scholarly journals Detection of light elements by energy dispersive x-ray fluorescence analysis using secondary emitters

1976 ◽  
Author(s):  
V.C. Anselmo
1993 ◽  
Vol 37 ◽  
pp. 577-583
Author(s):  
Christina Streli ◽  
P. Wobrauschek ◽  
H. Aiginger ◽  
W. Ladisich ◽  
R. Rieder

AbstractTotal Reflection X-Ray Fluorescence Analysis (TXRF) has been proved to be well suited for the energy dispersive analysis of light elements using a special spectrometer, which is equipped with an energy dispersive detector having all properties for the detection of low energy radiation. The detection of the light elements is strongly influenced by the excitation source which should provide a large number of photons with energies near the K-absorption edge of these elements (0.2 - 3 keV). Various standard tubes with Be-window as well as a homemade windowless tube are compared, all differing in focal size, total power and anode material. Optimized excitation conditions are provided by synchrotron radiation meeting all requirements for excellent excitation of light elements in total reflection geometry such as high brilliance and ideal spectral distribution specially in the low energy region. A comparison of excitation with X-ray tubes as well as with synchrotron radiation is shown. Detection limits of 200 fg for Mg have been obtained with synchrotron radiation.


1983 ◽  
Vol 19 (2) ◽  
pp. 201-211 ◽  
Author(s):  
A. B. Cormie ◽  
D. E. Nelson

AbstractThe use of energy-dispersive X-ray fluorescence analysis (XES) for the routine identification of three tephras (Mazama, Bridge River, Mount St. Helens Yn) commonly found in archeological sites in British Columbia has been investigated. Researchers have often assumed that chemical analysis of bulk samples of glass separates would be hampered by contamination and weathering effects. Our results indicate that XES of bulk glass separates provides a very reliable method for rapidly identifying the three tephras in question, even with a very simple sample preparation. This should enable persons not skilled in geology or in tephrochronology to collect and to identify samples of these tephras. Finally, as a part of the study, similar measurements were made on the separated glass portions of these three tephras and of three others (Glacier Peak B and G, White River) from northwest North America. The results suggest that this method may provide tephrochronologists with a useful additional tool for studying tephras in other regions.


1983 ◽  
Vol 12 (4) ◽  
pp. 175-181 ◽  
Author(s):  
P. Hoffmann ◽  
K. H. Lieser ◽  
T. Hofmann ◽  
R. Sommer

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