scholarly journals High Level Waste (HLW) Feed Process Control Strategy

2000 ◽  
Author(s):  
T.W. STAEHR
Keyword(s):  
Process Control ◽  
Control Strategy ◽  
High Level Waste ◽  
High Level

scholarly journals High Level Waste (HLW) Vitrification Experience in the US: Application of Glass Product/Process Control to Other HLW and Hazardous Wastes

2008 ◽  
Vol 1107 ◽  
Author(s):  
Carol M. Jantzen ◽  
James C. Marra
Keyword(s):  
Process Control ◽  
High Level Waste ◽  
Glass Product ◽  
Mechanistic Models ◽  
Glass Waste ◽  
Statistical Process ◽  
Feed Composition ◽  
Feed Forward ◽  
Bonding Structure ◽  
High Level

AbstractVitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. At the Savannah River Site (SRS) actual HLW tank waste has successfully been processed to stringent product and process constraints without any rework into a stable borosilicate glass waste since 1996. A unique “feed forward” statistical process control (SPC) has been used rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. In SQC, the glass product is sampled after it is vitrified. Individual glass property models form the basis for the “feed forward” SPC. The property models transform constraints on the melt and glass properties into constraints on the feed composition. The property models are mechanistic and depend on glass bonding/structure, thermodynamics, quasicrystalline melt species, and/or electron transfers. The mechanistic models have been validated over composition regions well outside of the regions for which they were developed because they are mechanistic. Mechanistic models allow accurate extension to radioactive and hazardous waste melts well outside the composition boundaries for which they were developed.

Effects of Aging on the Solubility of Palladium

1995 ◽  
Vol 412 ◽  
Author(s):  
C. Oda ◽  
H. Yoshikawa ◽  
M. Yui
Keyword(s):  
Aqueous Solution ◽  
Aging Time ◽  
Room Temperature ◽  
High Level Waste ◽  
Anaerobic Conditions ◽  
Dilute Aqueous Solution ◽  
Waste Repository ◽  
Ph Range ◽  
Effects Of Aging ◽  
High Level

AbstractPalladium solubility was measured in a dilute aqueous solution at room temperature in the pH range from 3 to 13 under anaerobic conditions. Crystalline Pd metal was clearly visible and the concentration of palladium in solution decreased gradually with aging time. The palladium concentrations in solution were less than 9.4×10-10M in the pH range from 4 to 10 and increased to 10-7M in the pH range greater than 10. This study suggests that palladium concentrations in certain high-level waste repository environments may be limited by Pd metal and may be less than 10-9M.

Performance assessment of the disposal of vitrified high-level waste in a clay layer

2001 ◽  
Vol 298 (1-2) ◽  
pp. 125-135 ◽  
Author(s):  
Dirk Mallants ◽  
Jan Marivoet ◽  
Xavier Sillen
Keyword(s):  
Performance Assessment ◽  
High Level Waste ◽  
Clay Layer ◽  
High Level

Use of microwave energy in reprocessing of high-level waste

Atomic Energy ◽  
1992 ◽  
Vol 73 (3) ◽  
pp. 730-734 ◽  
Author(s):  
A. A. Kurkumeli ◽  
M. I. Molokhov ◽  
O. D. Sadkovskaya ◽  
V. I. Kononov ◽  
G. B. Borisov ◽  
...  
Keyword(s):  
Microwave Energy ◽  
High Level Waste ◽  
High Level
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