scholarly journals Experience with a joule heated ceramic melter while converting simulated high-level waste to glass

1976 ◽  
Author(s):  
C.C. Chapman
2019 ◽  
Vol 505 ◽  
pp. 215-224 ◽  
Author(s):  
Devon L. McClane ◽  
Jake W. Amoroso ◽  
Kevin M. Fox ◽  
Albert A. Kruger

1978 ◽  
Author(s):  
B.E. Scheetz ◽  
D.K. Smith ◽  
M.W. Barnes ◽  
S. Komarneni ◽  
L.M. Stull ◽  
...  

1995 ◽  
Vol 223 (2) ◽  
pp. 151-156 ◽  
Author(s):  
Miguel A. Audero ◽  
Arturo M. Bevilacqua ◽  
Norma B.M. de Bernasconi ◽  
Diego O. Russo ◽  
Mario E. Sterba

Author(s):  
Robert E. Prince ◽  
Bradley W. Bowan

This paper describes actual experience applying a technology to achieve volume reduction while producing a stable waste form for low and intermediate level liquid (L/ILW) wastes, and the L/ILW fraction produced from pre-processing of high level wastes. The chief process addressed will be vitrification. The joule-heated ceramic melter vitrification process has been used successfully on a number of waste streams produced by the U.S. Department of Energy (DOE). This paper will address lessons learned in achieving dramatic improvements in process throughput, based on actual pilot and full-scale waste processing experience. Since 1991, Duratek, Inc., and its long-term research partner, the Vitreous State Laboratory of The Catholic University of America, have worked to continuously improve joule heated ceramic melter vitrification technology in support of waste stabilization and disposition in the United States. From 1993 to 1998, under contact to the DOE, the team designed, built, and operated a joule-heated melter (the DuraMelterTM) to process liquid mixed (hazardous/low activity) waste material at the Savannah River Site (SRS) in South Carolina. This melter produced 1,000,000 kilograms of vitrified waste, achieving a volume reduction of approximately 70 percent and ultimately producing a waste form that the U.S. Environmental Protection Agency (EPA) delisted for its hazardous classification. The team built upon its SRS M Area experience to produce state-of-the-art melter technology that will be used at the DOE’s Hanford site in Richland, Washington. Since 1998, the DuraMelterTM has been the reference vitrification technology for processing both the high level waste (HLW) and low activity waste (LAW) fractions of liquid HLW waste from the U.S. DOE’s Hanford site. Process innovations have doubled the throughput and enhanced the ability to handle problem constituents in LAW. This paper provides lessons learned from the operation and testing of two facilities that provide the technology for a vitrification system that will be used in the stabilization of the low level fraction of Hanford’s high level tank wastes.


1996 ◽  
Vol 465 ◽  
Author(s):  
Katherine L. Smith ◽  
Michael Colella ◽  
Gordon J. Thorogood ◽  
Mark G. Blackford ◽  
Gregory R. Lumpkin ◽  
...  

ABSTRACTSynroc containing 20 wt% simulated high level waste (HLW) was subjected to two sets of leach tests at 150°C where the leachant was and was not replaced during the test (replacement and non-replacement testing). The leachant was a KH-phthalate buffered solution (pH 4.2). Samples were characterised before and after leach testing using SEM, AEM and SIMS. Elemental concentrations in leachates were measured using ICP-MS. In concert with the findings of i) a dissolution study of perovskite in a flowing leachant and ii) a previous Synroc dissolution study (wherein Synroc containing 10 wt% simulated HLW was subjected to periodic replacement, leach testing in deionised water at 150°C), the results of this study show that when the leachant replacement frequency is varied from 7 d to the duration of the test, there is no effect on leach rate or leaching mechanisms.


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