scholarly journals Volatility of a zinc borosilicate glass containing simulated high-level radioactive waste. [800 to 1200/sup 0/C]

1976 ◽  
Author(s):  
W.J. Gray
Keyword(s):  
Radioactive Waste ◽  
Borosilicate Glass ◽  
High Level Radioactive Waste ◽  
High Level ◽  
Zinc Borosilicate

scholarly journals High-Level Radioactive Insoluble Waste Preparation for Vitrification

1984 ◽  
Vol 44 ◽  
Author(s):  
B. A. Hamm ◽  
R. E. Eibling ◽  
M. A. Ebra ◽  
T. Motyka ◽  
H. D. Martin
Keyword(s):  
Radioactive Waste ◽  
Borosilicate Glass ◽  
Savannah River ◽  
Soluble Salts ◽  
High Level Radioactive Waste ◽  
Savannah River Plant ◽  
High Level

AbstractAt the Savannah River Plant (SRP), a process has been developed for immobilizing high-level radioactive waste in a borosilicate glass. The waste is currently stored as soluble salts and insoluble solids. Insoluble waste as stored requires further processing before vitrification is possible. The processes required have been developed and demonstrated with actual waste. They include removal of aluminum in some waste, washing soluble salts out of the insoluble waste, and mercury stripping. Each of the processes and the results with actual SRP waste will be discussed. The benefits of each step will also be included.

Mercury Reduction and Removal During High-Level Radioactive Waste Processing and Vitrification

1981 ◽  
Vol 6 ◽  
Author(s):  
Russell E. Eibling ◽  
John R. fowler
Keyword(s):  
Radioactive Waste ◽  
Formic Acid ◽  
Borosilicate Glass ◽  
Processing Temperature ◽  
Savannah River ◽  
High Level Radioactive Waste ◽  
Savannah River Plant ◽  
Reference Process ◽  
Glass Melter ◽  
High Level

ABSTRACTA reference process for immobilizing the high-level radioactive waste in borosilicate glass has been developed at the Savannah River Plant. This waste contains a substantial amount of mercury from separations processing. Because mercury will not remain in borosilicate glass at the processing temperature, mercury must be removed before vitrification or must be handled in the off-gas system. A process has been developed to remove mercury by reduction with formic acid prior to vitrification. Additional benefits of formic acid treatment include improved sludge handling and glass melter redox control.

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