reactions

2003 ◽  
Author(s):  
M A Vannice
Keyword(s):  
Liquid Phase ◽  
Metal Support ◽  
Metal Support Interactions

scholarly journals Understanding Heteroatom-Mediated Metal–Support Interactions in Functionalized Carbons: A Perspective Review

2018 ◽  
Vol 8 (7) ◽  
pp. 1159 ◽  
Author(s):  
Sebastiano Campisi ◽  
Carine Chan-Thaw ◽  
Alberto Villa
Keyword(s):  
Liquid Phase ◽  
Metal Nanoparticles ◽  
Electronic Properties ◽  
Functional Groups ◽  
Theoretical Models ◽  
Alcohol Oxidation ◽  
Metal Interaction ◽  
Characterization Techniques ◽  
Metal Support ◽  
Metal Support Interactions

Carbon-based materials show unique chemicophysical properties, and they have been successfully used in many catalytic processes, including the production of chemicals and energy. The introduction of heteroatoms (N, B, P, S) alters the electronic properties, often increasing the reactivity of the surface of nanocarbons. The functional groups on the carbons have been reported to be effective for anchoring metal nanoparticles. Although the interaction between functional groups and metal has been studied by various characterization techniques, theoretical models, and catalytic results, the role and nature of heteroatoms is still an object of discussion. The aim of this review is to elucidate the metal–heteroatoms interaction, providing an overview of the main experimental and theoretical outcomes about heteroatom-mediated metal–support interactions. Selected studies showing the effect of heteroatom–metal interaction in the liquid-phase alcohol oxidation will be also presented.

Growth kinetic control over MgFe2O4 to tune Fe occupancy and metal–support interactions for optimum catalytic performance

CrystEngComm ◽  
2021 ◽  
Vol 23 (13) ◽  
pp. 2538-2546
Author(s):  
Min Yang ◽  
Guangshe Li ◽  
Huixia Li ◽  
Junfang Ding ◽  
Yan Wang ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Growth Kinetic ◽  
Catalytic Performance ◽  
Growth Behavior ◽  
Kinetic Control ◽  
Size Dependent ◽  
Metal Support ◽  
Support Size ◽  
Metal Support Interactions ◽  
First Time

For the first time, the growth behavior with size-dependent Fe occupancies at different sites of MgFe2O4 was examined. Hybrid catalysts of Pt/MgFe2O4 with a support size of 20.6 nm exhibited an optimal performance of CO oxidation.

Metal–Support Interactions in Fe/ZrO2Catalysts for Hydrogenation of CO

1997 ◽  
Vol 167 (2) ◽  
pp. 573-575 ◽  
Author(s):  
Kaidong Chen ◽  
Yining Fan ◽  
Qijie Yan
Keyword(s):  
Metal Support ◽  
Metal Support Interactions ◽  
Hydrogenation Of Co
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